Surface Quality of TC4 Machining Based on Synergistic Regulation by Surface Modification and Micro-texture Technology

TONG Xin, WANG Baiyi, YANG Shucai, LIU Feng, ZHANG Jinwei

Surface Technology ›› 2026, Vol. 55 ›› Issue (16) : 54-65.

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Surface Technology ›› 2026, Vol. 55 ›› Issue (16) : 54-65. DOI: 10.16490/j.cnki.issn.1001-3660.2026.16.005
Special Topic—Precision Machining of Difficult-to-Machine Materials

Surface Quality of TC4 Machining Based on Synergistic Regulation by Surface Modification and Micro-texture Technology

  • TONG Xin, WANG Baiyi, YANG Shucai*, LIU Feng, ZHANG Jinwei
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Abstract

TC4 titanium alloy is widely used in high-end manufacturing fields such as aerospace and marine equipment due to its low density, high specific strength and excellent corrosion resistance. However, the material features low thermal conductivity and strong chemical activity. When machined by ball-end milling cutters, severe tool-workpiece interfacial adhesion, high cutting loads, obvious machining vibration and unstable surface quality frequently occur, which greatly restricts its high-efficiency and precision machining. To address the above processing challenges, the work aims to propose a synergistic regulation method combining workpiece surface modification and micro-textured ball-end milling cutters. By optimizing the friction, adhesion and contact state of the cutting interface from both the workpiece substrate and cutting tool sides, the milling stability and machined surface quality of TC4 titanium alloy were effectively improved. Three surface treatment processes, namely chemical medium modification, pulsed ion sulfurization modification and active medium coating modification, were adopted to treat TC4 titanium alloy. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) were employed to characterize the microscopic morphology and elemental distribution of different modified layers. Combined with 75 consecutive milling force tests, the effects of various modification methods on cutting interface behaviors and the evolution of milling force were systematically investigated. The experimental results showed that the average milling force of unmodified TC4 titanium alloy after 75 machining cycles was 162.54 N. After chemical medium modification and pulsed ion sulfurization modification, micron-scale corrosion pits and sulfur-rich lubricating layers were formed on the workpiece surface respectively. The average milling forces decreased to 145.25 N and 143.73 N, with reduction rates of 10.64% and 11.57% in comparison with the base material. Through graphene coating modification, a continuous two-dimensional layered lubricating film formed on the titanium alloy surface, which isolated the direct contact between tool and workpiece and delivered outstanding friction reduction via interlayer sliding. It achieved the optimal force reduction effect, with an average milling force of only 140.17 N and a reduction of 13.76% relative to the unmodified specimens. On the basis of the optimized graphene-coated workpieces, orthogonal milling tests were carried out with micro-textured ball-end milling cutters. The effects of texture diameter, texture spacing, laser power, scanning speed and scanning times on the machined surface quality were emphatically analyzed. The research revealed that the micro-textures on the tool surface could store lubricating medium, accommodate fine wear debris and reduce the contact area between tools and chips, forming a favorable synergistic effect with the graphene modified layer. Within the range of selected parameters in this experiment, the minimum surface roughness of the machined workpiece reached 0.279 μm. Mechanism analysis indicated that workpiece surface modification could effectively weaken interfacial adhesion and reduce frictional resistance between tool and workpiece, while tool micro-textures further optimized the tool-chip contact mode and improved the retention condition of lubricating medium. The synergistic effect of the two technologies can significantly suppress the fluctuation of milling force, alleviate surface scratching and adhesive damage, and comprehensively improve the overall machining performance of TC4 titanium alloy during ball-end milling. This work provides a feasible technical solution and experimental reference for the low-load and high-quality cutting of difficult-to- machine titanium alloys.

Key words

TC4 titanium alloy / surface modification / micro-texture / graphene coating / milling force / interface friction reduction / surface quality

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TONG Xin, WANG Baiyi, YANG Shucai, LIU Feng, ZHANG Jinwei. Surface Quality of TC4 Machining Based on Synergistic Regulation by Surface Modification and Micro-texture Technology[J]. Surface Technology. 2026, 55(16): 54-65

