钛合金表面微弧氧化及其耐磨与绝缘强化策略研究进展

黄建超; 宋凯强; 吴护林; 彭冬; 白懿心; 王旋; 张敏; 何庆兵; 李立; 丛大龙; 李忠盛

doi:10.16490/j.cnki.issn.1001-3660.2026.07.016

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表面技术 ›› 2026, Vol. 55 ›› Issue (7) : 201-218. DOI: 10.16490/j.cnki.issn.1001-3660.2026.07.016

装备表面工程

钛合金表面微弧氧化及其耐磨与绝缘强化策略研究进展

黄建超, 宋凯强, 吴护林, 彭冬, 白懿心, 王旋, 张敏, 何庆兵, 李立, 丛大龙^*, 李忠盛^*

作者信息 +

Research Progress of Micro-arc Oxidation on Titanium Alloy Surface and its Wear-resistant and Insulating Strengthening Strategies

HUANG Jianchao, SONG Kaiqiang, WU Hulin, PENG Dong, BAI Yixin, WANG Xuan, ZHANG Min, HE Qingbing, LI Li, CONG Dalong^*, LI Zhongsheng^*

Author information +

文章历史 +

摘要

钛合金表面普遍存在耐磨与绝缘性能不足的问题,难以满足极端服役工况的要求。研究表明,微弧氧化（MAO）技术制备的陶瓷涂层在提升耐磨与绝缘性能方面具有显著潜力。为此,首先基于MAO陶瓷涂层生长过程与放电行为,系统阐述了其生长机制、放电模型和相关表征方法,为理解MAO工艺奠定理论基础;其次,重点归纳了电参数、电解质体系和基体预处理等因素对涂层组织结构的调控规律,为工艺优化提供科学依据;进而,深入探讨了耐磨与绝缘涂层的设计思路与性能评估,总结了涂层性能提升的关键技术路径;随后,分析了涂层耐磨与绝缘强化策略,阐明了涂层表面前处理、后处理以及复合协同工艺的作用机理与强化效果,为拓展钛合金表面强化技术提供参考;最后,展望了MAO技术在耐磨与绝缘改性领域的未来发展方向,以期巩固该技术在表面改性领域的不可替代性。

Abstract

Titanium alloy is extensively utilized in aerospace, marine engineering and other high-tech fields due to its excellent specific strength, thermal stability and corrosion resistance. However, its inherent low shear resistance and limited work-hardening capacity usually result in inadequate wear resistance, while its insufficient insulation performance caused by conductivity also limits its service performance under extreme conditions. Micro-arc oxidation (MAO), as a surface modification technology for in-situ growth of ceramic coatings, has become an effective method to improve the wear-resistance and insulation properties of titanium alloy surfaces. Its advantages include excellent coating-substrate, broad process adaptability, and environmental sustainability. In this paper, the research progress of MAO technology in wear resistance and insulation strengthening of titanium alloy surfaces is systematically reviewed. The coating growth mechanism, process control, performance design and composite strengthening strategies are discussed in detail. Firstly, the growth mechanism and discharge behavior of MAO ceramic coatings are systematically elucidated. The MAO process typically comprises three sequential stages: initial anodic oxidation, micro-arc discharge breakdown and steady-state deposition. The coating structure usually presents a double-layer feature with a dense inner layer and a porous outer layer. The growth of the coating is not only governed by electrical parameters but also significantly influenced by electrolyte composition and doped particles. In addition, integrating diverse discharge models with advanced characterization techniques provides a theoretical foundation for elucidating the coating formation mechanism. Secondly, the influence of process parameters on ceramic coatings microstructure is systematically analyzed. Among electrical parameters, the frequency and duty cycle synergistically control coating porosity and thickness. Elevated current densities generally accelerate coating growth and facilitate particle incorporation. The voltage application mode (whether constant or stepped) affects phase formation and structural uniformity. Regarding the electrolyte system, silicate-based electrolytes typically promote a porous outer layer, whereas phosphate-based solutions favor a denser inner layer; hybrid electrolytes can optimize both adhesion and wear resistance. Incorporating nanoparticles effectively seals micro-pores, enhances coating densification, and can introduce reinforcing hard phases or solid lubricants, thereby significantly improving coating properties. Additionally, substrate surface morphology and oxidation duration critically affect coating uniformity and final thickness. Design strategies for wear-resistant and insulating MAO coatings primarily encompass three approaches: (1) introducing high-hardness or lubricating composite phases to reduce the friction coefficient and improve the wear resistance; (2) employing hybrid surface engineering techniques to achieve structural optimization and synergistic performance enhancement; and (3) designing coatings with high density and increased thickness to barrier corrosive medium ingress, thereby improving both insulation and corrosion resistance. The performance analysis shows that the hard phases such as rutile TiO₂ and Al₂O₃ formed in the MAO coating can significantly improve the wear resistance, while the coating thickness and crystallinity are directly related to its insulation properties. To further improve coating performance, composite strengthening strategies integrating MAO are developed: (1) pre-treatment (e.g., laser texture, ultrasonic rolling), which can refine grains, induce residual compressive stress, and improve subsequent coating adhesion and density; (2) post-treatment (e.g., low temperature nitriding, anodic oxidation, sol-gel sealing), which can effectively infiltrate and seal inherent micro-pores and cracks, augmenting wear and corrosion resistance; and (3) synergistic in-process methods (e.g., laser, ultrasonic, magnetic field assisted MAO), which optimize discharge uniformity through energy field coupling and promote electrolyte doping and structural densification. Finally, future development of MAO technology is prospected to focus on three key directions: (1) developing energy-efficient, environmentally benign composite coating processes; (2) constructing data-driven and AI-enhanced predictive models for precise process-performance control; and (3) accelerating the industrial application of special functional coatings for extreme working conditions. Through interdisciplinary and industry-academia collaboration, micro-arc oxidation technology is expected to play an irreplaceable role in the field of titanium alloy surface modification.

