Impact Dynamics and Anti-icing Behavior of Droplets with Bionic Salvinia natans Structure

WAN Yanling, YIN Yuhong, ZHANG Guodong, XUE Jingze, YU Huadong

Surface Technology ›› 2026, Vol. 55 ›› Issue (6) : 199-214.

PDF(17467 KB)
PDF(17467 KB)
Surface Technology ›› 2026, Vol. 55 ›› Issue (6) : 199-214. DOI: 10.16490/j.cnki.issn.1001-3660.2026.06.015
Functional Surfaces and Technology

Impact Dynamics and Anti-icing Behavior of Droplets with Bionic Salvinia natans Structure

  • WAN Yanling1,*, YIN Yuhong1, ZHANG Guodong2, XUE Jingze1, YU Huadong3
Author information +
History +

Abstract

This represents an efficient and convenient anti-icing strategy that enables droplets to spontaneously detach before freezing. Inspired by the unique hierarchical morphology and exceptional wettability of the aquatic plant Salvinia natans, this study proposes a novel biomimetic surface to achieve highly efficient anti-icing and de-icing performance. The core innovation lies in replicating key features of Salvinia natans, including its hair-like microstructures and wettability, to engineer a multi-level super hydrophobic surface. This design enables dynamic droplet clearance from the surface while maintaining stable air film retention underwater.
A 6061 aluminum alloy substrate is used as the surface. The processing sequence begins with grinding and polishing using 400- to 2000-grit sandpaper, followed by ultrasonic cleaning with acetone, ethanol, and deionized water. A microstructure mimicking Salvinia natans is fabricated via electrical discharge machining (EDM) with a 0.18 mm molybdenum wire on an HA-400U EDM machine. Subsequently, the surface undergoes chemical modification with 1H,2H,3H-Perfluorodecyltrimethoxysilane (FAS-17) to reduce surface energy. The multilevel structure and micro/nano topography are observed via scanning electron microscopy (SEM) and super-depth-of-field microscopy. Wetting properties are evaluated with an OCA20 contact angle meter on 5-microliter deionized water droplets. Water drop impact dynamics are captured at 7039 frames per second with a PCO. dimax HS high-speed camera. Anti-icing performance is evaluated using a custom cryogenic stage equipped with a semiconductor cooler, an infrared thermometer, and an imaging system. Anti-icing performance testing is conducted by lowering the substrate temperature to -10 ℃ (±0.5 ℃) at ambient temperature of (15±2) ℃. The anti-icing capability is analyzed by observing the melting of ice and snow on the test specimens. To evaluate specimen stability, specimens are immersed in water at depths of 10-50 mm and inflated with an air bladder. The resistance to wetting is assessed by observing the retention of the air bladder on the specimen after 30 minutes in water.
In testing, the biomimetic surface demonstrates exceptional superhydrophobicity with a static contact angle of 152.5°. Scanning electron microscopy images confirm the successful formation of a hierarchical micro/nanostructure, where micro-pillars and submicron-scale pits are created via electrical discharge machining. Droplet impact analysis reveals unique dynamics: the surface promotes the transition from axial to normal spreading, suppresses Worthington jet formation, and reduces droplet contact time to 11 milliseconds. Dehumidification efficiency reaches 32%. Droplets are effectively removed even on surfaces inclined at 45°. In snowmelt experiments, accumulated snow completely evaporates within 33 seconds. Meltwater aggregates into movable droplets that detach effortlessly under weak airflow. Stability tests confirm exceptional performance longevity: after 30 minutes immersion in 50 mm deep water, the contact angle remains at 151.3°. Gas injection replenishes the sealed gas film, demonstrating robust long-term durability.
Its anti-icing mechanism stems from a dual "air cushion effect" and hydrophobicity. The microstructure significantly reduces solid-liquid contact area, slows heat conduction, and stabilizes the air layer, thereby effectively inhibiting ice nucleation of droplets on cold surfaces and preventing subsequent droplet adhesion. Even under inclined conditions, the surface achieves effective droplet removal, demonstrating excellent engineering adaptability. This study provides a scalable and durable solution for designing anti-icing surfaces through biomimetic microengineering techniques. It holds broad application prospects in fields with urgent demands for efficient passive anti-icing technologies, such as aviation, wind energy, and maritime operations.

