Effect of Laser Power on Microstructure and Wear Resistance of the Fe/TiC-VC Coating

MA Tianbing, WANG Mingxin, YU Yanqing, LI Yong, SHEN Chen, BIAN Ce

Surface Technology ›› 2026, Vol. 55 ›› Issue (5) : 201-212.

PDF(30965 KB)
PDF(30965 KB)
Surface Technology ›› 2026, Vol. 55 ›› Issue (5) : 201-212. DOI: 10.16490/j.cnki.issn.1001-3660.2026.05.017
Friction, Wear and Lubrication

Effect of Laser Power on Microstructure and Wear Resistance of the Fe/TiC-VC Coating

  • MA Tianbing, WANG Mingxin, YU Yanqing*, LI Yong, SHEN Chen, BIAN Ce
Author information +
History +

Abstract

As a critical component in mining operations for breaking rocks and coals, the pick suffers severe wear problems. To enhance the wear resistance of the 42CrMo alloy steel used in the pick, laser cladding technology has been widely employed due to its significant advantages, including controllable dilution rate, precise heat input, minimal base material thermal deformation, and high process stability. In this study, a metal substrate coating with high carbide content was developed, and its strengthening mechanism was analyzed. A 70% TiC-VC reinforced Fe-based composite coating was prepared on the surface of 42CrMo alloy steel with the laser cladding method. The differences in microstructure and tribological properties of the cladding layer at different laser powers (1 000 W, 1 500 W, and 2 000 W) were compared. The spot diameter, scan velocity, overlap rate, and pre-placed thickness were set to 3 mm, 500 mm/min, 50%, and 2 mm, respectively. Besides, to reduce stress concentration in the cladding layer and improve forming quality, the samples after laser cladding were annealed at 100 ℃ for 5 hours and then cooled to room temperature in the furnace. Then, the microstructure, phase composition, microhardness, and tribological properties of the samples before and after laser cladding were measured. Besides, the dissolution process of TiC particles was elucidated by comparing the temperature field distribution under different laser powers. The cladding layer under different laser powers all contained α-Fe, TiC, and VC phases. During the cladding process, irregular TiC particles dissolved when absorbing laser energy and combined with VC to form dispersed TiC-VC composite particles. TiC particles had the highest hardness and extremely poor toughness. However, the dispersed small TiC-VC composite particles maintained high hardness while ensuring toughness. The hardness of the cladding layer under different laser powers remained similar, reaching 1 005HV0.2, which was 1.81 times that of the 42CrMo steel substrate (357.6HV0.2). The dominant wear mechanisms before and after laser cladding were abrasive wear and oxidative wear, which remained unchanged. However, the small TiC-VC composite particles played a dispersion strengthening role, effectively limiting deformation in the cladding layer and significantly enhancing its resistance to abrasive erosion. After laser cladding, the wear scar surface became smooth, and grooves were no longer noticeable. When the laser power increased from 1 000 W to 2 000 W, the number of large TiC particles gradually decreased with a transition from a uniform distribution to a concentration at the bottom. Meanwhile, the number of small composite particles gradually increased, and their distribution became more dispersed. Simulation of the temperature field also verified this result. Therefore, as the laser power increased from 0 W to 1 000 W, 1 500 W, and 2 000 W, the wear volume decreased from 12.28×10-3 mm3 to 2.32× 10-3 mm3, 1.89×10-3 mm3, and 1.02×10-3 mm3, respectively, with the decline ratio of 81.1%, 84.6%, and 91.7%, respectively. The 70% TiC-VC reinforced Fe-based coating prepared by laser cladding can significantly improve the wear resistance of 42CrMo alloy steel, which is an effective method for protecting the pick from wear.

