Research on the Behavior of Dicyandiamide Modified by Bisphenol-A Type Phenolic Aldehyde Curing Epoxy Resin

TANG Nan, YANG You-hua, DENG Jing-wei, ZHOU Jian-ping, LIU Zhi-lei, LIU Guang-ming

Surface Technology ›› 2014, Vol. 43 ›› Issue (6) : 144-148.

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Surface Technology ›› 2014, Vol. 43 ›› Issue (6) : 144-148.

Research on the Behavior of Dicyandiamide Modified by Bisphenol-A Type Phenolic Aldehyde Curing Epoxy Resin

  • TANG Nan1, YANG You-hua1, DENG Jing-wei1, ZHOU Jian-ping2, LIU Zhi-lei2, LIU Guang-ming2
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Abstract

Objective To obtain a latent, low-temperature and fast curing dicyandiamide agent. Methods A new latent curing agent of dicyandiamide modified by bisphenol A type phenolic aldehyde resin was synthesized and the structure was characterized by FTIR spectra. The impact of dicyandiamide dosage on product performance was investigated. The activity of the modified curing a- gent, the dosage and the curing temperature were studied with differential scanning calorimetry (DSC). Results The results showed that the suitable molar ratio of dicyandiamide and phenolic aldehyde was 0. 6 : 1, the optimal dosage of the modified curing agent was 30% (relative to the epoxy resin mass fraction), and the constant curing temperature after modification was 127 ℃. Conclu- sions The resulting curing agent of bisphenol A phenolic resin modified dicyandiamide exhibited the best comprehensive perform- ances.

Key words

phenolic aldehyde; dicyandiamide; latent curing agent; modification

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TANG Nan, YANG You-hua, DENG Jing-wei, ZHOU Jian-ping, LIU Zhi-lei, LIU Guang-ming. Research on the Behavior of Dicyandiamide Modified by Bisphenol-A Type Phenolic Aldehyde Curing Epoxy Resin[J]. Surface Technology. 2014, 43(6): 144-148

Funding

Supported by State Grid Practical Project(521820130014)
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