透明表面防除冰技术:进展、挑战与展望

牛一凡, 吴韬, 王拙汸, 陶幸福

表面技术 ›› 2026, Vol. 55 ›› Issue (18) : 158-178.

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PDF(11629 KB)
表面技术 ›› 2026, Vol. 55 ›› Issue (18) : 158-178. DOI: 10.16490/j.cnki.issn.1001-3660.2026.18.013
功能表面及技术

透明表面防除冰技术:进展、挑战与展望

  • 牛一凡*, 吴韬, 王拙汸, 陶幸福*
作者信息 +

Transparent Surface Anti-icing/Deicing Technologies: Progress, Challenges and Prospects

  • NIU Yifan*, WU Tao, WANG Zhuofang, TAO Xingfu*
Author information +
文章历史 +

摘要

透明防除冰材料因在建筑玻璃、航空风挡、光学传感器及光伏组件等领域兼具光学透过与防除冰功能而受到广泛关注。然而,在保持高可见光透过率的同时实现高效防冰与除冰仍面临显著挑战。近年来,集成超疏水、光热、电热等多种机制的透明协同防除冰材料迅速发展,通过主动-被动协同策略有效提升了延迟结冰、融冰和除冰效率,为突破透明性与防除冰性能之间的限制提供了新思路。本文针对“透明性约束下的多机制协同”的核心问题,概述了透明防除冰材料中被动防冰与主动除冰的基本机制,包括超疏水延迟结冰、低冰黏附超滑表面、光热融冰及电热除冰等,并分析了不同机制在透明体系中的适用性与局限性。在此基础上,归纳了多机制协同透明防除冰材料的构筑策略,总结了不同材料体系在透明性、防冰性能、除冰效率及协同效应等方面的特点。进一步结合建筑玻璃、航空透明部件、光学器件和光伏组件等应用场景,分析了透明协同防除冰材料的工程应用潜力。最后,归纳了当前透明防除冰材料在性能协同、复杂环境稳定性及规模化制备等方面面临的关键问题,并展望了仿生结构、智能响应材料及人工智能辅助设计的发展方向。该综述有助于深化对透明协同防除冰机制与设计规律的认识,并为高性能透明防除冰材料的理论设计与工程应用提供参考。

Abstract

Transparent anti-icing/deicing materials have attracted growing interest owing to their unique ability to simultaneously maintain optical transmittance and mitigate ice accretion in applications such as construction glass, aircraft windshields, optical sensors, and photovoltaic modules, where both visibility and operational safety are critically required. Nevertheless, achieving efficient anti-icing and deicing performance without sacrificing high visible-light transmittance remains a major challenge. In recent years, transparent materials integrating multiple functionalities, including superhydrophobicity, photothermal conversion, and electrothermal heating, have developed rapidly. By coupling passive anti-icing with active deicing strategies, these systems have demonstrated enhanced icing-delay capability, accelerated ice melting, and improved ice removal efficiency, thereby offering a promising route to address the long-standing trade-off between transparency and ice-management performance.
With a focus on the critical challenge of achieving multi-mechanism synergy under transparency constraints, the fundamental mechanisms governing passive anti-icing in transparent materials are first outlined, encompassing superhydrophobic surfaces that delay ice nucleation through nanoscale interfacial engineering and slippery liquid-infused porous surfaces (SLIPS) that minimize ice adhesion via liquid-like lubrication layers. Then, active deicing strategies based on photothermal and electrothermal conversion are also systematically analyzed, with a particular emphasis on spectrally selective absorption that enables efficient heat generation without compromising visible-light transmittance. The applicability and inherent limitations of these mechanisms in transparent systems are also critically evaluated. Furthermore, this work highlights the synergistic interactions among different mechanisms elucidating how the integration of passive and active approaches to improve icing-delay capability, reduce ice adhesion strength, and rapid thermal deicing.
Subsequently, the design and fabrication strategies of transparent synergistic anti-icing/deicing materials are comprehensively summarized. Typical fabrication methods, including etching, templating, chemical vapor deposition, electrospinning, sol-gel processing, and spray coating, are comparatively analyzed from construction path, structural controllability, and engineering applicability. The relationships between micro/nano structure dimensions and optical properties are further discussed to clarify how subwavelength structures can suppress light scattering while maintaining excellent hydrophobicity or thermal conversion capability.
Furthermore, the application prospects of transparent synergistic anti-icing/deicing materials in representative scenarios are discussed in detail. In multiple fields such as transportation, power energy, intelligent buildings, etc., transparent synergistic anti-icing/deicing materials can be applied to the surfaces of automotive windshields, solar photovoltaic modules, smart building glass, etc. Different application scenarios have significantly different performance requirements for materials. Therefore, it's a key research issue to achieve a reasonable balance among multiple performance requirements and achieve targeted optimization through structural control and functional integration.
Finally, the major challenges and future development trends of transparent synergistic anti-icing/deicing materials are summarized. Although remarkable progress has been achieved, several critical issues still hinder their practical implementation, including insufficient long-term durability under repeated icing/deicing cycles, the trade-off between transparency and anti-icing/deicing efficiency, and difficulties associated with scalable and low-cost fabrication. Future research aims to continue along the lines of multi-mechanism coupling and collaboration, systematic integrated design, and improved engineering reliability. Development direction will focus on additional functional collaboration integration, biomimetic structural design, smart responsive materials, and artificial-intelligence-assisted materials development. This review is expected to provide a systematic understanding of the mechanisms and design principles of transparent synergistic anti-icing/deicing material. It points out the problems existing in current research, and provide useful guidance for the theoretical design and practical implementation of high-performance transparent ice-management systems.