Key words

de-icing / bionic design / super hydrophobic / low adhesion / air cushion effect

Cite this article

Download Citations
WAN Yanling, YIN Yuhong, ZHANG Guodong, XUE Jingze, YU Huadong. Impact Dynamics and Anti-icing Behavior of Droplets with Bionic Salvinia natans Structure[J]. Surface Technology. 2026, 55(6): 199-214

References

[1] RIBEIRO A C, SOARES B G, FURTADO J G M, et al. Superhydrophobic Nanocomposite Coatings Based on Different Polysiloxane Matrices Designed for Electrical Insulators[J]. Progress in Organic Coatings, 2022, 168: 106867.
[2] MATEJICKA L, GEORGAKIS C T.A Review of Ice and Snow Risk Mitigation and Control Measures for Bridge Cables[J]. Cold Regions Science and Technology, 2022, 193: 103429.
[3] SHESTAKOVA A A.Assessing the Risks of Vessel Icing and Aviation Hazards during Downslope Windstorms in the Russian Arctic[J]. Atmosphere, 2021, 12(6): 760.
[4] ZDERO R, TURAN O F.The Effect of Surface Strands, Angle of Attack, and Ice Accretion on the Flow Field around Electrical Power Cables[J]. Journal of Wind Engineering and Industrial Aerodynamics, 2010, 98(10/11): 672-678.
[5] ELIZBARASHVILI E S, VARAZANASHVILI O S, TSERETELI N S, et al.Icing of Wires in Mountain Areas of Georgia[J]. Russian Meteorology and Hydrology, 2012, 37(8): 567-569.
[6] ZHANG Z J, ZHANG H, YUE S, et al.A Review of Icing and Anti-Icing Technology for Transmission Lines[J]. Energies, 2023, 16(2): 601.
[7] ZHOU L, LIU R D, YI X.Research and Development of Anti-Icing/Deicing Techniques for Vessels: Review[J]. Ocean Engineering, 2022, 260: 112008.
[8] CAO Y H, TAN W Y, WU Z L.Aircraft Icing: An Ongoing Threat to Aviation Safety[J]. Aerospace Science and Technology, 2018, 75: 353-385.
[9] CAO Y, CHEN K.Helicopter Icing[J]. The Aeronautical Journal, 2010, 114(1152): 83-90.
[10] LI H R, ZHANG Y F, CHEN H X.Optimization Design of Airfoils under Atmospheric Icing Conditions for UAV[J]. Chinese Journal of Aeronautics, 2022, 35(4): 118-133.
[11] SHEN L H, LI D, SHANG Y H, et al.Deicing Behavior and Residue Characteristic on Cold Surface Excited by Ultrasonic Vibration[J]. International Journal of Refrigeration, 2023, 149: 168-180.
[12] STEFANIAK O M, CORSI S R, RUTTER T D, et al.Airport Deicers: An Unrecognized Source of Phosphorus Loading in Receiving Waters[J]. Environmental Science & Technology, 2023, 57(44): 17051-17060.
[13] EBRAHIMI BESHELI A, SAMIMI K, MOGHADAS NEJAD F, et al.Improving Concrete Pavement Performance in Relation to Combined Effects of Freeze-Thaw Cycles and De-Icing Salt[J]. Construction and Building Materials, 2021, 277: 122273.
[14] LI L N, KHODAKARAMI S, YAN X, et al.Enabling Renewable Energy Technologies in Harsh Climates with Ultra-Efficient Electro-Thermal Desnowing, Defrosting, and Deicing[J]. Advanced Functional Materials, 2022, 32(31): 2201521.
[15] RAN L X, QIU L J, ZHAO H, et al.Fabrication of MXene Based Sandwich-Like Films for Excellent Flexibility, Electromagnetic Interference Shielding and Thermal Management[J]. Composites Part A: Applied Science and Manufacturing, 2023, 173: 107672.
[16] BARTHLOTT W, NEINHUIS C.Purity of the Sacred Lotus, or Escape from Contamination in Biological Surfaces[J]. Planta, 1997, 202(1): 1-8.
[17] DENG L C, WANG Z W, NIU Y X, et al.CNTS-Induced Superhydrophobic and Photothermal Coating with Long-Term Durability and Self-Replenishing Property for Anti-Icing/de-Icing[J]. Composites Science and Technology, 2024, 245: 110347.
