The curing behavior of polyether amine / phenolic amine with epoxy resin was studied by different scanning calorimetry. The kinetics parameters of this system were analyzed at heating rates 5 ,10 ,15 and 20 ℃ / min from 25 ℃ to 230 ℃ . According to Kissinger equation, the apparent activation energy was 61 . 76 kJ / mol and frequence factor was 7 . 1 X10⁷s^-1.According to Crane equation, the order of reaction was 1. 116, and the kinetics equation of curing reation was found to be dα/dt=k(1-α)^1.116, k = 7 . 1 X10⁷exp (-7429 / T) .