关键词

透明防除冰材料 / 多机制协同 / 超疏水防冰 / 光热除冰 / 电热除冰

Key words

transparent anti-icing/deicing materials / multi-mechanism synergy / superhydrophobic anti-icing / photothermal deicing / electrothermal deicing

引用本文

导出引用
牛一凡, 吴韬, 王拙汸, 陶幸福. 透明表面防除冰技术:进展、挑战与展望[J]. 表面技术. 2026, 55(18): 158-178
NIU Yifan, WU Tao, WANG Zhuofang, TAO Xingfu. Transparent Surface Anti-icing/Deicing Technologies: Progress, Challenges and Prospects[J]. Surface Technology. 2026, 55(18): 158-178
中图分类号: TB34   

参考文献

[1] REKUVIENE R, SAEIDIHARZAND S, MAŽEIKA L, et al. A Review on Passive and Active Anti-Icing and De-Icing Technologies[J]. Applied Thermal Engineering, 2024, 250: 123474.
[2] 郭时毅, 安江峰, 吴军, 等. 风力发电机叶片覆冰机理及防除冰技术研究进展[J]. 表面技术, 2024, 53(12): 50-65.
GUO S Y, AN J F, WU J, et al.Research Progress of Wind Turbine Blade Ice-Covering Mechanism and Anti-Icing Technology[J]. Surface Technology, 2024, 53(12): 50-65.
[3] 胡琴, 王欢, 舒立春, 等. 覆冰条件下风力发电机叶片防/除冰方法综述[J]. 电工技术学报, 2024, 39(17): 5482-5496.
HU Q, WANG H, SHU L C, et al.Review of Anti-/de-Icing Methods for Wind Turbine Blades under Icing Conditions[J]. Transactions of China Electrotechnical Society, 2024, 39(17): 5482-5496.
[4] HE Z W, XIE H M, JAMIL M I, et al.Electro-/Photo-Thermal Promoted Anti-Icing Materials: A New Strategy Combined with Passive Anti-Icing and Active De-Icing[J]. Advanced Materials Interfaces, 2022, 9(16): 2200275.
[5] SU X J, LI H Q, LAI X J, et al.Vacuum-Assisted Layer- by-Layer Superhydrophobic Carbon Nanotube Films with Electrothermal and Photothermal Effects for Deicing and Controllable Manipulation[J]. Journal of Materials Chemistry A, 2018, 6(35): 16910-16919.
[6] DENG Y T, DU F, CHEN Z B, et al.Functionalized Superhydrophobic Coatings with Electro-Photothermal Effect for All-Day Durable Anti-Icing[J]. Advanced Materials Interfaces, 2024, 11(11): 2300869.
[7] PENG S L, XIAO X, WEI J, et al.Superhydrophobic Coating with Electro-Photo-Thermal Conversion Properties for All-Weather Anti-Icing[J]. Solar Energy, 2024, 270: 112384.
[8] WU X H, TANG Y X, SILBERSCHMIDT V V, et al.Mechanically Robust Transparent Anti-Icing Coatings: Roles of Dispersion Status of Titanate Nanotubes[J]. Advanced Materials Interfaces, 2018, 5(18): 1800773.
[9] SALEEM A, AWAD A, MAZEN A, et al.Estimating Snow Coverage Percentage on Solar Panels Using Drone Imagery and Machine Learning for Enhanced Energy Efficiency[J]. Energies, 2025, 18(7): 1729.
[10] WU S W, LIANG Z Y, LI Y P, et al.Transparent, Photothermal, and Icephobic Surfaces via Layer-by-Layer Assembly[J]. Advanced Science, 2022, 9(14): 2105986.
[11] TRIPATHI D, RAY P, SINGH A V, et al.Durability of Slippery Liquid-Infused Surfaces: Challenges and Advances[J]. Coatings, 2023, 13(6): 1095.
[12] LI Z Y, LIU Y Z, LIU Y B, et al.Robust Transparent Photothermal Omniphobic Coating for Efficient Anti/Deicing and Antifogging[J]. ACS Applied Materials & Interfaces, 2024, 16(27): 35805-35814.
[13] WEI H, LUO H H, FAN W W, et al.A Passive-Active Anti/Deicing Coating Integrating Superhydrophobicity, Thermal Insulation, and Photo/Electrothermal Conversion Effects[J]. ACS Applied Materials & Interfaces, 2024, 16(27): 35613-35625.
[14] WANG L Y, LIU M M, YADAV A, et al.A Method for Preparing and Investigating Anti-/de-Icing Surface by Integration of Laser-Induced Graphene (LIG) with a Silica Sol Adhesive (SMP@M-SiO2)[J]. Surface and Coatings Technology, 2023, 474: 130111.
[15] WEI X P, CAI F G, WANG J.Electrothermal/Photothermal Superhydrophobic Coatings Based on Micro/Nano Graphite Flakes for Efficient Anti-Icing and De-Icing[J]. Progress in Organic Coatings, 2023, 182: 107696.
[16] LI H, WANG Z H, TU H Y, et al.Leaf Vein-Inspired Transparent Superhydrophobic Coatings with High Stability[J]. Science China Materials, 2025, 68(4): 1203-1211.
[17] 王斯楠. SiO2气凝胶基透明超疏水涂层的制备及性能研究[D]. 南宁: 广西大学, 2024.
WANG S N.Preparation and Properties of SiO2 Aerogel- based Transparent Superhydrophobic[D]. Nanning: Guangxi University, 2024. Coatings[D]. Guangxi: Guangxi University, 2024: 2.
