Ru-Ir-Sn-Ti oxideanode coating were prepared by sol-gel method, and the electrochemical property and durability of the anode coating were investigated by oxygen evolution potential, chlorine evolution potential, cyclic voltammetry curve, polarization curve, electrochemical impedance and accelerated lifetime and compared with oxide anode coating prepared by thermal decomposition method. The results show that anode coating prepared by sol-gel method have lower chlorine evolution potential, higher oxygen evolution potential, longer accelerated lifetime and better electro-catalytic activity than metal oxide anodes coating prepared by thermal decomposition method.