Ni 含量对热浸 Zn-Al-Ni 合金镀层组织和耐腐蚀性能的影响

邵大伟, 贺志荣, 张永宏

表面技术 ›› 2013, Vol. 42 ›› Issue (2) : 18-19,43.

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PDF(3164 KB)
表面技术 ›› 2013, Vol. 42 ›› Issue (2) : 18-19,43.
研究与探索

Ni 含量对热浸 Zn-Al-Ni 合金镀层组织和耐腐蚀性能的影响

  • 邵大伟, 贺志荣, 张永宏
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Effect of Ni Content on Microstructure and Corrosion Resistance of Hot-dip Zn-Al-Ni Alloy Coating

  • SHAO Da-wei, HE Zhi-rong, ZHANG Yong-hong
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摘要

为了提高热浸镀锌层的耐腐蚀性能,向 Zn-0 . 01% Al 镀浴中添加少量 Ni, 在 Q235 钢表面获得Zn-Al-Ni热浸镀锌合金层,并用光学显微镜观察了镀层的组织,通过全浸腐蚀实验表征了镀层的耐腐蚀性能。 结果表明:随着镀浴中 Ni 含量的增加,Zn-Al-Ni 镀层的腐蚀速率先减小,后增大,当 Ni 含量为 0 . 05% 时,镀层的耐腐蚀性能最好;可以通过降低 ζ 相层的厚度以及增大 δ 相层的厚度,来提高镀层的耐腐蚀性能。

Abstract

In order to improve the corrosion resistance of hot-dip galvanizing coating, the hot-dip galvanizing alloy of Zn-Al-Ni were gained on the surface of Q235 steel by adding a small amount of Ni in the Zn-0 . 01 % Al bath. The microstructures of coatings were observed by the optical microscopy, and the corrosion resistance of coatings was characterized by full immersion corrosion test . The results show that the corrosion rate decreases firstly and then increases along with the increase of Ni content in the alloy bath. The corrosion resistance is the best for the coating when the Ni content is 0 . 05 % . The corrosion resistance can be enhanced by reducing the thickness of ζ phase and increasing the thickness of δ phase.

关键词

Zn-Al-Ni 合金; 热镀锌; 显微组织; 耐蚀性能

Key words

Zn-Al-Ni alloy; hot-dip galvanizing; microstructure; corrosion resistance

引用本文

导出引用
邵大伟, 贺志荣, 张永宏. Ni 含量对热浸 Zn-Al-Ni 合金镀层组织和耐腐蚀性能的影响[J]. 表面技术. 2013, 42(2): 18-19,43
SHAO Da-wei, HE Zhi-rong, ZHANG Yong-hong. Effect of Ni Content on Microstructure and Corrosion Resistance of Hot-dip Zn-Al-Ni Alloy Coating[J]. Surface Technology. 2013, 42(2): 18-19,43

基金

陕西省科技统筹创新工程计划项目(2011KTDZ01-03-06) ;汉中锌业有限责任公司科研基金项目( HZXY2011003)

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