[18] QIN L G, WU Y H, MA Z Y, et al.Fluorine-Free and Highly Durable Superhydrophobic Textiles for Antifouling and Anti-Icing Applications[J]. ACS Applied Polymer Materials, 2023, 5(8): 6278-6287.
[19] KARUNAKARAN R G, LU C H, ZHANG Z H, et al.Highly Transparent Superhydrophobic Surfaces from the Coassembly of Nanoparticles (≤100 nm)[J]. Langmuir, 2011, 27(8): 4594-4602.
[20] XIANG Q, LIU H Q, HUANG M, et al.A Superhydrophobic Composite Coating with Transparency, Long- Term Durability and Self-Healing Properties for Cleaning of Photovoltaic Systems[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2025, 716: 136666.
[21] 邱豪楠, 刘威, 唐悦, 等. 仿生超滑涂层研究进展[J]. 清华大学学报(自然科学版), 2024, 64(3): 393-408.
QIU H N, LIU W, TANG Y, et al.Research Progress in Bioinspired Slippery Coatings[J]. Journal of Tsinghua University (Science and Technology), 2024, 64(3): 393-408.
[22] WANG J, WU M J.Study on Durable Icephobic Surfaces Modified with Phase Change Oil Impregnation[J]. Surface and Coatings Technology, 2024, 481: 130646.
[23] BAKHTIARI M, BAKHSHANDEH E, JAFARI R, et al.Enhancing Anti-Icing Efficacy in Hybrid Polyurethane Coatings: Evaluating the Significance of Molecular Weight, Chemical Structure, and Content of PEG/PDMS[J]. Applied Surface Science, 2025, 684: 161951.
[24] HUANG B L, JIANG S S, DIAO Y H, et al.Hydrogels as Durable Anti-Icing Coatings Inhibit and Delay Ice Nucleation[J]. Molecules, 2020, 25(15): 3378.
[25] 王硕. 中空玻璃微球基光热转换材料的制备及其太阳能界面蒸发性能研究[D]. 兰州: 兰州理工大学, 2022: 8.
WANG S.Preparation of Hollow Glass Microspheres Based Photothermal Conversion Materials and Their Solar-driven Interface Evaporation Performance[D]. Lanzhou: Lanzhou University of Technology, 2022: 8.
[26] 杨道征. 柔性透明MXene基光热转换薄膜的制备和性能研究[D]. 郑州: 郑州大学, 2021: 12-13.
YANG D Z.Preparation and Research on Flexible Transparent Mxene-Based Film with Photothermal Energy Conversion Performance[D]. Zhengzhou: Zhengzhou University, 2021: 12-13.
[27] LIU H, HAN L L, DUAN X G, et al.Photothermal Catalytic C1 Conversion on Supported Catalysts[J]. Energy Advances, 2023, 2(10): 1541-1564.
[28] 要鹏, 杨睿, 濮金欢, 等. 基于等离激元颗粒的透明光热防/除冰薄膜研究[J]. 工程热物理学报, 2024, 45(9): 2767-2772.
YAO P, YANG R, PU J H, et al.Study on Plasmonic Nanoparticles-Based Photothermal Films for Transparent Anti/de-Icing[J]. Journal of Engineering Thermophysics, 2024, 45(9): 2767-2772.
[29] 张静. 三氧化二钛基光热转换涂层的制备及其性能研究[D]. 陕西: 陕西科技大学, 2024: 6.
ZHANG J.Preparation and Performance Research of Titanium Trioxide-based Photothermal Conversion Coating[D]. Shaanxi: Shaanxi University of Science & Technology, 2024: 6.
[30] LI W H, LIN C J, MA W, et al.Transparent Selective Photothermal Coatings for Antifogging Applications[J]. Cell Reports Physical Science, 2021, 2(5): 100435.
[31] ZHANG Y, YAO F, TU H, et al.One-Piece Insulating Superhydrophobic Photothermal Coating for Suppression of Icing and Thermal Aging of Wind Turbine Blades[J]. Progress in Organic Coatings, 2025, 209: 109630.
[32] WU X L, WANG Y, LI J, et al.Durable and Ultra-Black Superhydrophobic Coatings for High-Efficiency Photothermal Applications under Harsh Conditions[J]. Advanced Optical Materials, 2026, 14(7): e03714.
[33] LIU Z L, XU Q, XU N, et al.Construction of Photothermal Superhydrophobic Coating with Carbon Black- Copper Oxide Gradient Heterostructure Synergistic Modulation and Efficient Anti/de-Icing Performance Investigation[J]. Applied Thermal Engineering, 2025, 280: 128406.
[34] LI L T, ZHAO Z H, JI X Y, et al.Constructing Entwined TiN@CNT Hybrid Network via Hydrogen Bonding Self-Assembly towards Photothermal and Durable Superhydrophobic Anti-/de-Icing[J]. Chemical Engineering Journal, 2025, 518: 164805.
[35] LIAN W R, CHEN H J, WANG X, et al.Near- Quantitative Photothermal Conversion in Non-Fluorescent Diradicaloid Organic Molecules for Efficient Solar Energy Harvesting[J]. Advanced Materials, 2025, 37(42): e11877.
[36] HU W B, SHENG H Q, ZHAO W W, et al.Spectrally Engineered Hierarchical Nanocomposite Enabling Full-Spectrum Solar-Thermal Conversion and Dynamic Anti-/de-Icing in Harsh Environments[J]. Small, 2026, 22(7): e10191.