Key words

laser cladding / Fe/TiC-VC coating / laser power / microstructure / wear resistance

Cite this article

Download Citations
MA Tianbing, WANG Mingxin, YU Yanqing, LI Yong, SHEN Chen, BIAN Ce. Effect of Laser Power on Microstructure and Wear Resistance of the Fe/TiC-VC Coating[J]. Surface Technology. 2026, 55(5): 201-212

References

[1] 秦彦凯, 张永飞, 张晓红, 等. 采掘机械截齿退化机制研究[J]. 煤炭工程, 2022, 54(9): 168-174.
QIN Y K, ZHANG Y F, ZHANG X H, et al.Degradation Mechanism of Mining Machinery Pick[J]. Coal Engineering, 2022, 54(9): 168-174.
[2] 秦彦凯, 张晓红, 曾建潮, 等. 悬臂式掘进机截齿系统维修与备件库存联合决策[J]. 煤炭工程, 2023, 55(7): 94-101.
QIN Y K, ZHANG X H, ZENG J C, et al.Joint Decision of Maintenance and Spare Parts Inventory for Boom-Type Roadheader Pick System[J]. Coal Engineering, 2023, 55(7): 94-101.
[3] 张泽疆, 李新梅, 朱春金, 等. B4C添加量对42CrMo钢表面Stellite6+B4C激光熔覆层形貌与性能的影响[J]. 金属热处理, 2024, 49(7): 200-208.
ZHANG Z J, LI X M, ZHU C J, et al.Effect of B4C Addition on Morphology and Properties of Stellite6+B4C Laser Clad Layers on 42CrMo Steel Surface[J]. Heat Treatment of Metals, 2024, 49(7): 200-208.
[4] GAO M Y, LI S C, GUAN W M, et al.Excellent Thermal Shock Resistance of NiCrAlY Coatings on Copper Substrate via Laser Cladding[J]. Journal of Materials Science & Technology, 2022, 130: 93-102.
[5] 孙方红, 任延杰, 宋文卿. 42CrMo钢表面激光熔覆涂层的研究现状及进展[J]. 中国腐蚀与防护学报, 2025, 45(4): 849-858.
SUN F H, REN Y J, SONG W Q.Research Status and Progress of Laser Clad Coatings on 42CrMo Steel[J]. Journal of Chinese Society for Corrosion and Protection, 2025, 45(4): 849-858.
[6] LV G J, YANG X F, GAO Y L, et al.Investigation on Fretting Wear Performance of Laser Cladding WC/Co06 Coating on 42CrMo Steel for Hydraulic Damper[J]. International Journal of Refractory Metals and Hard Materials, 2023, 111: 106068.
[7] 李二盼, 梁国星, 刘东刚, 等. 42CrMo钢表面激光熔覆颗粒增强Co基涂层的组织与性能[J]. 金属热处理, 2023, 48(3): 159-165.
LI E P, LIANG G X, LIU D G, et al.Microstructure and Properties of Particles Reinforced Co-Based Coating by Laser Cladding on 42 CrMo Steel[J]. Heat Treatment of Metals, 2023, 48(3): 159-165.
[8] 罗亮斌, 梁国星, 刘东刚, 等. 42CrMo钢表面激光熔覆钴基金刚石耐磨层组织及性能[J]. 表面技术, 2024, 53(5): 96-107.
LUO L B, LIANG G X, LIU D G, et al.Microstructure and Properties of Laser Cladding Co-Based Diamond Wear Resistant Layer on 42CrMo Steel Surface[J]. Surface Technology, 2024, 53(5): 96-107.
[9] 田鹿岩, 李新梅, 路国闯. 42crmo钢表面激光熔覆Stellite6复合熔覆层组织及性能[J]. 应用激光, 2024, 44(12): 29-37.
TIAN L Y, LI X M, LU G C.Microstructure and Properties of Stellite6 Composite Cladding Layer on 42crmo Steel Surface by Laser Cladding[J]. Applied Laser, 2024, 44(12): 29-37.
[10] ZHENG X, ZHENG K, CHANG J N, et al.Microstructure, Mechanical Properties and Reciprocating Wear Properties of Diamond Grits-Reinforced NiCrBSi Composite Coatings on 42CrMo[J]. Surface and Coatings Technology, 2022, 445: 128703.
[11] 效益, 孙文磊, 肖猛, 等. 激光熔覆镍基WC复合涂层工艺优化及组织性能研究[J]. 热加工工艺, 2026, 55(1): 135-141.
XIAO Y, SUN W L, XIAO M, et al.Research on Process Optimization and Microstructure Properties of Laser Cladding Nickel-Based WC Composite Coating[J]. Hot Working Technology, 2026, 55(1): 135-141.
[12] 张现虎, 陈成龙, 李远田, 等. 42CrMo钢激光熔覆不锈钢粉掺杂Ni-WC涂层的组织及性能研究[J]. 热加工工艺, 2021, 50(16): 66-70.
