Impact of Amorphous Carbon Thin Films on the Suppression of Multipactor Effects

JIANG Zhaomin, CHU Kun, HU Xiaochuan, FENG Guobao

Surface Technology ›› 2026, Vol. 55 ›› Issue (2) : 266-277.

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Surface Technology ›› 2026, Vol. 55 ›› Issue (2) : 266-277. DOI: 10.16490/j.cnki.issn.1001-3660.2026.02.020
Functional Surfaces and Technology

Impact of Amorphous Carbon Thin Films on the Suppression of Multipactor Effects

  • JIANG Zhaomin1, CHU Kun1, HU Xiaochuan1,*, FENG Guobao2
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Abstract

Multipactor is one of the key factors leading to on-orbit failure of high-power spaceflight microwave devices. The work aims to elucidate the mechanism of how amorphous carbon (a-C) thin films modulate the secondary electron emission (SEE) properties of copper (Cu) surfaces in order to suppress the multipactor effect in microwave devices and to quantify its suppression effect in parallel flat plates and coaxial transmission lines. The direct current magnetron sputtering technique was used to deposit a-C thin films on Cu substrates. Then, the secondary electron yield (SEY) of Cu and a-C/Cu samples was measured by the bias current method, respectively, and the secondary electron spectrum (SES) at 300 eV incident electron energy was recorded with the electrostatic electron spectroscopy technique. Based on the Furman theory, a Monte Carlo model was developed to predict the SEE properties of Cu and a-C/Cu. Subsequently, CST Studio Suite electromagnetic simulation software was used to construct parallel flat plate and coaxial transmission line structure models. The effect of a-C film on the threshold voltage of the multipactor was investigated by depositing it on the inner wall of the microwave structure. The thickness of the deposited a-C film layer was (1.27 ± 0.05) μm, measured by scanning electron microscope (SEM). This coating reduced the maximum value of SEY for Cu from 2.18 to 1.65, which was a 24.1% reduction. The first critical energy increased from 36 eV to 58 eV, and the second critical energy decreased from 2 843 eV to 1 000 eV. Meanwhile, the intensity and area of the intrinsic peak of the SES decayed by 44% and 33%, respectively. By comparing the deviation between the Monte Carlo predicted SEY results and the experimental results, it was found that the maximum error of Cu occurred at an incident energy of 800 eV, with an error value of 14%, while the maximum error of a-C/Cu occurred at an incident energy of 1 000 eV, with an error value of 4%. The model fitted well with experimental results. CST simulations showed that the a-C film compressed the multipactor sensitive interval of the parallel flat plate model by 42.3% in the frequency range of 2 to 9 GHz·mm. Specifically, when f × d= 3 GHz·mm, the lower threshold voltage increased by 17.9% from 237.7 V to 280.42 V, and the upper threshold voltage decreased by 25.3% from 898.89 V to 671.34 V. The coaxial transmission line model showed a similar trend, with the lower and upper threshold voltages varying by +11.29 V and -60.56 V, respectively. The results show that the a-C thin film can reduce the SEY of Cu materials, which in turn has a significant suppression effect on the SEE of Cu. The film results in a significant reduction of the multipactor sensitivity interval for two typical microwave structures, a parallel flat plate and a coaxial transmission line. It has been demonstrated that a-C thin films, as a low-cost and scalable surface modification strategy, can effectively enhance the anti-multipactor capability of microwave devices in extreme spatial environments. The combination of experiments and simulations provides a strong scientific basis for understanding and suppressing multipactor effects and provides theoretical support for the surface modification design of spacecraft microwave devices.

Key words

multipactor / amorphous carbon film / secondary electron emission / Furman model / Monte Carlo method

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JIANG Zhaomin, CHU Kun, HU Xiaochuan, FENG Guobao. Impact of Amorphous Carbon Thin Films on the Suppression of Multipactor Effects[J]. Surface Technology. 2026, 55(2): 266-277

