In-situ Fabrication of Self-collected Ni(OH) 2 Supercapacitor Electrode Materials by Hydrothermal Treatment of Ni Foam in H2O2 Solution

GE Meng-qi, ZHANG Jie, XU Jing, LEI Jing-lei, LI Ling-jie

Surface Technology ›› 2015, Vol. 44 ›› Issue (1) : 47-50,63.

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PDF(1668 KB)
Surface Technology ›› 2015, Vol. 44 ›› Issue (1) : 47-50,63.

In-situ Fabrication of Self-collected Ni(OH) 2 Supercapacitor Electrode Materials by Hydrothermal Treatment of Ni Foam in H2O2 Solution

  • GE Meng-qi, ZHANG Jie, XU Jing, LEI Jing-lei, LI Ling-jie
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Abstract

Objective To in-situ fabricate self-collected Ni(OH)2 supercapacitor electrode materials with excellent capacitance and good cycle stability by a facile, cost-effective and green method. Methods The hydrothermal treatment of Ni foam was performed in a 15wt. % H2O2 solution at 180 ℃ for 24 h to in-situ fabricate Ni(OH)2. The morphologies, phase composition and electrochemical performance of the as-prepared Ni(OH)2 electrode material were characterized. Results The β-Ni(OH)2 hexagonal platelets with the side lengths of 400 ~600 nm and the thickness of ~200 nm were obliquely laid on the Ni foam at high densities. The electrode demonstrated excellent capacitance (2534 F/ g at a scan rate of 1 mV/ s) and good cycling stability (91% capacitance retention after 1000 cycles at a scan rate of 50 mV / s) in 2 mol / L KOH aqueous solution. Conclusion The fabrication method developed here was facile, cost-effective and green. The as-prepared binder-free, self-collected electrode material exhibited remarkable electrochemical performance with high specific capacity and good cycling stability.

Key words

Ni(OH) 2 ;hydrothermal method; in-situ fabrication; supercapacitor

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GE Meng-qi, ZHANG Jie, XU Jing, LEI Jing-lei, LI Ling-jie. In-situ Fabrication of Self-collected Ni(OH) 2 Supercapacitor Electrode Materials by Hydrothermal Treatment of Ni Foam in H2O2 Solution[J]. Surface Technology. 2015, 44(1): 47-50,63

Funding

Supported by the Natural Science Foundation of CQ (CSTC2011AB4056) and the Fundamental Research Funds for the Central Universities (CD-JZR13225501, CDJZR14228801, CDJXS12221102)
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