Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells

XIN Yang, GUO Peng, LI Hao, CHEN Ren-de, SUN Li-li, MA Guan-shui, WANG Ai-ying

Surface Technology ›› 2020, Vol. 49 ›› Issue (6) : 22-33.

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Surface Technology ›› 2020, Vol. 49 ›› Issue (6) : 22-33. DOI: 10.16490/j.cnki.issn.1001-3660.2020.06.003
Special Topic—Study on Carbon-based Functional Films and Their Applications

Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells

  • XIN Yang1, GUO Peng2, LI Hao2, CHEN Ren-de2, SUN Li-li2, MA Guan-shui2, WANG Ai-ying3
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Abstract

In this work, the performances of bare metallic plate, traditional graphite plate and metallic bipolar plate modified with carbon-based coating used in the proton exchange membrane fuel cells (PEMFCs) were compared; the latest achievements of carbon-based coatings in improving the conductivity and corrosion resistance of metallic bipolar plates were reviewed; and issues such as performance degradation and limited life of carbon-based coatings were discussed, especially after long-term operation in PEMFCs environment. By analyzing the factors that affect the performance of carbon-based coatings, it was found that systematic researches on the relationship between microstructure of carbon-based coating and its performance were insufficient, leading to an unclear damage and degradation mechanism of a-C carbon coating/ metallic bipolar plate. The research progress of modified carbon-based coating materials for PEMFCs metal plates at home and abroad was mainly discussed, including improving the coating performance by adjusting the microstructure of carbon-based coatings (a-C); preparing metal-doped carbon coating (a-C:Me) by combing theoretical calculation with practice; solving the poor adhesion, high pressure stress and other issues between coating and special metallic matrix, design multi-layer structures to reduce penetrability defects. The failure mechanism of several kinds of coatings was discussed and the development trend of carbon-based coating technology for metallic plate modification was prospected.

Key words

proton exchange membrane fuel cell; bipolar plate; carbon-based film; conductivity; corrosion resistance

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XIN Yang, GUO Peng, LI Hao, CHEN Ren-de, SUN Li-li, MA Guan-shui, WANG Ai-ying. Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells[J]. Surface Technology. 2020, 49(6): 22-33

Funding

K. C. Wong Education Foundation (GJTD-2019-13); National Natural Science Foundation of China (51801226); Ningbo Science and Technology Innovation Project (2018B10014)
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