References

[1] IQBAL A, WEN D Q, VERBONCOEUR J, et al.Recent Advances in Multipactor Physics and Mitigation[J]. High Voltage, 2023, 8(6): 1095-1114.
[2] 崔万照, 张娜, 封国宝, 等. 二次电子发射研究进展及其空间应用[J]. 空间电子技术, 2022, 19(4): 1-9.
CUI W Z, ZHANG N, FENG G B, et al.Research Progress of Secondary Electron Emission Research and Its Space Application[J]. Space Electronic Technology, 2022, 19(4): 1-9.
[3] CHEN Y, HUANG G R, YANG Y, et al.Development of a Measurement System for the Secondary Electron Emission Yield Spectrum of Space Materials[C]//2020 International Conference on Sensing, Measurement & Data Analytics in the era of Artificial Intelligence (ICSMD). Xi’an, China. IEEE, 2020: 160-163.
[4] 邓晨晖, 韩立, 王岩, 等. 二次电子产额影响因素的研究进展[J]. 材料导报, 2023, 37(24): 18-27.
DENG C H, HAN L, WANG Y, et al.Progress in the Study of Factors Influencing the Secondary Electron Yield[J]. Materials Reports, 2023, 37(24): 18-27.
[5] 魏晶慧, 刘晋允, 王一楠, 等. 不同材料的二次电子发射系数研究[J]. 真空电子技术, 2025(1): 57-60.
WEI J H, LIU J Y, WANG Y N, et al.Research on Secondary Electron Yield of Different Materials[J]. Vacuum Electronics, 2025(1): 57-60.
[6] 蔡亚辉, 王丹, 张雯, 等. PTFE-SiO2复合涂层电子发射特性及抑制放电[J]. 表面技术, 2023, 52(6): 369-376.
CAI Y H, WANG D, ZHANG W, et al.Electron Emission Characteristics and Discharge Suppression of PTFE-SiO2 Composite Coating[J]. Surface Technology, 2023, 52(6): 369-376.
[7] 贺永宁, 王丹, 叶鸣, 等. 铝合金镀银表面粗糙化处理方法及其SEY抑制机理[J]. 表面技术, 2018, 47(5): 1-8.
HE Y N, WANG D, YE M, et al.Roughening Method and SEY Inhibition Mechanism of Aluminium Alloy Silver Plated Surface[J]. Surface Technology, 2018, 47(5): 1-8.
[8] 万雪曼, 杨晶, 胡天存, 等. 表面镀膜调控二次电子发射的研究进展[J]. 表面技术, 2024, 53(24): 31-39.
WAN X M, YANG J, HU T C, et al.Research Progress of Coatings Modulating Secondary Electron Emission Characteristics[J]. Surface Technology, 2024, 53(24): 31-39.
[9] 王丹, 贺永宁, 崔万照. 氮化钛薄膜二次电子发射特性研究[J]. 表面技术, 2018, 47(5): 9-14.
WANG D, HE Y N, CUI W Z.Secondary Electron Emission Characteristics of Titanium Nitride Thin Film[J]. Surface Technology, 2018, 47(5): 9-14.
[10] 胡笑钏, 刘样溪, 楚坤, 等. 非晶态碳薄膜对金属二次电子发射的影响[J]. 物理学报, 2024, 73(4): 297-305.
HU X C, LIU Y X, CHU K, et al.Effect of Amorphous Carbon Film on Secondary Electron Emission of Metal[J]. Acta Physica Sinica, 2024, 73(4): 297-305.
[11] CHU S F, LIU P, ZHANG Y, et al.In Situ Atomic-Scale Observation of Dislocation Climb and Grain Boundary Evolution in Nanostructured Metal[J]. Nature Communications, 2022, 13: 4151.
[12] ZAHARESCU T, MARIŞ M.Irradiation Effects in Polymer Composites for Their Conversion into Hybrids[J]. Journal of Composites Science, 2022, 6(4): 109.
[13] SCHULTRICH B.Structure and Characterization of Vacuum Arc Deposited Carbon Films—A Critical Overview[J]. Coatings, 2022, 12(2): 109.
[14] ANGELUCCI M, NOVELLI A, SPALLINO L, et al.Minimum Thickness of Carbon Coating for Multipacting Suppression[J]. Physical Review Research, 2020, 2(3): 032030.
[15] 张宇心, 王一刚, 葛晓琴, 等. 无定形碳薄膜的二次电子发射特性研究[J]. 真空科学与技术学报, 2018, 38(12): 1065-1069.
ZHANG Y X, WANG Y G, GE X Q, et al.Amorphous Carbon Coating Material with Low Secondary Electron Yield for High Energy Particle Accelerator[J]. Chinese Journal of Vacuum Science and Technology, 2018, 38(12): 1065-1069.
[16] LI J, YI X K, HU W B, et al.Substrate Temperature Dependent Microstructure and Electron-Induced Secondary Electron Emission Properties of Magnetron Sputter- Deposited Amorphous Carbon Films[J]. Materials, 2019, 12(16): 2631.
[17] LU Q, YU B, HU Z Q, et al.Surface Roughness Evolution Induced Low Secondary Electron Yield in Carbon Coated Ag/Al Substrates for Space Microwave Devices[J]. Applied Surface Science, 2020, 501: 144236.
