摘要
目的 在镁合金上堆焊Al-Si合金涂层,分析Mg/Al界面处过渡区的组织、成分与形成过程。方法 采用低成本、高效的直流脉冲熔化极气体保护焊(DC-PMIG welding),在低热输入下将ER4043(AlSi5)焊丝堆焊到AZ91D镁合金表面,形成Al-Si合金涂层。采用金相显微镜、扫描电镜、能谱仪、X射线衍射仪分析Mg/Al过渡区的微观组织,讨论过渡区的组织、成分,并分析其形成过程与机理。结果 过渡区分为两部分。区域I的主要成分依次为Mg+Al12Mg17、Al12Mg17、Al12Mg17+Al3Mg2和Al3Mg2,不规则块状Mg2Si相弥散分布于其中。区域II的主要成分为柱状α-Al,表面析出了大量点状Al3Mg2,α-Al柱状晶晶界处存在黑色点状Mg2Si。结论 直流脉冲熔化极气体保护焊能够在AZ91D镁合金表面制备Al-Si合金涂层,基体与涂层之间存在过渡区,过渡区中不同位置的镁、铝相对含量不同,成分也不相同。区域I与区域II中Mg2Si不同的析出顺序,使其微观结构不同:Mg2Si在镁含量相对较多的区域I中优先析出并长大,形成块状Mg2Si;而区域II中率先析出α-Al,随后在α-Al晶界处形成了黑色点状Mg2Si。
Abstract
The work aims to overlayAl-Si alloy coating on magnesium alloy, and analyze microstructure, composition and formation process of the transition zone on Al/Mg interface. A low-cost high-efficiency production process-direct current (DC) pulse metal inert gas (PMIG) shielded welding was used to deposit Al-Si alloy coating on AZ91D magnesium alloy using ER4043 wires (AlSi5). Microstructure, morphology and composition of the Mg/Al transition zone were measured with metallurgical microscope, scanning electron microscope, energy-dispersive spectrometer (EDS) and X-ray diffractometer(XRD). Formation process and composition of the transition zone were analyzedas well. The transition zone consisted of two regions. Region I was made up of Mg+Al12Mg17, Al12Mg17, Al12Mg17+Al3Mg2 and Al3Mg2, respectively. Irregular massive Mg2Si phase was dispersed in region I. The region II was mainly made up of columnar α-Al, with plenty of precipitated dotted Al3Mg2, and there was black dotted Mg2Si on grain boundary of columnar α-Al. Direct current pulse metal inert gas shielded welding can be used to prepare Al-Si coating on AZ91D magnesium alloy. There is a transition zone between substrate and coating. Relative Mg and Al content and composition are differentin positions of the transition zone.The precipitation of Mg2Si in region I and region II was different, which explained the different morphology. Mg2Si preferentially precipitated and grew tomassive Mg2Si in region I with relatively high magnesium content, while α-Al precipitated first in region II, and subsequently forms black dotted Mg2Si on grain boundary of α-Al.
关键词
AZ91D镁合金;ER4043焊丝;DC-PMIG堆焊;金属间化合物;微观组织
Key words
AZ91D magnesium alloy; ER4043 welding wire; DC-PMIG surfacing; intermetallic compound; microstructure
刘车凯, 李志勇, 裴小龙, 杨柳青, 薛铜辉, 仁杰亮.
AZ91D镁合金表面堆焊Al-Si合金涂层微观组织及分析[J]. 表面技术. 2018, 47(4): 172-176
LIU Che-kai, LI Zhi-yong, PEI Xiao-long, YANG Liu-qing, XUE Tong-hui, REN Jie-liang.
Microstructure and Analysis of Surfacing Al-Si Coating on AZ91D Magnesium Alloy[J]. Surface Technology. 2018, 47(4): 172-176
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基金
山西省重点研发计划工业项目(201603D121002-1);山西省自然科学基金(2012011021-1);山西省回国留学人员科研基金资助项目(2013-07)