导出引用

黄建超, 宋凯强, 吴护林, 彭冬, 白懿心, 王旋, 张敏, 何庆兵, 李立, 丛大龙, 李忠盛. 钛合金表面微弧氧化及其耐磨与绝缘强化策略研究进展[J]. 表面技术. 2026, 55(7): 201-218

HUANG Jianchao, SONG Kaiqiang, WU Hulin, PENG Dong, BAI Yixin, WANG Xuan, ZHANG Min, HE Qingbing, LI Li, CONG Dalong, LI Zhongsheng. Research Progress of Micro-arc Oxidation on Titanium Alloy Surface and its Wear-resistant and Insulating Strengthening Strategies[J]. Surface Technology. 2026, 55(7): 201-218

中图分类号： TG174.4

参考文献

[1] HE Y, XIAO G J, ZHU S W, et al.Surface Formation in Laser-Assisted Grinding High-Strength Alloys[J]. International Journal of Machine Tools and Manufacture, 2023, 186: 104002.
[2] TANG S S, SU J L, LI L, et al.Achieving Superior High-Temperature Strength and Ductility in Near-α Titanium Alloys by In-Situ Silicide Modulation[J]. Journal of Materials Science & Technology, 2025, 237: 38-53.
[3] ALIOFKHAZRAEI M, MACDONALD D D, MATYKINA E, et al.Review of Plasma Electrolytic Oxidation of Titanium Substrates: Mechanism, Properties, Applications and Limitations[J]. Applied Surface Science Advances, 2021, 5: 100121.
[4] LI J Z, WANG D Y, ZHU D.A New Perspective on the Surface Quality of Titanium Alloys in Pulsed Electrochemical Machining: Effect of Frequency and Passivation Film[J]. Journal of Materials Processing Technology, 2024, 330: 118463.
[5] YAO Y Y, CUI K, TIAN B Y, et al.Anti-Wear Protection for Titanium Alloy Interface Based on "Soft-Hard" Molecular Design Strategy and Viscosity-Lubrication Effect of Ionic Liquids[J]. Tribology International, 2026, 214: 111193.
[6] 南榕, 李思兰. 钛合金微动磨损的研究进展[J]. 钛工业进展, 2022, 39(5): 33-38.
NAN R, LI S L.Research Advances in Fretting Wear of Titanium Alloys[J]. Titanium Industry Progress, 2022, 39(5): 33-38.
[7] ESWARAPPA PRAMEELA S, POLLOCK T M, RAABE D, et al.Materials for Extreme Environments[J]. Nature Reviews Materials, 2023, 8(2): 81-88.
[8] CHOI Y, JEONG C.Improving Insulating and Wettability Properties of Titanium Alloys via Electrochemical Anodization[J]. Corrosion Science and Technology, 2025, 24(3): 151-161.
[9] LIU Z Y, ZHOU K, ZHU J H, et al.Fabricating Ultra Wear-Resistant Surfaces on Titanium Alloy by Combining Laser-Induced Modification with Abrasive Belt Grinding[J]. Tribology International, 2024, 200: 110160.
[10] ZHANG G, CHEN Y S, CAO Y K, et al.Superior Self-Lubricating Coatings with Heterogeneous Nanocomposite Structures on Ti-Nb-Zr-Ta-Hf Refractory Multi- Principal Element Alloy[J]. Advanced Functional Materials, 2024, 34(44): 2405657.
[11] ZHOU D W, WANG Z Y, ZHANG Y, et al.Stimulated Corrosion Damage of Ti-Al-N Multilayer Coatings under Interval Salt Spray and Hot Condition[J]. Corrosion Science, 2023, 222: 111431.
[12] YAN H J, TAI Z F, WU L K, et al.Improved High- Temperature Oxidation Resistance of TC4 Alloy by Electrodeposited SiO₂ Coating[J]. Corrosion Communications, 2021, 3: 34-44.
[13] LIU S L, ZHENG X P.Microstructure and Properties of AC-HVAF Sprayed Ni60/WC Composite Coating[J]. Journal of Alloys and Compounds, 2009, 480(2): 254-258.
[14] HUANG J C, ZHU J H, ZHOU K, et al.Probing Wear Mechanism of Ti₆Al₄V Micro-Textured Surfaces Processed by Laser-Assisted Grinding[J]. Journal of Alloys and Compounds, 2025, 1010: 178272.
[15] MARION S, LENCI M, GALIPAUD J, et al.Influence of the Crystallographic Orientations of Ti-6Al-4V Substrate on the Morphology and Optical Properties of Oxide Thin Films Obtained by Anodizing[J]. Surfaces and Interfaces, 2024, 47: 104193.