[37] 安燕, 荆永良, 刘涛, 等. 聚苯胺光热超疏水防冰涂层的制备及其防冰除冰性能[J]. 中国腐蚀与防护学报, 2024, 44(6): 1485-1494.
AN Y, JING Y L, LIU T, et al.Preparation, Anti-Icing and De-Icing Performance of Polyaniline Photothermal Superhydrophobic Anti-Icing Coating[J]. Journal of Chinese Society for Corrosion and Protection, 2024, 44(6): 1485-1494.
[38] 王富强. 高透光率纳米级柔性电热膜的制备及性能研究[D]. 大连: 大连理工大学, 2022: 2-8.
WANG F Q.Study on Preparation and Performance of Nano-Scale Flexible Electric Heating Films with High Light Transmittance[D]. Dalian: Dalian University of Technology, 2022: 2-8.
[39] 朱一方. ATO透明电热薄膜的制备与性能研究[D]. 广州: 华南理工大学, 2023: 4-9.
ZHU Y F.Preparation and Properties of ATO Transparent Electrothermal Film[D]. Guangzhou: South China University of Technology, 2023: 4-9.
[40] YE Y J, BAI Y, ZHOU P D, et al.All Polymer-Based Transparent Composites for Electrothermal Actuator and Supercapacitor[J]. Journal of Applied Polymer Science, 2023, 140(5): e53392.
[41] KIM Y R, JUNG J H, YONG S M, et al.Design of Patterned Fluorine-Doped Tin Oxide for Radome De-Icing Heater[J]. Journal of Physics D: Applied Physics, 2021, 54(10): 105301.
[42] QIAN P F, WANG T, GENG W H, et al.All-Solution Processed Layer-by-Layer Deposition of Multifunctional Flexible Transparent Conductive Films with Ultra-High Adhesion[J]. Surfaces and Interfaces, 2025, 70: 106830.
[43] ALTINKOK A, OLUTAS M, ALTINKOK S.Investigation of Electrothermal Properties of Indium-Tin-Oxide Thin Films[J]. Modern Physics Letters B, 2024, 38(25): 2450229.
[44] KWON G, KO Y, LEE K, et al.Flexible and Transparent Cellulose-Based Electrothermal Composites for High- Performance Heaters[J]. Cellulose, 2024, 31(1): 335-347.
[45] GUPTA R, RAO K D, SRIVASTAVA K, et al.Spray Coating of Crack Templates for the Fabrication of Transparent Conductors and Heaters on Flat and Curved Surfaces[J]. ACS Applied Materials & Interfaces, 2014, 6(16): 13688-13696.
[46] WANG Y H, DU D X, YANG X, et al.Optoelectronic and Electrothermal Properties of Transparent Conductive Silver Nanowires Films[J]. Nanomaterials, 2019, 9(6): 904.
[47] 徐婉婷. 碳纳米管透明导电薄膜电热特性及其在建筑家居中的应用[J]. 居舍, 2024(16): 88-90.
XU W T.Electrothermal Characteristics of Carbon Nanotube Transparent Conductive Film and Its Application in Architecture and Home[J]. JU SHE, 2024(16): 88-90.
[48] SUI D, HUANG Y, HUANG L, et al.Flexible and Transparent Electrothermal Film Heaters Based on Graphene Materials[J]. Small, 2011, 7(22): 3186-3192.
[49] LIU J L, YANG H Y, et al.Ultrafast Transparent Defogger Based on High-Quality Graphene Film Directly Grown via Copper Vapor-Assisted Method[J]. ACS Applied Energy Materials, 2025, 8(8): 5334-5342.
[50] 刘代军, 陈亚莉. 用于波音787的新型复合材料机翼除冰系统[J]. 航空制造技术, 2009, 52(17): 82-83.
LIU D J, CHEN Y L.Application of New Type of Composite Wing Deicing System in Boeing 787[J]. Aeronautical Manufacturing Technology, 2009, 52(17): 82-83.
[51] 陈磊, 王榆淞, 张军, 等. 飞机气动除冰系统试验研究[J]. 南京航空航天大学学报, 2024, 56(2): 300-306.
CHEN L, WANG Y S, ZHANG J, et al.Experimental Research on Pneumatic De-Icing Systems of Aircraft[J]. Journal of Nanjing University of Aeronautics & Astronautics, 2024, 56(2): 300-306.
[52] 何舟东, 朱永峰, 周景锋. 飞机电脉冲除冰技术探讨[J]. 实验流体力学, 2016, 30(2): 38-45.
HE Z D, ZHU Y F, ZHOU J F.Study on Electro-Impulse De-Icing Technology[J]. Journal of Experiments in Fluid Mechanics, 2016, 30(2): 38-45.
[53] 董文俊, 张永杰, 赵宾宾. 飞机电脉冲除冰技术研究进展[J]. 山东工业技术, 2015(16): 185-186.
DONG W J, ZHANG Y J, ZHAO B B.Research Progress of Aircraft Electrical Pulse Deicing Technology[J]. Shandong Industrial Technology, 2015(16): 185-186.
[54] 夏祖西, 彭华乔, 苏正良, 等. 机场除冰液对水环境影响的研究进展[J]. 四川环境, 2009, 28(1): 54-56.
XIA Z X, PENG H Q, SU Z L, et al.Study Progress in Impact of Airport De-Icing Fluid on Water Environment[J]. Sichuan Environment, 2009, 28(1): 54-56.
[55] TORUN I, CELIK N, KIREMITLER N B, et al.Fully Transparent and Superhydrophobic Electrodes Enabled by Soft Interfaces[J]. Surfaces and Interfaces, 2023, 36: 102576.