[18] XU Y, DING S L, YANG F C, et al.Photothermal and Superhydrophobic Composite Coatings with Sandwich and Interlocking Structure for Effective Anti-Icing and De-Icing[J]. Surfaces and Interfaces, 2023, 42: 103410.
[19] QIAN H C, LIU B, WU D Q, et al.Magnetically Responsive Lubricant-Infused Porous Surfaces with Controllable Lubricity and Durable Anti-Icing Performance[J]. Surface and Coatings Technology, 2021, 406: 126742.
[20] LEE S H, KIM J, SEONG M, et al.Magneto-Responsive Photothermal Composite Cilia for Active Anti-Icing and De-Icing[J]. Composites Science and Technology, 2022, 217: 109086.
[21] WU S W, WANG T W, DU Y J, et al.Tough, Anti- Freezing and Conductive Ionic Hydrogels[J]. NPG Asia Materials, 2022, 14: 65.
[22] LIAN Z X, ZHOU J H, LIU Z M, et al.Hierarchically Structured Superhydrophobic Surfaces with Photothermal Conversion to Avoid Icing[J]. International Journal of Mechanical Sciences, 2024, 275: 109341.
[23] WANG F, XIANG M T, YANG W B.Effects of Contact Angle Hysteresis on Frosting and Defrosting Characteristics on Vertical Superhydrophobic Surfaces[J]. Applied Thermal Engineering, 2024, 236: 121881.
[24] DENG H Y, CHANG S N, LI W.Experimental Study on Ice Adhesion Forces of the Copper Plates with Specific Contact Angle and Roughness[J]. Sustainable Energy Technologies and Assessments, 2021, 43: 100942.
[25] LI B, LI X W.Efficient and Controllable Preparation of Super-Hydrophobic Alumina-Based Ceramics Coating on Aviation Al-Li Alloy Surface for Corrosion Resistance and Anti-Icing Behavior[J]. Coatings, 2024, 14(9): 1223.
[26] LI X W, MA C H, SHI T, et al.Waterborne Robust Superhydrophobic PFDTES@TiO2-PU Coating with Stable Corrosion Resistance, Long-Term Environmental Adaptability, and Delayed Icing Functions on Al-Li Alloy[J]. Journal of Materials Research and Technology, 2024, 32: 3357-3370.
[27] LI A L, LI G T, XU Y, et al.Superhydrophobic Surface with Good Anti-Icing Properties and High Durability[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 698: 134539.
[28] HE H Y, ZHOU S F, DU J B, et al.Anti-Icing and Corrosion Resistance of Superhydrophobic Coatings by Precision Machining and One-Step Electrodeposition on Mg-Li Alloy[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 685: 133294.
[29] SHU Y X, LU X Y, LU W S, et al.Mechanically Robust Superhydrophobic Copper Surface with Self-Cleaning, Anti-Icing, and Corrosion Resistance[J]. Surface and Coatings Technology, 2023, 455: 129216.
[30] RODIČ P, KAPUN B, MILOŠEV I. Superhydrophobic Aluminium Surface to Enhance Corrosion Resistance and Obtain Self-Cleaning and Anti-Icing Ability[J]. Molecules, 2022, 27(3): 1099.
[31] DITSCHE P, GORB E, MAYSER M, et al.Elasticity of the Hair Cover in Air-Retaining Salvinia Surfaces[J]. Applied Physics A, 2015, 121(2): 505-511.
[32] JIANG Y L, YANG Z, XU X, et al.Spreading Model of Single Droplet Impacting the Banana Leaf Surface and Computational Fluid Dynamics Simulation Analysis[J]. Computers and Electronics in Agriculture, 2024, 223: 109113.
[33] WANG B, WANG J, YU C L, et al.Sustained Agricultural Spraying: From Leaf Wettability to Dynamic Droplet Impact Behavior[J]. Global Challenges, 2023, 7(9): 2300007.