[16] 孙华为, 刘攀, 张雷, 等. 钎涂工艺对TC4表面金刚石复合涂层组织与耐磨性能影响[J]. 稀有金属材料与工程, 2025, 54(2): 481-489.
SUN H W, LIU P, ZHANG L, et al.Influence of Brazing Process on the Microstructure and Wear Resistance of Diamond Composite Coating on TC4[J]. Rare Metal Materials and Engineering, 2025, 54(2): 481-489.
[17] WENG F, CHEN C Z, YU H J.Research Status of Laser Cladding on Titanium and Its Alloys: A Review[J]. Materials & Design, 2014, 58: 412-425.
[18] BAO Y C, DENG J X, CAO S H, et al.Laser Micro- Cladding in Situ Forming Textured Surface to Improve the Tribological Performance[J]. Wear, 2024, 550: 205422.
[19] NOURI E P, ALLAHKARAM S R, GHARAGOZLOU M.Optimization of the Plasma Electrolytic Oxidation Process Parameters on 7075 Aluminum Alloy Using Taguchi Method[J]. Journal of Materials Research and Technology, 2025, 37: 537-548.
[20] WU G L, YIN Y Y, ZHANG S, et al.Effect of Laser Texturing on the Antiwear Properties of Micro-Arc Oxidation Coating Formed on Ti-6Al-4V[J]. Surface and Coatings Technology, 2023, 453: 129114.
[21] JIANG C Y, WANG Y M, WANG S Q, et al.Effects of Negative Voltage on Microstructure, Electrical Insulating, Anti-Corrosion, and Thermal Physical Performance of Plasma Electrolytic Oxidation Coating on SiCp/Al Composite[J]. Applied Surface Science, 2023, 636: 157789.
[22] CHEN X W, LI M L, ZHANG D F, et al.Corrosion Resistance of MoS₂-Modified Titanium Alloy Micro-Arc Oxidation Coating[J]. Surface and Coatings Technology, 2022, 433: 128127.
[23] PEGASHKIN V F, GOLUBEV V I, MEDISON V V.Use of Electrical Insulation of the Cutting Tool to Increase Tool Life when Machining Titanium Alloys[J]. The International Journal of Advanced Manufacturing Technology, 2014, 74(5): 599-614.
[24] MOURA C G, CARVALHO O, GONÇALVES L M V, et al. Laser Surface Texturing of Ti-6Al-4V by Nanosecond Laser: Surface Characterization, Ti-Oxide Layer Analysis and Its Electrical Insulation Performance[J]. Materials Science and Engineering: C, 2019, 104: 109901.
[25] MA D H, TONG J X, JIANG W, et al.Enhanced Surface Corrosion Resistance and Insulating Properties of 6061 Aluminum Alloy via LSM Pretreatment and Nano-AlN Incorporation by Plasma Electrolytic Oxidation[J]. Journal of Alloys and Compounds, 2025, 1030: 180834.
[26] JIANG B L, WANG Y M.Plasma Electrolytic Oxidation Treatment of Aluminium and Titanium Alloys[M]//Surface Engineering of Light Alloys. Amsterdam: Elsevier, 2010: 110-154.
[27] KASEEM M, AADIL M, THANAA T T, et al.Improving the Photocatalytic Performance of TiO₂ Coating via the Dual Incorporation of MoO₂ and V₂O₅ by Plasma Electrolytic Oxidation[J]. Surfaces and Interfaces, 2025, 56: 105558.
[28] KASEEM M, FATIMAH S, NASHRAH N, et al.Recent Progress in Surface Modification of Metals Coated by Plasma Electrolytic Oxidation: Principle, Structure, and Performance[J]. Progress in Materials Science, 2021, 117: 100735.
[29] YAO Z P, JIANG Y L, JIA F Z, et al.Growth Characteristics of Plasma Electrolytic Oxidation Ceramic Coatings on Ti-6Al-4V Alloy[J]. Applied Surface Science, 2008, 254(13): 4084-4091.
[30] 翟大军, 邱涛, 沈骏, 等. Ti-6Al-4V合金微弧氧化膜在磷酸盐/硅酸盐电解液中的生长动力学过程及其机理[J]. 矿物冶金与材料学报(英文版), 2022, 29(11): 1991-1999.