[56] WANG Y M, ZHANG K T, CUI X X, et al.A Transparent Photo/Electrothermal Composite Coating with Liquid- Like Slippery Property for All-Day Anti-/de-Icing[J]. ACS Applied Materials & Interfaces, 2024, 16(31): 41400-41408.
[57] ZHAO Z H, WANG Y M, WANG Z, et al.A New Composite Material with Energy Storage, Electro/Photo- Thermal and Robust Super-Hydrophobic Properties for High-Efficiency Anti-Icing/de-Icing[J]. Small, 2024, 20(31): 2311435.
[58] 郭贵静, 王优强, 张海洋, 等. TiO2/HWCNTs光热超疏水复合涂层防覆冰/除冰性能[J]. 表面技术, 2026, 55(2): 221-232.
GUO G J, WANG Y Q, ZHANG H Y, et al.Anti-Icing/de-Icing Performance of Photothermal Superhydrophobic TiO2/HWCNTS Composite Coatings[J]. Surface Technology, 2026, 55(2): 221-232.
[59] ZHANG J H, SINGH V, KABI P, et al.Reticular Photothermal Traps Enabling Transparent Coatings with Exceptional All-Day Icephobicity[J]. Nano Today, 2025, 62: 102673.
[60] WANG J Y, LI P H, YU P, et al.Efficient Photothermal Deicing Employing Superhydrophobic Plasmonic MXene Composites[J]. Advanced Composites and Hybrid Materials, 2022, 5(4): 3035-3044.
[61] TONG W, HAN M M, MA C, et al.Empowering Photovoltaic Panel Anti-Icing: Superhydrophobic Organic Composite Coating with in Situ Photothermal and Transparency[J]. ACS Applied Materials & Interfaces, 2024, 16(24): 31567-31575.
[62] 彭健, 周娟, 韦红草, 等. 超疏水涂层在防除冰领域的研究进展[J]. 表面技术, 2025, 54(5): 1-26.
PENG J, ZHOU J, WEI H C, et al.Research Progress of Anti-Icing/Deicing with Superhydrophobic Coating[J]. Surface Technology, 2025, 54(5): 1-26.
[63] WANG P, YAO T, LI Z Q, et al.A Superhydrophobic/Electrothermal Synergistically Anti-Icing Strategy Based on Graphene Composite[J]. Composites Science and Technology, 2020, 198: 108307.
[64] HAN J T, KIM S Y, WOO J S, et al.Transparent, Conductive, and Superhydrophobic Films from Stabilized Carbon Nanotube/Silane Sol Mixture Solution[J]. Advanced Materials, 2008, 20(19): 3724-3727.
[65] ZHOU B, LI Z Y, LI Y L, et al.Flexible Hydrophobic 2D Ti3C2Tx-Based Transparent Conductive Film with Multifunctional Self-Cleaning, Electromagnetic Interference Shielding and Joule Heating Capacities[J]. Composites Science and Technology, 2021, 201: 108531.
[66] LI S T, LIU Z F, PAN X L, et al.Boosting Thermal Generation in Cation-Exchanged Transparent MXene Composite Films with Hierarchical Wrinkled Structure[J]. ACS Applied Materials & Interfaces, 2025, 17: 6793-6804.
[67] GUO Y, ZHAO H B, ZHANG C S, et al.Super Photothermal/Electrothermal Response and Anti-Icing/Deicing Capability of Superhydrophobic Multi-Walled Carbon Nanotubes/Epoxy Coating[J]. Chemical Engineering Journal, 2024, 497: 154383.
[68] MA T, MA J H, YANG C, et al.Robust, Multiresponsive, Superhydrophobic, and Oleophobic Nanocomposites via a Highly Efficient Multifluorination Strategy[J]. ACS Applied Materials & Interfaces, 2021, 13(24): 28949-28961.
[69] 李玥, 卢亚妹, 王鹏飞, 等. 透明超疏水材料的制备及其应用[J]. 化学进展, 2021, 33(12): 2362-2377.
LI Y, LU Y M, WANG P F, et al.Preparation and Application of Transparent Superhydrophobic Materials[J]. Progress in Chemistry, 2021, 33(12): 2362-2377.
[70] 崔忠刚. 新型透明导电电极的模板法构筑及其光电特性[D]. 开封: 河南大学, 2012: 15.
CUI Z G.Photo-electric Properties of the New Type Transparent Conductive Electrodes Fabricated by Nanosphere Lithography[D]. Kaifeng: Henan University, 2012: 15.
[71] 于勃. 透明超疏水/超双疏涂层的制备及性能研究[D]. 兰州: 兰州理工大学, 2017: 9-10.
YU B.Preparation and Performance of Transparent Superhydrophobic Coatings and Transparent Superamphiphobic Coatings[D]. Lanzhou: Lanzhou University of Technology, 2017: 9-10.
[72] OGAWA K, SOGA M, TAKADA Y, et al.Development of a Transparent and Ultrahydrophobic Glass Plate[J]. Japanese Journal of Applied Physics, 1993, 32(4B): L614.
[73] WANG B, HUA Y Q, YE Y X, et al.Transparent Superhydrophobic Solar Glass Prepared by Fabricating Groove-Shaped Arrays on the Surface[J]. Applied Surface Science, 2017, 426: 957-964.
[74] 张耀. 银嵌入型FTO基透明导电薄膜的制备与性能研究[D]. 镇江: 江苏大学, 2020: 67.
ZHANG Y.Research on Preparation and Properties of Ag Embedded FTO-based Transparent Conductive Film[D]. Zhenjiang: Jiangsu University, 2020: 67.
