Research Progress of Adding Third Element and Nano-particle into Zn-Ni Alloy Coating

GAO Rong-long, XIANG Ke-you, LIN Jian-hua, XU Liang, LAN Yu-liang, SHAO Yan-jing, ZHU Li-qun

Surface Technology ›› 2018, Vol. 47 ›› Issue (10) : 262-268.

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Surface Technology ›› 2018, Vol. 47 ›› Issue (10) : 262-268. DOI: 10.16490/j.cnki.issn.1001-3660.2018.10.035
Coating Material and Technology

Research Progress of Adding Third Element and Nano-particle into Zn-Ni Alloy Coating

  • GAO Rong-long1, XIANG Ke-you1, LIN Jian-hua1, XU Liang1, LAN Yu-liang1, SHAO Yan-jing2, ZHU Li-qun3
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Abstract

The work introduces the electroplating Zn-Ni alloy coating of steel parts widely used in the automotive, aerospace and other industries and the better corrosion resistance and catalytic properties of zinc-nickel ternary alloy coating obtained by adding Fe, Co, Mn, Ce, P and other third elements to alkaline, chloride and other zinc-nickel alloy plating solution. The progress of adding nano-particles of silicon oxide, cerium oxide, titanium oxide, aluminum oxide and SiC into the Zn-Ni alloy plating bath is also introduced. The zinc-nickel composite coating containing nano-particles has higher corrosion resistance and wear resistance, high hardness, thermal stability, etc. The new research progress of multilayer coatings added with the third element and nano-particles in Zn-Ni alloy electroplating since 2016 is also introduced. Ni-P and Zn-Ni alloy multi-layer coatings deposited from Zn-Ni single bath can form Ni-P coating at low current density; while at higher current density, a Zn-Ni-P alloy coating with 3.2wt% P element can be deposited, thus greatly improving the corrosion resistance of steel parts. In addition, Ni-Co-SiC nano-composite plated on Zn-Ni containing Ni 12wt% is also introduced. This multi-layer structure can improve the adhesion of the coating and the corrosion resistance in 3.5wt% NaCl, and form a new attractive Zn-Ni alloy composite coating with high hardness and low wear.

Key words

Zn-Ni alloy coating; third element; nano-particle composite plating; corrosion resistance

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GAO Rong-long, XIANG Ke-you, LIN Jian-hua, XU Liang, LAN Yu-liang, SHAO Yan-jing, ZHU Li-qun. Research Progress of Adding Third Element and Nano-particle into Zn-Ni Alloy Coating[J]. Surface Technology. 2018, 47(10): 262-268

Funding

National Natural Science Foundation of China (U1637204)
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