ZHAI D J, QIU T, SHEN J, et al.Growth Kinetics and Mechanism of Microarc Oxidation Coating on Ti-6Al-4V Alloy in Phosphate/Silicate Electrolyte[J]. International Journal of Minerals, Metallurgy and Materials, 2022, 29(11): 1991-1999.
[31] LI S J, HU J, CAO X M. Research on Growth Process and Microstructure of Microarc Oxidation Coating on Titanium[J]. Advanced Materials Research, 2011, 383/384/385/386/387/388/389/390: 1905-1909.
[32] KARBASI M, NIKOOMANZARI E, HOSSEINI R, et al.A Review on Plasma Electrolytic Oxidation Coatings for Organic Pollutant Degradation: How to Prepare Them and What to Expect of Them?[J]. Journal of Environmental Chemical Engineering, 2023, 11(3): 110027.
[33] WANG J T, PAN Y K, FENG R, et al.Effect of Electrolyte Composition on the Microstructure and Bio-Corrosion Behavior of Micro-Arc Oxidized Coatings on Biomedical Ti₆Al₄V Alloy[J]. Journal of Materials Research and Technology, 2020, 9(2): 1477-1490.
[34] VIJH A K.Sparking Voltages and Side Reactions during Anodization of Valve Metals in Terms of Electron Tunnelling[J]. Corrosion Science, 1971, 11(6): 411-417.
[35] VAN T B, Brown S D, Wirtz G P.Mechanism of Anodic Spark Deposition[J]. Am. Ceram. Soc. Bull.;(United States), 1977, 56(6): 563-566.
[36] IKONOPISOV S.Theory of Electrical Breakdown during Formation of Barrier Anodic Films[J]. Electrochimica Acta, 1977, 22(10): 1077-1082.
[37] ALBELLA J M, MONTERO I, MARTÍNEZ-DUART J M. Electron Injection and Avalanche during the Anodic Oxidation of Tantalum[J]. Journal of the Electrochemical Society, 1984, 131(5): 1101-1104.
[38] DITTRICH K H, KRYSMANN W, KURZE P, et al.Structure and Properties of ANOF Layers[J]. Crystal Research and Technology, 1984, 19(1): 93-99.
[39] YEROKHIN A L, SNIZHKO L O, GUREVINA N L, et al.Discharge Characterization in Plasma Electrolytic Oxidation of Aluminium[J]. Journal of Physics D: Applied Physics, 2003, 36(17): 2110.
[40] 王亚明. Ti₆Al₄V合金微弧氧化涂层的形成机制与摩擦学行为[D]. 哈尔滨: 哈尔滨工业大学, 2006.
WANG Y M.Formmation Mechanism and Tribological Behavior of Microarc Oxidation Coatings on Ti₆Al₄V Alloy[D]. Harbin: Harbin Institute of Technology, 2006.
[41] DUNLEAVY C S, GOLOSNOY I O, CURRAN J A, et al.Characterisation of Discharge Events during Plasma Electrolytic Oxidation[J]. Surface and Coatings Technology, 2009, 203(22): 3410-3419.
[42] LIU X J, LI G, XIA Y.Investigation of the Discharge Mechanism of Plasma Electrolytic Oxidation Using Ti Tracer[J]. Surface and Coatings Technology, 2012, 206(21): 4462-4465.
[43] NOMINÉ A, TROUGHTON S C, NOMINÉ A V, et al.High Speed Video Evidence for Localised Discharge Cascades during Plasma Electrolytic Oxidation[J]. Surface and Coatings Technology, 2015, 269: 125-130.
[44] ZHANG X, ALIASGHARI S, NĚMCOVÁ A, et al. X-Ray Computed Tomographic Investigation of the Porosity and Morphology of Plasma Electrolytic Oxidation Coatings[J]. ACS Applied Materials & Interfaces, 2016, 8(13): 8801-8810.
[45] PAVARINI M, MOSCATELLI M, CANDIANI G, et al.Influence of Frequency and Duty Cycle on the Properties of Antibacterial Borate-Based PEO Coatings on Titanium for Bone-Contact Applications[J]. Applied Surface Science, 2021, 567: 150811.
[46] ABBAS A, KUNG H P, LIN H C.Effects of Electrical Parameters on Micro-Arc Oxidation Coatings on Pure Titanium[J]. Micromachines, 2023, 14(10): 1950.
