430 不锈钢表面月桂酸自组装膜的探究

王海人, 陈凤, 屈钧娥, 聂德键

表面技术 ›› 2013, Vol. 42 ›› Issue (3) : 81-84.

PDF(3310 KB)
PDF(3310 KB)
表面技术 ›› 2013, Vol. 42 ›› Issue (3) : 81-84.
应用技术

430 不锈钢表面月桂酸自组装膜的探究

  • 王海人, 陈凤, 屈钧娥, 聂德键
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Research on the Lauric Acid SAMs on the Surface of 430 Stainless Steel

  • WANG Hai-ren, CHEN Feng, QU Jun-e, NIE De-jian
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摘要

采用浸泡法在 430 不锈钢表面制备了月桂酸自组装膜,通过电化学方法、接触角测试及微观形貌分析,研究了该自组装膜在 430 不锈钢表面的吸附行为及缓蚀作用。 研究结果表明:经过简单的浸泡,月桂酸分子能够稳定地吸附在不锈钢表面,自组装时间、组装液浓度以及基底表面前处理对组装膜的缓蚀效率有较大影响,自组装时间 4 h、月桂酸浓度 5 mmol / L、组装温度 35 ℃ 为最佳自组装条件;基底在组装之前进行钝化处理,有利于形成致密的自组装分子膜,提高不锈钢的耐蚀性能。

Abstract

Self-assembled monolayers ( SAMs) of Lauric Acid ( LA) were prepared on the surfaces of 430 stainless steel (430 SS) by immersing method in the assembly solutions. The adsorption behavior and corrosion inhibition performance of LA SAMs were investigated by electrochemical tests, contact angle measurement and microscopic morphology analysis. The results indicated that LA SAMs was chemically absorded on 430 SS via a simply immersion progress. The assembly time of 4 h, LA concentration of 5 mmol / L,assembly temperature of 35 ℃ were the optimal parameters for assembling. Passivation pretreatment was beneficial for forming a denser SAMs on the surface of 430 SS and improving the corrodion resistance of 430 SS.

关键词

430 不锈钢; 月桂酸; 自组装膜; 缓蚀效率

Key words

430 stainless steel; lauric acid; SAMs; corrosion inhibition performance

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导出引用
王海人, 陈凤, 屈钧娥, 聂德键. 430 不锈钢表面月桂酸自组装膜的探究[J]. 表面技术. 2013, 42(3): 81-84
WANG Hai-ren, CHEN Feng, QU Jun-e, NIE De-jian. Research on the Lauric Acid SAMs on the Surface of 430 Stainless Steel[J]. Surface Technology. 2013, 42(3): 81-84

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