[18] KANG Y F, LI B, ZHAO J Y, et al.Effect of Structure on the Secondary Electron Emission of Tetrahedral Amorphous Carbon Films[J]. Vacuum, 2020, 172: 109043.
[19] LI J, LIU B Y, WU S L, et al.Electron-Induced Secondary Electron Emission of Aluminum Alloy Processed via the Combination of Alodine Treatment and Carbon Film Deposition[J]. Materials Letters, 2022, 327: 133085.
[20] 段潮锋, 胡笑钏, 楚坤, 等. 亚微米碳基薄膜抑制二次电子发射效应及其对微放电阈值的调控[J]. 真空科学与技术学报, 2025, 45(9): 802-809.
DUAN C F, HU X C, CHU K, et al.The Effect of Sub- Micron Carbon-Based Films on Suppressing Secondary Electron Emission and Its Regulation on the Multipactor Threshold[J]. Chinese Journal of Vacuum Science and Technology, 2025, 45(9): 802-809.
[21] RATSCH C, VENABLES J A.Nucleation Theory and the Early Stages of Thin Film Growth[J]. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 2003, 21(5): S96-S109.
[22] CAO M, ZHANG X S, LIU W H, et al.Secondary Electron Emission of Graphene-Coated Copper[J]. Diamond and Related Materials, 2017, 73: 199-203.
[23] FURMAN M, PIVI M.Probabilistic Model for the Simulation of Secondary Electron Emission[J]. Physical Review Special Topics - Accelerators and Beams, 2002, 5(12): 124404.
[24] 张娜, 王瑞, 崔万照. 影响星载微波部件微放电阈值的Furman模型研究[J]. 空间电子技术, 2022, 19(4): 58-63.
ZHANG N, WANG R, CUI W Z.Influence of the Furman Model on the Multipactor Threshold of Satellite-Borne Microwave Component[J]. Space Electronic Technology, 2022, 19(4): 58-63.
[25] 张娜, 李亚峰, 魏焕, 等. Furman能谱模型对空间微波部件微放电效应的影响分析[J]. 真空电子技术, 2024(6): 42-46.
ZHANG N, LI Y F, WEI H, et al.The Influence of Furman Spectral Model on Multipactor Effect of Space Microwave Components[J]. Vacuum Electronics, 2024(6): 42-46.
[26] 翟永贵, 王瑞, 王洪广, 等. 铁氧体环形器微放电阈值快速粒子模拟[J]. 真空电子技术, 2017(2): 11-13.
ZHAI Y G, WANG R, WANG H G, et al.Fast Particle-in- Cell Method for Multipactor Threshold Calculation of Ferrite Circulator[J]. Vacuum Electronics, 2017(2): 11-13.
[27] GONZÁLEZ-IGLESIAS D, GÓMEZ Á, GIMENO B, et al. Analysis of Multipactor RF Breakdown in a Waveguide Containing a Transversely Magnetized Ferrite[J]. IEEE Transactions on Electron Devices, 2016, 63(12): 4939-4947.
[28] DENNISON J R, HOLTZ M, SWAIN G.Raman Spectroscopy of Carbon Materials[J]. Spectroscopy, 1996, 11(8): 38-45.
[29] FIL N, BELHAJ M, HILLAIRET J, et al.Multipactor Threshold Sensitivity to Total Electron Emission Yield in Parallel-Plate Waveguide and TEEY Models Accuracy[C]//2016 IEEE MTT-S International Microwave Symposium (IMS). San Francisco, CA, USA. IEEE, 2016: 1-4.
[30] 张雨婷, 杨晶, 杨兆伦, 等. 钼的二次电子发射特性研究[J]. 稀有金属材料与工程, 2024, 53(2): 465-473.
ZHANG Y T, YANG J, YANG Z L, et al.Research on the Secondary Electron Emission Characteristics of Molybdenum[J]. Rare Metal Materials and Engineering, 2024, 53(2): 465-473.
[31] HU X C, CHEN Y Z, SUN G Z, et al.Secondary Electron Spectrum of Metals with Different Surface Potential Barriers[J]. Journal of Applied Physics, 2023, 134: 013305.
[32] 林舒, 夏宁, 王洪广, 等. 同轴传输线微放电的统计理论稳态建模及敏感区域计算[J]. 物理学报, 2018, 67(22): 401-410.
LIN S, XIA N, WANG H G, et al.Multipactor Susceptibility Chart of Coaxial Transmission Lines with Stationary Statistical Modeling[J]. Acta Physica Sinica, 2018, 67(22): 401-410.

Funding

National Key Laboratory Foundation (2024-CXPT-GF-JJ-013-02); Science and Technology Plan Project of Xi 'an (24GDW0023); Natural Science Basic Research Program of Shaanxi (2023-JC-YB-004)
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