[47] BAYATI M R, GOLESTANI-FARD F, MOSHFEGH A Z, et al.In Situ Derivation of Sulfur Activated TiO₂ Nano Porous Layers through Pulse-Micro Arc Oxidation Technology[J]. Materials Research Bulletin, 2011, 46(10): 1642-1647.
[48] LEE Y K.Effects of Electrical Parameters on Titania Film Grown by Micro Arc Oxidation[J]. Modern Physics Letters B, 2009, 23(16): 2035-2040.
[49] NIKOOMANZARI E, FATTAH-ALHOSSEINI A, KARBASI M, et al.A Versatile TiO₂/ZrO₂ Nanocomposite Coating Produced on Ti-6Al-4V via Plasma Electrolytic Oxidation Process[J]. Surfaces and Interfaces, 2022, 32: 102128.
[50] TANG Y, YANG C P, SUN Q Q, et al.Effects of TiC Particles on Tribological and Corrosion Resistance of PEO Coating on TC4 Alloy[J]. Corrosion Communications, 2024, 14: 1-10.
[51] KHALAGHI M, RAEISSI K, NAHVI S M.Electrocatalytic Performance of Fluoride- and Antimony-Doped Tin Oxide Coatings Produced on Titanium Substrates Using Plasma Electrolytic Oxidation for the Electrochemical Degradation of Organic Contaminants in Water[J]. Surfaces and Interfaces, 2025, 74: 107737.
[52] QIAN W F, NING B K, WANG S, et al.Hierarchically Structured Ceramic Coatings Based on Zirconia and Magnesium Oxide with High Toughness[J]. Advanced Functional Materials, 2025, 35(14): 2418312.
[53] LI L, NING B K, MAO Y M, et al.Synthesis of Bioinspired Gradient MoS₂/TiO₂ Coatings for Enhancing Tribological Performance of Titanium Alloys[J]. Applied Surface Science, 2025, 679: 161296.
[54] 郭豫鹏, 李鑫, 潘墨儒, 等. 微弧氧化高低频耦合脉冲对TiO₂膜层组织和性能的影响[J]. 稀有金属材料与工程, 2024, 53(11): 3233-3240.
GUO Y P, LI X, PAN M R, et al.Effect of High and Low-Frequency Coupled Pulse of Micro-Arc Oxidation on Microstructure and Properties of TiO₂ Coatings[J]. Rare Metal Materials and Engineering, 2024, 53(11): 3233-3240.
[55] VENKATESWARLU K, RAMESHBABU N, SREEKANTH D, et al.Role of Electrolyte Chemistry on Electronic and in Vitro Electrochemical Properties of Micro-Arc Oxidized Titania Films on Cp Ti[J]. Electrochimica Acta, 2013, 105: 468-480.
[56] 李帅康, 宁炳坤, 钱伟峰, 等. 高温下钛合金表面WO₃/TiO₂非晶复合膜层的摩擦磨损行为[J]. 中国有色金属学报, 2025, 35(11): 3821-3835.
LI S K, NING B K, QIAN W F, et al.Friction and Wear Behavior of WO₃/TiO₂ Amorphous Composite Coating on Titanium Alloy Surface at High Temperature[J]. The Chinese Journal of Nonferrous Metals, 2025, 35(11): 3821-3835.
[57] LI Q B, YANG W B, LIU C C, et al.Correlations between the Growth Mechanism and Properties of Micro-Arc Oxidation Coatings on Titanium Alloy: Effects of Electrolytes[J]. Surface and Coatings Technology, 2017, 316: 162-170.
[58] WU T, BLAWERT C, SERDECHNOVA M, et al.Role of Phosphate, Silicate and Aluminate in the Electrolytes on PEO Coating Formation and Properties of Coated Ti₆Al₄V Alloy[J]. Applied Surface Science, 2022, 595: 153523.
[59] 邵珠倩, 马颖, 欧凯奇, 等. 基于配方均匀试验研究TC4钛合金表面磷酸盐系微弧氧化膜层的性能[J]. 电镀与涂饰, 2025, 44(9): 10-20.
SHAO Z Q, MA Y, OU K Q, et al.Properties of Phosphate-Based Micro-Arc Oxidation Coatings on TC4 Titanium Alloy via Mixture Uniform Design[J]. Electroplating & Finishing, 2025, 44(9): 10-20.
[60] 张云龙, 董鑫焱, 翟梓棫, 等. Er₂O₃微粒掺杂对TC4钛合金微弧氧化涂层组织和耐磨性的影响[J]. 稀有金属, 2024, 48(8): 1120-1131.
ZHANG Y L, DONG X Y, ZHAI Z Y, et al.Microstructure and Wear Resistance of MAO Coatings of TC4 Alloy with Different Er₂O₃ Doping Amounts[J]. Chinese Journal of Rare Metals, 2024, 48(8): 1120-1131.
