自组装硅烷膜对 6061 铝合金表面耐蚀性影响的研究

温玉清, 孟惠民, 尚伟, 张敏, 张旋, 陶勇, 黄成泽

表面技术 ›› 2013, Vol. 42 ›› Issue (3) : 78-80,111.

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PDF(3577 KB)
表面技术 ›› 2013, Vol. 42 ›› Issue (3) : 78-80,111.
应用技术

自组装硅烷膜对 6061 铝合金表面耐蚀性影响的研究

  • 温玉清1, 孟惠民2, 尚伟3, 张敏4, 张旋4, 陶勇4, 黄成泽4
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The Research of the Effect of the Self-assembly Silane Film on Corrosion Resistance of 6061 Aluminum Alloy Surface

  • WEN Yu-qing1, MENG Hui-min2, SHANG Wei3, ZHANG Min4, ZHANG Xuan4, TAO Yong4, HUANG Cheng-ze4
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摘要

采用自组装方法,在 6061 铝合金表面制备十二氟庚基丙基三甲氧基硅烷自组装膜层,对制备工艺进行了优化,并对自组装膜层进行了表面形貌分析,通过极化曲线和电化学阻抗谱研究了自组装膜层的耐蚀性能。 结果表明:与铝合金基体相比,自组装膜的腐蚀电流密度减小了 3 个数量级,电化学阻抗值增大了近 1 倍,达到了提高铝合金表面耐蚀性能的目的。

Abstract

The SAMs of twelve fluorine heptyl propyl silane three oxygen radicals was prepared by self-assembly( SA) methods. In the study, discussing and optimizing conditions to enhance corrosion protection of metals. The surface morphology of the SAMs were token by SEM,the corrosion resistance of the SAMs were researched by the methods of polarization curve and EIS. The results showed that compared with aluminum alloy matrix, corrosion current density decreased by 3 orders of magnitude and electrochemical impedance was increased near 1 times. So the SAMs had better anti-corrosion property on aluminum alloy than bare Aluminum alloy.

关键词

铝合金; 自组装膜; 十二氟庚基丙基三甲氧基硅烷; 耐蚀性

Key words

aluminum alloy; the self-assembly film; twelve fluorine heptyl propyl silane three oxygen radicals; corrosion resistance

引用本文

导出引用
温玉清, 孟惠民, 尚伟, 张敏, 张旋, 陶勇, 黄成泽. 自组装硅烷膜对 6061 铝合金表面耐蚀性影响的研究[J]. 表面技术. 2013, 42(3): 78-80,111
WEN Yu-qing, MENG Hui-min, SHANG Wei, ZHANG Min, ZHANG Xuan, TAO Yong, HUANG Cheng-ze. The Research of the Effect of the Self-assembly Silane Film on Corrosion Resistance of 6061 Aluminum Alloy Surface[J]. Surface Technology. 2013, 42(3): 78-80,111

基金

国家自然科学基金资助项目(21063005) ; 广西教育厅科研项目(201012MS104)

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