Effects of Process Parameters on Morphology and Corrosion Resistance of Manganese Phosphating Film on 38MnVS Steel

MA Dong-wei, SHI Qiu-yue, YUAN Guo-min, LUO Cheng, WANG Min, HU Zhi-hua

Surface Technology ›› 2017, Vol. 46 ›› Issue (8) : 221-225.

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Surface Technology ›› 2017, Vol. 46 ›› Issue (8) : 221-225. DOI: 10.16490/j.cnki.issn.1001-3660.2017.08.036
Surface Failure and Protection

Effects of Process Parameters on Morphology and Corrosion Resistance of Manganese Phosphating Film on 38MnVS Steel

  • MA Dong-wei1, SHI Qiu-yue1, LUO Cheng1, WANG Min1, HU Zhi-hua1, YUAN Guo-min2
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Abstract

The work aims to obtain optimum process parameters of manganese phosphating film on 38MnVS steel by studying influence of phosphating temperature and time on morphology, film thickness and corrosion resistance of 38MnVS steel. Manganese phosphating film was prepared on the surface of 38MnVS provided with different phosphating temperature and time by controlling single-factor variables. Morphology, film thickness and corrosion resistance of 38MnVS steel phosphating film were analyzed using scanning electron microscope (SEM), thickness gauge and performing bronze sulfate pitting test. The phosphating film was heterogeneous nucleation and first formed on scratches and grain boundaries. As phosphating time prolonged, grains of the phosphating film covered the substrate surface quickly, and both film thickness and corrosion resistance increased continuously. Performance of the phosphating film changed slightly when phosphating time exceeded 15 min. At the phosphating temperature of below 75 ℃, growth of the film was inhibited, the film failed to cover the substrate, and the film thickness and corrosion resistance were low. As the phosphating temperature rose, the grains grew continuously, thickness and corrosion resistance increased rapidly. At the phosphating temperature of over 95 ℃, performance of the film increased slowly. The optimum phosphating process of 38MnVS steel is 85 ℃ and 15 min.

Key words

38MnVS steel; manganese phosphating film; phosphating temperature; phosphating time; surface morphology; corrosion resistance; film thickness

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MA Dong-wei, SHI Qiu-yue, YUAN Guo-min, LUO Cheng, WANG Min, HU Zhi-hua. Effects of Process Parameters on Morphology and Corrosion Resistance of Manganese Phosphating Film on 38MnVS Steel[J]. Surface Technology. 2017, 46(8): 221-225

Funding

Supported by the Outsatanding Young Scientific and Technological Innovation Team of Colleges and Universities in Hubei Province (T201518), the Innovative Training Program for College Students in Hubei Province (201510525005)
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