[75] 肖荣诗, 张寰臻, 黄婷. 飞秒激光加工最新研究进展[J]. 机械工程学报, 2016, 52(17): 176-186.
XIAO R S, ZHANG H Z, HUANG T.Recent Progress in Femtosecond Pulsed Laser Processing Research[J]. Journal of Mechanical Engineering, 2016, 52(17): 176-186.
[76] 汪超炜. 多材料飞秒激光微加工技术及其应用研究[D]. 合肥: 中国科学技术大学, 2019: 2-5.
WANG C W.Research on femtosecond laser microfabrication for various materials and their applications[D]. Hefei: University of Science and Technology of China, 2019: 2-5.
[77] 林义. 超快激光制备高透光超疏水玻璃及稳定性和耐久性研究[D]. 北京: 清华大学, 2018: 69.
LIN Y.Exceptionally Transparent Superhydrophobic Glass Surfaces Fabricated by Ultrafast Laser and Their Stability and Durability[D]. Beijing: Tsinghua University, 2018: 69.
[78] 石小凤. 透明导电掺铝氧化锌薄膜的制备修饰及其自清洁性能研究[D]. 哈尔滨: 哈尔滨工业大学, 2013: 9.
SHI X F.Preparation and modification of Transparent Conductive Aluminium Doped Zinc Oxide Thin Films and Their Self-Cleaning Property[D]. Harbin: Harbin Institute of Technology, 2013: 9.
[79] 湛位. 透明超疏水多孔玻璃制备及其性能研究[D]. 南京: 东南大学, 2018: 71.
ZHAN W.Preparation and Properties of Transparent Super Hydrophobic Porous Glass[D]. Nanjing: Southeast University, 2018: 71.
[80] FEI L, HE Z Z, LACOSTE J D, et al.A Mini Review on Superhydrophobic and Transparent Surfaces[J]. The Chemical Record, 2020, 20(11): 1257-1268.
[81] 胡沛然. 基于纤维模板的柔性导电材料制备及其性能研究[D]. 上海: 东华大学, 2012: 9-13.
HU P R.Synthesis and Properties of Flexible Conductive Materials Based on Fibre Template[D]. Shanghai: Donghua University, 2012: 9-13.
[82] 薛小丹, 马剑钢, 徐海阳, 等. 电镀法制备基于龟裂网格模板的柔性ITO/Au网格复合透明加热膜[J]. 中国科技论文, 2017, 12(16): 1876-1880.
XUE X D, MA J G, XU H Y, et al.Fabrication of ITO/Au Mesh Composite Film as Flexible and Transparent Heaters by an Electroplating Process Based Crack Template[J]. China Sciencepaper, 2017, 12(16): 1876-1880.
[83] 肖宗湖, 王新莲, 韩春, 等. 裂纹模板法制备的金属网栅透明导电薄膜光电性能[J]. 新余学院学报, 2018, 23(1): 1-5.
XIAO Z H, WANG X L, HAN C, et al.Photoelectric Properties of Transparent Conductive Metal Mesh Prepared by Crack Template[J]. Journal of XinYu College, 2018, 23(1): 1-5.
[84] GONG D W, LONG J Y, JIANG D F, et al.Robust and Stable Transparent Superhydrophobic Polydimethylsiloxane Films by Duplicating via a Femtosecond Laser- Ablated Template[J]. ACS Applied Materials & Interfaces, 2016, 8(27): 17511-17518.
[85] LI H, TU S H, TU H Y, et al.Construction of Transparent, Robust and Haze-Selectable Superhydrophobic Coatings with Honeycomb Structure[J]. Chemical Engineering Journal, 2024, 483: 149319.
[86] 王培壮. 甲壳素纳米纤维的制备及其透明涂层疏水疏油改性机理研究[D]. 长春: 吉林大学, 2023: 20-21.
WANG P Z.Preparation of Chitin Nanofibers and Study on Amphiphobic Modification Mechanism of Their Transparent Coatings[D]. Changchun: Jilin University, 2023: 20-21.
[87] 沈可可, 吕晓猛, 贾瑛, 等. 透明超疏水表面的研究进展[J]. 表面技术, 2021, 50(9): 108-119.
SHEN K K, LYU X M, JIA Y, et al.Research Progress of Transparent and Super-Hydrophobic Surface[J]. Surface Technology, 2021, 50(9): 108-119.
[88] 尹婉莹. 基于纳米减反结构调控石墨烯复合透明导电薄膜光电及润湿性能研究[D]. 上海: 华东师范大学, 2023: 67-68.
YIN W Y.Research on Photoelectric and Wettability Performance of Graphene Composite Transparent Conductive Films Based on Antireflection Nano Structure[D]. Shanghai: East China Normal University, 2023: 67-68.
[89] 岳盈. 透明导电碳纳米薄膜的大面积制备与光电探测研究[D]. 北京: 中国科学院大学(中国科学院物理研究所), 2024: 20-21.
YUE Y.Study on Large-Area Preparation and Photodetection of Transparent Conductive Carbon Nanofilms[D]. Beijing: Chinese Academy of Sciences(Institute of Physics), 2024: 20-21.
[90] ZHANG Y, YANG F, LIU H, et al.Transparent Heaters Based on CVD Grown Few-Layer Graphene[J]. Journal of Materials Science: Materials in Electronics, 2022, 33(7): 3586-3594.
[91] ZHUANG A Y, LIAO R J, DIXON S C, et al.Transparent Superhydrophobic PTFE Films via One-Step Aerosol Assisted Chemical Vapor Deposition[J]. RSC Advances, 2017, 7(47): 29275-29283.
[92] 刘秋丽. 纤维基柔性光学透明薄膜的制备及防眩性能研究[D]. 长春: 吉林大学, 2024: 7-8+63.
LIU Q L. Preparation and Anti-glare Performance Study of Flexible Optical Transparent Films Based on Fibers Matrix[D]. Changchun: Jilin University, 2024: 7-8+63.