[34] CAO C, LIU M X, MA X X, et al.Enhancing Droplets Deposition on Superhydrophobic Plant Leaves by Bio-Based Surfactant: Experimental Characterization and Molecular Dynamics Simulations[J]. Journal of Molecular Liquids, 2023, 387: 122696.
[35] LI Z L, MA Y, ZHAO K F, et al.Regulating Droplet Impact and Wetting Behaviors on Hydrophobic Weed Leaves by a Double-Chain Cationic Surfactant[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(7): 2891-2901.
[36] JONG R D, ZHAO S C, MEER D.Physics; Researchers at University of Twente Discuss Findings in Physics (Crater Formation During Raindrop Impact on Sand)[J]. Physics Week, 2017, 95(4): 518.
[37] FU X, LI H N.Theoretical and Experimental Studies of the Rain Load for Transmission Tower Based on Single- Raindrop Impinging Force[J]. International Journal of Structural Stability and Dynamics, 2019, 19(11): 1950133.
[38] BHOSALE Y, ESMAILI E, BHAR K, et al.Bending, Twisting and Flapping Leaf Upon Raindrop Impact[J]. Bioinspiration & Biomimetics, 2020, 15(3): 036007.
[39] LAUDERBAUGH L K, GINEBRA-SOLANELLAS R M, HOLDER C D, et al. A Biomechanical Model of Leaf Inclination Angle Oscillations after Raindrop Impact[J]. Environmental and Experimental Botany, 2021, 190: 104586.
[40] PALOMBA I, DORIA A, MARCONI E, et al.Vibration Energy Harvesting from Raindrops Impacts: Experimental Tests and Interpretative Models[J]. Applied Sciences, 2022, 12(7): 3249.
[41] VERMA S, BENOUAGUEF I, MUSUNURI N, et al.Marangoni Flow Induced in a Waterbody by the Impact of a Raindrop[J]. Mechanics Research Communications, 2023, 133: 104187.
[42] YAMAMOTO K, MOTOSUKE M, OGATA S.Initiation of the Worthington Jet on the Droplet Impact[J]. Applied Physics Letters, 2018, 112(9): 093701.
[43] JAMALI M, ROSTAMIJAVANANI A, NOURI N M, et al.An Experimental Study of Cavity and Worthington Jet Formations Caused by a Falling Sphere into an Oil Film on Water[J]. Applied Ocean Research, 2020, 102: 102319.
[44] LEE Y, SHIN S, CHOI G, et al.Symmetry Breaking of Worthington Jets by Gradients in Liquid Pool Depth[J]. Physics of Fluids, 2020, 32(11): 112104.
[45] ZHANG Y C, HU Y L, XU B, et al.Robust Underwater Air Layer Retention and Restoration on Salvinia-Inspired Self-Grown Heterogeneous Architectures.[J]. ACS nano, 2022, 16(2): 2730-2740.
[46] XIANG Y L, HUANG S L, HUANG T Y, et al.Superrepellency of Underwater Hierarchical Structures on Salvinia Leaf[J]. Proceedings of the National Academy of Sciences of the United States of America, 2020, 117(5): 2282-2287.
[47] ZHANG X H, LEI Y, LI C X, et al.Superhydrophobic and Multifunctional Aerogel Enabled by Bioinspired Salvinia Leaf-Like Structure[J]. Advanced Functional Materials, 2022, 32(14): 2110830.
[48] BRACKBILL J U, KOTHE D B, ZEMACH C.A Continuum Method for Modeling Surface Tension[J]. Journal of Computational Physics, 1992, 100(2): 335-354.
[49] Youngs D L .Time-Dependent Multi-material Flow with Large Fluid Distortion[J].Numerical Methods for Fluid Dynamics, 1982.
[50] HU Z F, CHU F Q, WU X M.Double-Peak Characteristic of Droplet Impact Force on Superhydrophobic Surfaces[J]. Extreme Mechanics Letters, 2022, 52: 101665.
[51] WANG L Z, LI D Z, JIANG G C, et al.Dual-Energy- Barrier Stable Superhydrophobic Structures for Long Icing Delay[J]. ACS Nano, 2024, 18(19): 12489-12502.

Funding

Jilin Provincial Natural Science Foundation (20260102057JC)
PDF(17467 KB)

Accesses

Citation

Detail

Sections
Recommended

/