[61] GUO Z W, YANG Z H, CHEN Y N, et al.One-Step Plasma Electrolytic Oxidation with Graphene Oxide for Ultra-Low Porosity Corrosion-Resistant TiO₂ Coatings[J]. Applied Surface Science, 2022, 594: 153477.
[62] SHI L, JIANG C P, ZHAO R Y, et al.Effect of Al₂O₃ Nanoparticles Additions on Wear Resistance of Plasma Electrolytic Oxidation Coatings on TC4 Alloys[J]. Ceramics International, 2024, 50(11): 18484-18496.
[63] GREBNEVS V, DULSKI M, HUSAK Y, et al.Advancements in Plasma Electrolytic Oxidation with Particle Suspensions: A Novel Approach for the Direct Incorporation of Calcium Carbonate[J]. Applied Surface Science, 2025, 713: 164360.
[64] XI F Q, ZHANG X W, JIANG X Y, et al.Growth Mechanism of Oxide Layer on Ti-6Al-4 V Substrate with Different Surface Topographies during the Early Stage of Micro-Arc Oxidation[J]. Surface and Coatings Technology, 2023, 467: 129685.
[65] XU L, WU C, LEI X C, et al.Effect of Oxidation Time on Cytocompatibility of Ultrafine-Grained Pure Ti in Micro- Arc Oxidation Treatment[J]. Surface and Coatings Technology, 2018, 342: 12-22.
[66] YANG C, CUI S H, WU Z C, et al.High Efficient Co-Doping in Plasma Electrolytic Oxidation to Obtain Long-Term Self-Lubrication on Ti₆Al₄V[J]. Tribology International, 2021, 160: 107018.
[67] 齐玉明, 彭振军, 刘百幸, 等. 钛合金表面高硬度微弧氧化膜的制备和耐磨性研究[J]. 表面技术, 2019, 48(7): 81-88.
QI Y M, PENG Z J, LIU B X, et al.Fabrication and Wear Resistance of Hard Micro Arc Oxidation Coatings on Ti Alloys[J]. Surface Technology, 2019, 48(7): 81-88.
[68] 祝存款, 张明远, 王守仁, 等. 微弧氧化对Ti₆Al₄V钛合金在高温域(300 ℃)下的微动磨损行为影响研究[J]. 材料保护, 2025, 58(7): 75-84.
ZHU C K, ZHANG M Y, WANG S R, et al.Effect of Micro-Arc Oxidation on Fretting Wear Behavior of Ti₆Al₄V Titanium Alloy in High-Temperature (300 ℃) Range[J]. Materials Protection, 2025, 58(7): 75-84.
[69] SHARIFI H, ALIOFKHAZRAEI M, DARBAND G B, et al.Tribological Properties of PEO Nanocomposite Coatings on Titanium Formed in Electrolyte Containing Ketoconazole[J]. Tribology International, 2016, 102: 463-471.
[70] ALIASGHARI S, SKELDON P, THOMPSON G E.Plasma Electrolytic Oxidation of Titanium in a Phosphate/Silicate Electrolyte and Tribological Performance of the Coatings[J]. Applied Surface Science, 2014, 316: 463-476.
[71] ZHAO X R, CHEN Y Z, JI R N, et al.TiO₂-hBN Nanocomposite Coating with Excellent Wear and Corrosion Resistance on Ti₆Al₄V Alloy Prepared by Plasma Electrolytic Oxidation[J]. Surface and Coatings Technology, 2024, 494: 131471.
[72] LIU A, GAO S, DU S, et al.Enhancing PEO Coating on TC6 Alloy through In-Situ Synthesis of MoSe₂—Towards More Efficient Wear-Reducing Lubrication and Wear Resistance[J]. Tribology International, 2024, 193: 109409.
[73] MOLAEIPOUR P, ALLAHKARAM S R, AKBARZADEH S.Corrosion Inhibition of Ti₆Al₄V Alloy by a Protective Plasma Electrolytic Oxidation Coating Modified with Boron Carbide Nanoparticles[J]. Surface and Coatings Technology, 2022, 430: 127987.
[74] JIN F Y, CHU P K, WANG K, et al.Thermal Stability of Titania Films Prepared on Titanium by Micro-Arc Oxidation[J]. Materials Science and Engineering: A, 2008, 476(1/2): 78-82.
[75] NING B K, QIAN W F, YANG Z H, et al.Long-Term Anti-Friction Gradient Coating on Titanium Alloys by Plasma Electrolytic Oxidation with Efficient Strain Transfer[J]. Materials Research Letters, 2025, 13(3): 264-273.