[93] GANESH V A, NAIR A S, RAUT H K, et al.Superhydrophobic Fluorinated POSS-PVDF-HFP Nanocomposite Coating on Glass by Electrospinning[J]. Journal of Materials Chemistry, 2012, 22(35): 18479.
[94] 杨立宁. ITO透明导电薄膜的电纺丝制备工艺研究[D]. 河北: 石家庄铁道大学, 2012: 54.
YANG L N.Study on Preparation Process of ITO Thin Film by Electrospinning[D]. Hebei: Shijiazhuang Tiedao University, 2012: 54.
[95] YOSHIKAWA R, TENJIMBAYASHI M, MATSUBAYASHI T, et al.Designing a Flexible and Transparent Ultrarapid Electrothermogenic Film Based on Thermal Loss Suppression Effect: A Self-Fused Cu/Ni Composite Junctionless Nanonetwork for Effective Deicing Heater[J]. ACS Applied Nano Materials, 2018, 1(2): 860-868.
[96] LI H X, CHEN Y D, WU T, et al.Light-Induced Welding of Electrospun Poly(ε-Caprolactone) Nanofibers in a Nonwoven Mat by Leveraging the Photothermal Effect of Gold Nanocages[J]. Macromolecular Rapid Communications, 2025, 46(13): 2401144.
[97] 孙英纯, 刘如, 徐建峰, 等. 绿色环保型超疏水涂层的研究进展[J]. 表面技术, 2023, 52(9): 63-78.
SUN Y C, LIU R, XU J F, et al.Research Progress and Development Trend of Green and Environmental Friendly Superhydrophobic Coating[J]. Surface Technology, 2023, 52(9): 63-78.
[98] JIANG Z Q, SUN Y X, YAN M M, et al.Recent Advancements in Fabrication Strategies and Applications of Superhydrophobic Coatings[J]. Journal of Materials Science, 2025, 60(19): 7826-7858.
[99] 王春云. 溶胶-凝胶法功能膜的成膜技术及其应用[J]. 化工新型材料, 2000, 28(3): 26-29.
WANG C Y.Membrane Forming Technology of Sol-Gel Functional Membrane and Its Application[J]. New Chemical Materials, 2000, 28(3): 26-29.
[100] 赵立强, 南泉, 全贞兰, 等. 溶胶-凝胶法制备超疏水表面的研究进展[J]. 低温与特气, 2015, 33(5): 1-5.
ZHAO L Q, NAN Q, QUAN Z L, et al.Research Progress in Super-Hydrophobic Surface Fabricated by Sol-Gel Method[J]. Low Temperature and Specialty Gases, 2015, 33(5): 1-5.
[101] 张力, 王健农, 许前锋. 溶胶-凝胶法制备透明超疏水性SiO2涂层[J]. 材料导报, 2008, 22(S3): 112-114.
ZHANG L, WANG J N, XU Q F.Preparation of Transparent Superhydrophobic SiO2 Film by Sol-Gel Technique[J]. Materials Review, 2008, 22(S3): 112-114.
[102] NOMEIR B, LAKHOUIL S, BOUKHEIR S, et al.Durable and Transparent Superhydrophobic Coating with Temperature-Controlled Multi-Scale Roughness for Self- Cleaning and Anti-Icing Applications[J]. Progress in Organic Coatings, 2024, 189: 108338.
[103] DUAN Y T, HOU G Y, GUO B, et al.“a Shield” for Solar Panels in Cold and Dusty Environments: A Bifunctional Transparent Anti-Icing and Anti-Dust Coating[J]. Progress in Organic Coatings, 2026, 212: 109839.
[104] WANG F J, YU S, OU J F, et al.Anti-Icing Performance of Transparent and Superhydrophobic Surface under Wind Action[J]. Journal of Sol-Gel Science and Technology, 2015, 75(3): 625-634.
[105] ZHU T X, CHENG Y, HUANG J Y, et al.A Transparent Superhydrophobic Coating with Mechanochemical Robustness for Anti-Icing, Photocatalysis and Self-Cleaning[J]. Chemical Engineering Journal, 2020, 399: 125746.
[106] ALLAHDINI A, JAFARI R, MOMEN G.Transparent Non-Fluorinated Superhydrophobic Coating with Enhanced Anti-Icing Performance[J]. Progress in Organic Coatings, 2022, 165: 106758.
[107] ZHOU B, SU M J, YANG D Z, et al.Flexible MXene/Silver Nanowire-Based Transparent Conductive Film with Electromagnetic Interference Shielding and Electro- Photo-Thermal Performance[J]. ACS Applied Materials & Interfaces, 2020, 12(36): 40859-40869.
[108] 陈翠玉. 银纳米线柔性透明导电膜的制备及其光电、机械性能研究[D]. 镇江: 江苏大学, 2016: 14.
CHEN C Y.Prepararion and Photoelectric, Mechanical Properties of Silver Nanowire Flexible Transparent Conductive Films[D]. Zhenjiang: Jiangsu University, 2016: 14.
[109] 方袁烽, 周锰濛, 李萌, 等. 超疏水透明涂层制备方法研究进展[J]. 杭州师范大学学报(自然科学版), 2020, 19(3): 239-243.
FANG Y F, ZHOU M M, LI M, et al.On the Preparation Methods of Superhydrophobic Transparent Coating[J]. Journal of Hangzhou Normal University (Natural Sciences Edition), 2020, 19(3): 239-243.
[110] 郝赛赛. 光热超疏水表面的制备及防/除冰性能研究[D]. 江苏: 江苏理工学院, 2024: 3-5.
HAO S S.Research on Preparation and Anti/De-icing Performance of Photothermal Superhydrophobic Surfaces[D]. Jiangsu: Jiangsu University of Technology, 2024: 3-5.