References

[1] 李安海, 张茹凤, 赵军, 等. 基于净切削比能的钛合金清洁切削加工表面完整性研究[J]. 表面技术, 2023, 52(12): 57-64.
LI A H, ZHANG R F, ZHAO J, et al.Surface Integrity of Clean Machined Titanium Alloy Based on Net Specific Cutting Energy[J]. Surface Technology, 2023, 52(12): 57-64.
[2] 王慧, 李南奇, 赵国超, 等. 基于航空铸造钛合金Ti-6Al-4V高速铣削参数的表面质量及切削效率优化[J]. 表面技术, 2022, 51(2): 331-337.
WANG H, LI N Q, ZHAO G C, et al.Optimization of Surface Quality and Cutting Efficiency for High-Speed Milling Parameters of Titanium Alloy Ti-6Al-4V for Aviation Casting[J]. Surface Technology, 2022, 51(2): 331-337.
[3] YOU L M, PENG D Q, ZHOU L Y, et al.Acid Pickling Process of Titanium Alloys and Its Investigation of Intergranular Corrosion and Pitting Corrosion[C]// Proceedings of the 2015 6th International Conference on Manufacturing Science and Engineering. Qingdao, China. Atlantis Press, 2015: 1 652-1 656.
[4] 林翠, 胡舸, 梁静, 等. TC1和TC4钛合金腐蚀加工溶解行为研究[J]. 航空材料学报, 2010(6): 43-50.
LIN C, HU G, LIANG J, et al.Dissolution Behavior of Corrosion Processing for TC1 and TC4 Titanium Alloy[J]. Journal of Aeronautical Materials, 2010(6): 43-50.
[5] 高发, 李文辉, 郭策, 等. TC4钛合金HF-HNO3化学抛光的表面质量和元素机理分析[J]. 现代制造工程, 2023(4): 103-109.
GAO F, LI W H, GUO C, et al.Surface Quality and Elemental Mechanism Analysis of HF-HNO3 Chemical Polishing of TC4 Titanium Alloy[J]. Modern Manufacturing Engineering, 2023(4): 103-109.
[6] 赵国龙, 冒鹏程, 杜亚男, 等. 激光诱导氧化辅助微细铣削TA19钛合金高深宽比微结构的研究[J]. 表面技术, 2021, 50(6): 317-326.
ZHAO G L, MAO P C, DU Y N, et al.Fabrication of High Aspect Ratio Feature on TA19 Titanium Alloy with Laser-Induced Oxidation Assisted Micro-Milling[J]. Surface Technology, 2021, 50(6): 317-326.
[7] 雍青松, 马国政, 王海斗, 等. 低温离子渗硫技术的发展历程和研究应用现状[J]. 材料导报, 2016, 30(17): 115-119.
YONG Q S, MA G Z, WANG H D, et al.Development and Application Status of Low-Temperature Ion Sulfurizing Technology[J]. Materials Review, 2016, 30(17): 115-119.
[8] 田晓东, 王利捷, 郑文鹏. TC4钛合金表面辉光离子渗Mo渗S复合处理涂层的组织和摩擦学性能[J]. 表面技术, 2013, 42(2): 4-6.
TIAN X D, WANG L J, ZHENG W P.Microstructure and Tribological Properties of Coatings Prepared by Glow Plasma Deposition Mo and S on TC4 Titanium Alloy[J]. Surface Technology, 2013, 42(2): 4-6.
[9] SHCHUKIN E D. The Influence of Surface-Active Media on the Mechanical Properties of Materials[J]. Advances in Colloid and Interface Science, 2006, 123/124/125/126: 33-47.
[10] 王伟, 彭怡晴, 丁士杰, 等. Ti-6Al-4V合金表面石墨基粘结固体润滑涂层的高温摩擦学性能[J]. 材料研究学报, 2023, 37(6): 432-442.
WANG W, PENG Y Q, DING S J, et al.Tribological Properties of Graphite-Based Solid Lubricating Coatings for Ti-6Al-4V Alloy at 500-800 ℃[J]. Chinese Journal of Materials Research, 2023, 37(6): 432-442.
[11] 孟君晟, 李成硕, 弭德振, 等. TC4合金表面熔覆石墨烯增强钛基复合涂层的组织及性能[J]. 表面技术, 2021, 50(4): 79-85.
MENG J S, LI C S, MI D Z, et al.Structure and Properties of Graphene Reinforced Ti-based Composite Coatings on TC4 Alloy[J]. Surface Technology, 2021, 50(4): 79-85.
[12] 刘伟, 刘顺, 梁桂强, 等. 微织构刀具切削性能及减摩效果的仿真分析[J]. 表面技术, 2022, 51(2): 338-346.
LIU W, LIU S, LIANG G Q, et al.Finite Element Analysis on Cutting Performance and Friction Reduction Effect of Micro-Texture Tools[J]. Surface Technology, 2022, 51(2): 338-346.
[13] 李文轩, 段海涛, 李国政, 等. 激光表面织构技术调控材料摩擦学性能的研究进展[J]. 表面技术, 2024, 53(9): 85-101.
LI W X, DUAN H T, LI G Z, et al.Research Progress in Controlling Material Tribological Properties by Laser Surface Texture Technology[J]. Surface Technology, 2024, 53(9): 85-101.
[14] 刘朝伟, 杨发展, 姜芙林, 等. 微量润滑工况下纳米粒子协同微织构对刀具切削性能的影响[J]. 表面技术, 2024, 53(10): 183-195.