[76] WANG S Q, WANG Y M, CUI Y, et al.High Voltage Resistance Ceramic Coating Fabricated on Titanium Alloy for Insulation Shielding Application[J]. Ceramics International, 2019, 45(2): 1909-1917.
[77] LI H M, ZHANG M, WU X W, et al.Effect of Electrical Modes on Dielectric and Insulation Properties of Plasma Electrolytic Oxidation Ceramic Films on Al[J]. Surface and Coatings Technology, 2024, 485: 130881.
[78] ZHANG J H, ZUO S H, CHENG F, et al.Effective Combined Treatments of Micro-Arc Oxidation and Resin Pre-Coating on Ti-6Al-4V Substrate: Constructing Epoxy Micro-Anchor Bolts for Bonding Strength Improvement of Ti-6Al-4V/CFRP Joint[J]. Surface and Coatings Technology, 2025, 515: 132594.
[79] LU H L, ZHU Z Q, LI S B, et al.Study on the Synergistic Modification of Aluminum Alloy Surface Properties by Robotic Arm-Assisted Laser Texturing and Scanning Micro-Arc Oxidation[J]. Surface and Coatings Technology, 2025, 512: 132377.
[80] 黄云, 黄建超, 肖贵坚, 等. 超疏水表面加工技术及耐磨性能研究进展[J]. 中国机械工程, 2024, 35(1): 2-26.
HUANG Y, HUANG J C, XIAO G J, et al.Research Progresses of Superhydrophobic Surface Processing Technology and Abrasion Resistance[J]. China Mechanical Engineering, 2024, 35(1): 2-26.
[81] HU Y Z, WANG H S, WANG D H, et al.High- Performance Bioceramic Coatings of 3D Printed Titanium Alloys via FS-Auxiliary Micro-Arc Oxidation Manufacturing[J]. Journal of Manufacturing Processes, 2024, 119: 337-347.
[82] FAN C Y, SHI W Q, LIN F, et al.Impact of Picosecond Laser Surface Texturing on the Microstructure and Corrosion Resistance of Micro-Arc Oxidation Coating on Ti-6Al-4V Alloy[J]. Surface and Coatings Technology, 2025, 513: 132445.
[83] WU G L, ZHU L B, CHEN X H, et al.Growth Characteristics and Wear Properties of Micro-Arc Oxidation Coating on Ti-6Al-4V with Different Laser Texture Shapes[J]. Surface and Coatings Technology, 2023, 475: 130108.
[84] WANG S X, YU T J, PANG Z W, et al.Improving the Fatigue Resistance of Plasma Electrolytic Oxidation Coated Titanium Alloy by Ultrasonic Surface Rolling Pretreatment[J]. International Journal of Fatigue, 2024, 181: 108157.
[85] 罗军明, 陈宇海, 黄俊, 等. 喷丸处理和微弧氧化对TC4合金组织和疲劳性能的影响[J]. 中国有色金属学报, 2019, 29(6): 1210-1218.
LUO J M, CHEN Y H, HUANG J, et al.Effect of Shot Peening and Micro-Arc Oxidation on Microstructure and Fatigue Properties of TC4 Titanium Alloy[J]. The Chinese Journal of Nonferrous Metals, 2019, 29(6): 1210-1218.
[86] WEI X W, HUANG H J, SUN M X, et al.Effects of Honeycomb Pretreatment on MAO Coating Fabricated on Aluminum[J]. Surface and Coatings Technology, 2019, 363: 265-272.
[87] 顾艳红, 马慧娟, 陈玲玲, 等. Ti₆Al₄V钛合金超声波冷锻/微弧氧化涂层的制备及耐磨性能[J]. 中国表面工程, 2016, 29(1): 87-95.
GU Y H, MA H J, CHEN L L, et al.Wear Resistance of MAO Coated Ti₆Al₄V Alloy Prepared by Ultrasonic Cold Forging Technology[J]. China Surface Engineering, 2016, 29(1): 87-95.
[88] 唐伟清, 罗军明, 陈宇海, 等. TC4钛合金表面激光冲击强化-微弧氧化涂层的组织和性能[J]. 材料热处理学报, 2023, 44(3): 144-151.
TANG W Q, LUO J M, CHEN Y H, et al.Microstructure and Properties of Laser Shock Strengthened Micro Arc Oxidation Coating on TC4 Titanium Alloy Surface[J]. Transactions of Materials and Heat Treatment, 2023, 44(3): 144-151.
[89] KAZEK-KĘSIK A, KROK-BORKOWICZ M, DERCZ G, et al. Multilayer Coatings Formed on Titanium Alloy Surfaces by Plasma Electrolytic Oxidation-Electrophoretic Deposition Methods[J]. Electrochimica Acta, 2016, 204: 294-306.