[111] GAO H, YIN T J, MA J Y, et al.Research Progress of Photothermal Superhydrophobic Surfaces for Anti-Icing/Deicing[J]. Molecules, 2025, 30(9): 1865.
[112] 马维, 李洋, 姚舒怀, 等. 光热防冰防霜防雾表面近期研究进展[J]. 物理学报, 2022, 71(8): 341-351.
MA W, LI Y, YAO S H, et al.Recent Advances in Solar- Thermal Surfaces for Anti-Icing/Anti-Frosting/Anti- Fogging[J]. Acta Physica Sinica, 2022, 71(8): 341-351.
[113] CHEONG W S, KIM Y H, LEE J M, et al.High- Performance Transparent Electrodes for Automobile Windshield Heaters Prepared by Combining Metal Grids and Oxide/Metal/Oxide Transparent Electrodes[J]. Advanced Materials Technologies, 2019, 4(4): 1800550.
[114] CHEN X L, NIE S H, GUO W R, et al.Printable High-Aspect Ratio and High-Resolution Cu Grid Flexible Transparent Conductive Film with Figure of Merit over 80 000[J]. Advanced Electronic Materials, 2019, 5(5): 1800991.
[115] PRZYBYSZEWSKI B, ZIĘTKOWSKA K, GRZĘDA D, et al. Anti-Icing Transparent Coatings Modified with Bi- and Tri-Functional Octaspherosilicates for Photovoltaic Panels[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 703: 135402.
[116] HAO T T, ZHANG P X, CHI C, et al.Transparent Anti-Icing Moiré-Film Enhancing Photovoltaic Stability in Extreme Cold Climates[J]. Advanced Materials, 2025, 37(39): 2507034.
[117] SANSI SEUKEP A M, CUI Z X, PANDZOU D R, et al. Superhydrophobic Thermochromic Coating with Dual Photo-Electrothermal Modulation for All-Season Energy Efficiency Smart Window[J]. Advanced Functional Materials, 2026, 36(44): e75218.
[118] LI H, WU Y, TU H Y, et al.Dragonfly-Inspired Transparent Superhydrophobic Coatings with Low Haze and High Mechanical Robustness[J]. ACS Applied Materials & Interfaces, 2024, 16(50): 70138-70145.
[119] 卢林宇, 袁文鹏, 张越, 等. 超疏水涂层耐久性研究进展[J]. 复合材料学报, 2026, 43(2): 637-654.
LU L Y, YUAN W P, ZHANG Y, et al.Research Progress on Durability of Superhydrophobic Coatings[J]. Acta Materiae Compositae Sinica, 2026, 43(2): 637-654.
[120] ZHUO Y Z, HÅKONSEN V, LIU S Q, et al. Ultra-Robust Icephobic Coatings with High Toughness, Strong Substrate Adhesion and Self-Healing Capability[J]. Science China Materials, 2023, 66(5): 2071-2078.
[121] NIU H H, LUO S K, YAO X Y, et al.A Review of Transparent Superhydrophobic Materials and Their Research in the Field of Photovoltaic Dust Removal[J]. Materials Science in Semiconductor Processing, 2023, 166: 107741.
[122] FAN X Q, DING Y, LIU Y, et al.Plasmonic Ti3C2TxMXene Enables Highly Efficient Photothermal Conversion for Healable and Transparent Wearable Device[J]. ACS Nano, 2019, 13(7): 8124-8134.
[123] ZHOU Y S, PEI K, GUO Z G.Emerging Transparent Conductive Superhydrophobic Surfaces[J]. Advances in Colloid and Interface Science, 2025, 340: 103443.
[124] 孙浩淼, 矫维成, 金浩正, 等. 智能技术在防/除冰中的应用研究进展[J]. 复合材料学报, 2025, 42(1): 37-53.
SUN H M, JIAO W C, JIN H Z, et al.Research Progress on Application of Smart Technology in Anti-Icing and De-Icing[J]. Acta Materiae Compositae Sinica, 2025, 42(1): 37-53.
[125] HUAI J R, ZHANG J X, WANG P, et al.A Smart Slippery Surface with Reversible Dynamic Temperature Responsiveness for Long-Term Controllable Anti-Icing[J]. Advanced Materials Technologies, 2025, 10(8): 2401705.
[126] LIANG J, YANG Q, ZHANG C J, et al.Bioinspired, Anti-Fogging and De-Icing Transparent Surfaces with Flexible Property[J]. Applied Materials Today, 2024, 39: 102325.
[127] MITRIDIS E, LAMBLEY H, TRÖBER S, et al. Transparent Photothermal Metasurfaces Amplifying Superhydrophobicity by Absorbing Sunlight[J]. ACS Nano, 2020, 14(9): 11712-11721.
[128] LU Y N, LI J, SHI W T, et al.Laser-Induced Biomimetic Honeycomb Structures Synergizing with Nanocomposites to Build Durable Copper-Based Superhydrophobic Coatings[J]. Applied Surface Science, 2025, 706: 163592.

基金

国家自然科学基金青年项目(22402226); 天津市自然科学基金联合基金资助项目(24JCQNJC00050); 天津市教委科研计划项目(2023KJ229); 中国民用航空局安全能力建设基金(HA202512); 中国民航大学国家自然科学基金配套专项(3122025PT10)

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