ZHANG X H, CHEN C L, LI Y T, et al.Research on Microstructure and Properties of Laser Cladding Stainless Steel Powders Doped Ni-WC Coatings on 42CrMo Steel[J]. Hot Working Technology, 2021, 50(16): 66-70.
[13] ZENG X B, WANG Q T, CHEN C R, et al.Effects of WC Addition on the Morphology, Microstructure and Mechanical Properties of Fe50/TiC/WC Laser Claddings on AISI 1045 Steel[J]. Surface and Coatings Technology, 2021, 427: 127781.
[14] 刘东刚, 梁国星, 郝新辉, 等. 不同含量WC颗粒增强激光熔覆截齿涂层性能研究[J]. 表面技术, 2023, 52(9): 408-419.
LIU D G, LIANG G X, HAO X H, et al.Properties of Laser Cladded Coating on Pick with Different Content of WC Particles[J]. Surface Technology, 2023, 52(9): 408-419.
[15] LIU S F, LIU D C.Effect of Hard Phase Content on the Mechanical Properties of TiC-316 L Stainless Steel Cermets[J]. International Journal of Refractory Metals and Hard Materials, 2019, 82: 273-278.
[16] ZHANG H, LIU G, REN N N, et al.Microstructure Evolution and High Temperature Wear Resistance of In-Situ Synthesized Carbides Reinforced NiCoFeCrSiMo High Entropy Alloy Coatings Fabricated by Laser Cladding[J]. Surface and Coatings Technology, 2023, 464: 129573.
[17] CHEN H, LU Y Y, WU K H, et al.Effect of WC Addition on TiC Reinforced Fe Matrix Composites Produced by Laser Deposition[J]. Surface and Coatings Technology, 2022, 434: 128185.
[18] ZHU Y Q, SHEN S K, YANG X F, et al.Study on the Friction and Wear Performance of Laser Cladding WC- TiC/Ni60 Coating on the Working Face of Shield Bobbing Cutter[J]. Optical Materials, 2024, 148: 114875.
[19] KHANZADEH M, ALAHYARIZADEH G.A DFT Study on Pressure Dependency of TiC and ZrC Properties: Interconnecting Elastic Constants, Thermodynamic, and Mechanical Properties[J]. Ceramics International, 2021, 47(7): 9990-10005.
[20] WANG X Q, TU J B, LIU B C.Enhancement of Mechanical and Thermal Properties of Diamond Particles via Vanadium Carbide Coatings[J]. Diamond and Related Materials, 2024, 148: 111510.
[21] CHEN L Y, YU T B, XU P F, et al.In-Situ NbC Reinforced Fe-Based Coating by Laser Cladding: Simulation and Experiment[J]. Surface and Coatings Technology, 2021, 412: 127027.
[22] ZHAO Y, GUAN C, CHEN L Y, et al.Effect of Process Parameters on the Cladding Track Geometry Fabricated by Laser Cladding[J]. Optik, 2020, 223: 165447.
[23] ZHU S C, NIU B L, CHANG Z, et al.Research on Heat and Mass Transfer in the Molten Pool of Laser Cladding[J]. The International Journal of Advanced Manufacturing Technology, 2024, 132(1): 983-1004.
[24] XIAO M Y, JIANG F C, GUO C H, et al.Investigation on Microstructure and Mechanical Properties of Fe-Based Amorphous Coatings Prepared via Laser Cladding Assisted with Ultrasonic Vibration[J]. Optics & Laser Technology, 2023, 162: 109294.
[25] LU J Z, CAO J, LU H F, et al.Wear Properties and Microstructural Analyses of Fe-Based Coatings with Various WC Contents on H13 Die Steel by Laser Cladding[J]. Surface and Coatings Technology, 2019, 369: 228-237.
[26] ZHANG H F, WANG L, ZHANG S, et al.Design, Fabrication, Microstructure and Properties of In-Situ Synthesized TiC Reinforced Stainless Steel Matrix Composite Coating by Laser Cladding[J]. Materials Characterization, 2023, 204: 113177.
