镍钨合金镀层对 QT-900 油管耐 CO2 腐蚀的影响

孙福洋, 赵国仙, 郭清超, 李丹平

表面技术 ›› 2014, Vol. 43 ›› Issue (6) : 6-10,15.

PDF(2896 KB)
PDF(2896 KB)
表面技术 ›› 2014, Vol. 43 ›› Issue (6) : 6-10,15.

镍钨合金镀层对 QT-900 油管耐 CO2 腐蚀的影响

  • 孙福洋1, 赵国仙1, 郭清超2, 李丹平3
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Effect of Ni-W Alloy Coating on the Corrosion Resistance of QT-900 Coiled Tubing

  • SUN Fu-yang1, ZHAO Guo-xian1, GUO Qing-chao2, LI Dan-ping3
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摘要

目的 对镍钨合金镀层在连续油管上的应用进行初步探索。 方法 通过直流电沉积法,在 QT-900 连续油管表面沉积镍钨合金层。 模拟某油田腐蚀环境,通过高温高压腐蚀实验,采用金相显微镜、SEM 和 EDS 等分析手段,对比镀镍钨合金连续油管和普通连续油管的耐蚀性能,研究在 CO2 介质中镍钨合金镀层对油管耐蚀性的影响。 结果 镍钨合金镀层中主要含 Ni 和 W 元素,Fe 和 Mn 元素含量较少,镀层平均厚度在 55 μm 左右。 在温度 60 ℃ ,CO2 分压 1. 07 MPa,拉应力 439 MPa 的条件下,镍钨合金镀层的平均腐蚀速率为 0. 0160 mm/ a,约为普通连续油管的 1 /40,属于轻度腐蚀。 结论 镍钨合金镀层具有良好的耐 CO2 腐蚀性能。

Abstract

Objective To preliminarily explore the application of Ni-W alloy coating in QT-900 coiled tubing. Methods Ni-W alloy coating was deposited on the surface of QT-900 coiled tubing by DC electrodeposition. An oilfield corrosion environment was simulated by high temperature and high pressure corrosion tests. The effect of Ni-W alloy coating on coiled tubing was studied by comparing the corrosion resistance of Ni-W alloy coating and coiled tubing using analysis methods such as microscopy, SEM and EDS. The effect of Ni-W alloy coating on the corrosion resistance of oil tubing in CO2 medium was studied. Results Ni-W alloy coating mainly consisted of Ni and W elements, and the Fe and Mn contents were low. The average thickness of the coating was 55 μm. The uniform corrosion rate of Ni-W alloy coating was 0. 0160 mm/ a at 60℃, with a CO2 partial pressure of 1. 07 MPa and a tensile stress of 439 MPa, which was 1 /40 of that of the ordinary coiled tubing. The corrosion rate belonged to slight corrosion. Conclusion Ni-W alloy coating had a good resistance to CO2 corrosion.

关键词

镍钨合金镀层; QT-900 连续油管; 耐蚀性

Key words

Ni-W alloy coating; QT-900 coiled tubing; corrosion resistance

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孙福洋, 赵国仙, 郭清超, 李丹平. 镍钨合金镀层对 QT-900 油管耐 CO2 腐蚀的影响[J]. 表面技术. 2014, 43(6): 6-10,15
SUN Fu-yang, ZHAO Guo-xian, GUO Qing-chao, LI Dan-ping. Effect of Ni-W Alloy Coating on the Corrosion Resistance of QT-900 Coiled Tubing[J]. Surface Technology. 2014, 43(6): 6-10,15

基金

国家自然科学基金资助项目(51271146)

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