[90] 杨嘉乐, 徐立新, 李东山, 等. 微弧预氧化对Ti₆Al₄V钛合金低温等离子体氮化层耐磨耐蚀性的影响[J]. 材料保护, 2025, 58(6): 102-115.
YANG J L, XU L X, LI D S, et al.Effect of Micro-Arc Pre-Oxidation on Wear and Corrosion Resistance of Low- Temperature Plasma Nitrided Layer on Ti₆Al₄V Titanium Alloy[J]. Materials Protection, 2025, 58(6): 102-115.
[91] FAN Z S, LU H L, LIU P, et al.Growth Mechanism and Performance of MAO-AO Composite Coating Obtained by Two-Stage Process[J]. Ceramics International, 2024, 50(22): 44993-45005.
[92] WANG G Q, LI J K, CHENG Q, et al.Hierarchical MAO-Diamond Coating for Titanium Alloys: Enhancing Tribological Performance through Experimental and Atomistic Insights[J]. Applied Surface Science, 2025, 714: 164393.
[93] MASHTALYAR D V, NADARAIA K V, IMSHINETSKIY I M, et al.Composite Coatings Formed on Ti by PEO and Fluoropolymer Treatment[J]. Applied Surface Science, 2021, 536: 147976.
[94] JIN J, LI X H, WU J W, et al.Improving Tribological and Corrosion Resistance of Ti₆Al₄V Alloy by Hybrid Microarc Oxidation/Enameling Treatments[J]. Rare Metals, 2018, 37(1): 26-34.
[95] AKBARZADEH S, PAINT Y, OLIVIER M G.A Comparative Study of Different Sol-Gel Coatings for Sealing the Plasma Electrolytic Oxidation (PEO) Layer on AA2024 Alloy[J]. Electrochimica Acta, 2023, 443: 141930.
[96] 徐明波, 黄小波, 高玉魁. 锆合金微弧氧化后喷丸致密化研究[J]. 表面技术, 2020, 49(4): 238-244.
XU M B, HUANG X B, GAO Y K.Investigation on Shot Peening Treatment of ZIRLO Alloy after MAO[J]. Surface Technology, 2020, 49(4): 238-244.
[97] WANG Y, PENG Q D, WU G L, et al.Effect of Auxiliary Laser Irradiation on Characteristics and Properties of Micro-Arc Oxidation Coating on Ti₆Al₄V Alloy[J]. Ceramics International, 2024, 50(11): 19412-19423.
[98] KOMAROVA E G, AKIMOVA E B, KAZANTSEVA E A, et al.Effect of Ultrasonic Power Applied to Micro-Arc Oxidation on the Morphology, Chemistry, Wettability and Electrical Properties of Calcium Phosphate Coatings on Titanium[J]. Journal of Alloys and Compounds, 2025, 1039: 183056.
[99] XU W K, LIU Z D, LI B, et al.Effects of Magnetic Field Force in Preparation of Plasma Electrolytic Oxidation Coatings: A Novel Method to Improve the Corrosion Resistance of Magnesium[J]. Journal of Alloys and Compounds, 2022, 906: 162642.
[100] WANG Y, HU Z X, WU G L, et al.Effect of Laser Power on the Microstructure and Wear Resistance of TiO₂-SiO₂ Ceramic Coating by Laser-Assisted Micro-Arc Oxidation on Ti₆Al₄V Alloy[J]. Surface and Coatings Technology, 2025, 497: 131764.
[101] 吴国龙, 陈祥辉, 王晔, 等. 激光同步复合微弧氧化制备TiO_2/ZrO_2涂层的特性及性能研究[J]. 表面技术, 2025, 54(15): 176-188.
WU G L, CHEN X H, WANG Y, et al.Properties and Performance of TiO₂/ZrO₂ Coatings Prepared by Laser- Assisted Micro-Arc Oxidation[J]. Surface Technology, 2025, 54(15): 176-188.
[102] ZHANG X X, ZHANG T, LV Y, et al.Enhanced Uniformity, Corrosion Resistance and Biological Performance of Cu-Incorporated TiO₂ Coating Produced by Ultrasound-Auxiliary Micro-Arc Oxidation[J]. Applied Surface Science, 2021, 569: 150932.
[103] ZONG B T, LI J S, WANG P, et al.Spatiotemporal Microstructure Evolution during Martensitic Transformation in Titanium Alloys Using Deep Learning[J]. Acta Materialia, 2025, 301: 121603.
[104] WANG P, JIANG Y, LIAO W J, et al.Generalizable Descriptors for Automatic Titanium Alloys Design by Learning from Texts via Large Language Model[J]. Acta Materialia, 2025, 296: 121275.