[27] TELASANG G, DUTTA MAJUMDAR J, PADMANABHAM G, et al.Effect of Laser Parameters on Microstructure and Hardness of Laser Clad and Tempered AISI H13 Tool Steel[J]. Surface and Coatings Technology, 2014, 258: 1108-1118.
[28] WANG H P, SUN R X, ZHANG M Q, et al.Impact- Sliding Behavior of Ni-Based Coating Prepared on Tunnel Boring Machine Disc Cutter Material Produced Using a Plasma Transferred Arc Welding Process[J]. Surface and Coatings Technology, 2022, 442: 128186.
[29] ZHANG M Y, LI M, CHI J, et al.Microstructure Evolution, Recrystallization and Tribological Behavior of TiC/ WC Composite Ceramics Coating[J]. Vacuum, 2019, 166: 64-71.
[30] KANG N, MA W Y, HERAUD L, et al.Selective Laser Melting of Tungsten Carbide Reinforced Maraging Steel Composite[J]. Additive Manufacturing, 2018, 22: 104-110.
[31] HAN Q Q, LOW K W Q, GU Y C, et al. The Dynamics of Reinforced Particle Migration in Laser Powder Bed Fusion of Ni-Based Composite[J]. Powder Technology, 2021, 394: 714-723.
[32] ZHANG H F, WANG L, ZHANG S, et al.An Investigation on Wear and Cavitation Erosion-Corrosion Characteristics of the TiC Modified Fe-Based Composite Coating via Laser Cladding[J]. Journal of Materials Research and Technology, 2023, 26: 8440-8455.
[33] DADOO A, ALI BOUTORABI S M, KHEIRANDISH S. Effect of Titanium Carbide Concentration on the Morphology of MC Carbides in Pulsed Laser Surface Alloyed AISI H13 Tool Steel[J]. Optics & Laser Technology, 2019, 112: 236-244.
[34] QI X X, LI F Y, LI Y L, et al.Microstructure Regulation and Reinforcement Mechanisms of Ultrafine TiC/Fe55 Composite Coatings via Laser Melting Deposition[J]. Materials & Design, 2023, 229: 111924.
[35] WANG L X, YANG L J, HUANG Y M, et al.Carbides Reinforced Ni-Ti Matrix Coating Fabricated by Laser Wire Deposition: Microstructure and Wear Behaviors[J]. Materials Letters, 2022, 307: 131008.
[36] LUO X, LI J, LI G J.Effect of NiCrBSi Content on Microstructural Evolution, Cracking Susceptibility and Wear Behaviors of Laser Cladding WC/Ni-NiCrBSi Composite Coatings[J]. Journal of Alloys and Compounds, 2015, 626: 102-111.
[37] RADHAKRISHNAN M, HASSAN M, LONG B, et al.Microstructures and Properties of Ti/TiC Composites Fabricated by Laser-Directed Energy Deposition[J]. Additive Manufacturing, 2021, 46: 102198.
[38] WANG Y X, FAN W, DANG M J, et al.Achieving Superior High-Temperature Performance in Ti60 Alloy with Dispersed TiC Reinforcement via Directed Energy Deposition[J]. Composites Part B: Engineering, 2025, 304: 112690.
[39] HADIAN KAFFASH N, MARANDI S, BEIDOKHTI B, et al.Effect of Heat Treatment on Microstructure and Wear Properties of Laser Additively Manufactured 316 L Stainless Steel/Co-Cr-W Alloy Part Using Directed Energy Deposition Method[J]. Materials Today Communications, 2024, 38: 107865.

Funding

The University Synergy Innovation Program of Anhui Province (GXXT-2022-019); State Key Laboratory for Mining Response and Disaster Prevention and Control of Deep Coal Mines Open Fund (SKLMRDPC23KF23, SKLMRDPC22KF26); Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology (2023yjrc69)
PDF(30965 KB)

Accesses

Citation

Detail

Sections
Recommended

/