LIU (C /Z)W, YANG F Z, JIANG F L, et al. Synergistic Effect of Nano Particles and Micro-Texture on Tool Cutting Performance under Micro Lubrication Conditions[J]. Surface Technology, 2024, 53(10): 183-195.
[15] 李婧, 杨发展, 姜芙林, 等. 特斯拉阀微织构对YG8N刀具切削性能的提升机制研究[J]. 表面技术, 2025, 54(24): 207-219.
LI J, YANG F Z, JIANG F L, et al.Mechanism of Cutting Performance Enhancement of YG8N Tools by Tesla Valve Micro-Texturing[J]. Surface Technology, 2025, 54(24): 207-219.
[16] YANG S C, LIU L K, HE C S.Study on Milling Behavior of TiAlN Coated Tool with Variable Distribution Density Micro-Texture[J]. Machining Science and Technology, 2024, 28(1): 74-97.
[17] TANG S W, LIU P F, SU Z, et al.Preparation and Cutting Performance of Nano-Scaled Al2O3-Coated Micro-Textured Cutting Tool Prepared by Atomic Layer Deposition[J]. High Temperature Materials and Processes, 2021, 40(1): 77-86.
[18] LI Q H, MA C L, XIE L T, et al.Effect of Coated Composite Micro-Texture Tool on Cutting Shape and Cutting Force during Aluminum Alloy Cutting[J]. Machines, 2023, 11(4): 439.
[19] XU T T, SHI H, WANG B Z, et al.Research on Machinability of Dry Cutting 7075 Aluminum Alloy with TiN Coating Micro-Texture Turning Tool[J]. Journal of Nanoelectronics and Optoelectronics, 2024, 19(3): 284-292.
[20] ZHOU L, ZOU P, REN B Y, et al.Influence of Tool Micro-Texturing and AlCrN Coating on Cutting Performance in Dry Turning AISI 304[J]. The International Journal of Advanced Manufacturing Technology, 2024, 130(7): 3945-3965.
[21] LI Q H, MA C L, WANG C Y, et al.Analysis of the Cutting Performance of Coated Micro-Textured Bionic Tools for Dry Cutting AISI 52100[J]. Machines, 2023, 11(9): 886.
[22] WANG Z, LI Y, WANG S, et al.Feasibility and Mechanism of Atmospheric Pressure Cold Plasma Jet (APCPJ) Assisted Micro-milling of Bulk Metallic Glasses (BMGs)[J]. Ceramics International, 2024, 50(7): 11094-11105.
[23] 王红波. 离子渗氮—渗硫复合处理对Ti-6Al-4V合金摩擦学性能的影响[D]. 西安: 长安大学, 2009.
WANG H B.Effect of ion nitriding-sulfurizing composite treatment on tribological behavior of Ti-6Al-4V[D]. Xi'an: Changan University, 2009.
[24] 刘峰. 织构化涂层球头铣刀铣削改性钛合金切削性能研究[D]. 哈尔滨: 哈尔滨理工大学, 2026.
LIU F.Research on Cutting Performance of Textured Coated Ball-end Milling Cutter in Milling Modified Titanium Alloy[D]. Harbin: Harbin University of Science and Technology, 2026.
[1] LIU S Y, SHIN Y C.Additive Manufacturing of Ti6Al4V Alloy: A Review[J]. Materials & Design, 2019, 164: 107552.
[25] 王利捷, 王红波, 郝建民. 钛合金辉光离子渗硫与摩擦学特性研究[J]. 稀有金属材料与工程, 2009, 38(S1): 342-344.
WANG L J, WANG H B, HAO J M.Study on Glow Ion Sulfurizing Processing of Titanium Alloy and Its Tibological Property[J]. Rare Metal Materials and Engineering, 2009, 38(S1): 342-344.
[26] 元云岗, 康嘉杰, 岳文, 等. 不同温度下等离子渗氮后TC4钛合金的摩擦磨损性能[J]. 材料工程, 2020, 48(2): 156-162.
YUAN Y G, KANG J J, YUE W, et al.Tribological Properties of TC4 Titanium Alloy Treated by Plasma Nitriding at Different Temperatures[J]. Journal of Materials Engineering, 2020, 48(2): 156-162.
[27] 邱天, 言兰, 王福增, 等. 材料去除过程中 Rehbinder 效应的研究进展[J]. 中国表面工程, 2024, 37(1): 59-74.
QIU T, YAN L, WANG F Z, et al.Research Progress of the Rehbinder Effect in Material Removal Process[J]. China Surface Engineering, 2024, 37(1): 59-74.

Funding

National Natural Science Foundation of China (52475445); Natural Science Foundation of Heilongjiang Province (ZD2025E009)
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