多组元稀土硅酸盐环境障涂层材料研究进展

刘原; 邵建伟; 苏杭; 吴萌萌; 雷力明; 李树索; 宫声凯

doi:10.16490/j.cnki.issn.1001-3660.2026.16.013

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表面技术 ›› 2026, Vol. 55 ›› Issue (16) : 167-189. DOI: 10.16490/j.cnki.issn.1001-3660.2026.16.013

腐蚀与防护

多组元稀土硅酸盐环境障涂层材料研究进展

刘原¹, 邵建伟^1,2, 苏杭², 吴萌萌¹, 雷力明^1,*, 李树索², 宫声凯²

作者信息 +

Advances in Multi-component Rare-earth Silicate Environmental Barrier Coating Materials

LIU Yuan¹, SHAO Jianwei^1,2, SU Hang², WU Mengmeng¹, LEI Liming^1,*, LI Shusuo², GONG Shengkai²

Author information +

文章历史 +

摘要

面向SiC_f/SiC陶瓷基复合材料环境障涂层的高温服役需求,稀土硅酸盐正由单一组元向多组元协同设计发展。本文系统综述RE₂SiO₅和RE₂Si₂O₇的晶体结构、热物理性能及高温水氧/CMAS腐蚀行为,比较2类材料在热膨胀匹配、相稳定性和环境耐久性方面的差异。RE₂SiO₅环境稳定性较好,但热膨胀失配风险较高;RE₂Si₂O₇与基体热匹配性更优,但易受相变、Si挥发和晶界渗透影响。在此基础上,重点总结多组元稀土正硅酸盐和焦硅酸盐的成分-结构-性能关系。多稀土阳离子共占位可通过调控平均离子半径稳定X2或β相,并借助质量差异、晶格畸变及局部化学环境复杂化增强声子散射、降低热导率;同时,通过强化Si-O和RE-O键合、调节表面润湿与晶界结构、提高元素迁移阻力及改变保护性反应产物的形成与致密性,改善水氧和CMAS腐蚀抗力。最后,针对1 500 ℃以上相稳定性、长时耦合腐蚀评价和涂层可控制备等不足,提出多目标性能协同优化、结构-工艺一体化、低成本工程化及第一性原理与机器学习融合的发展方向。

Abstract

Rare-earth silicates have emerged as leading candidates for environmental barrier coatings (EBCs) on SiC_f/SiC ceramic matrix composites because of their low thermal conductivity, adjustable thermal expansion behavior, and comparatively high environmental stability. However, single-component RE₂SiO₅ and RE₂Si₂O₇ systems generally cannot simultaneously satisfy the coupled requirements of thermal-expansion compatibility, high-temperature phase stability, low heat transport, and resistance to water-vapor and calcium-magnesium-aluminosilicate (CMAS) attack. This review summarizes recent progress in multi-component rare-earth silicate EBC materials, with particular emphasis on the relationships among composition, crystal structure, thermophysical properties, and high-temperature corrosion behavior. The structural characteristics and thermal properties of RE₂SiO₅ and RE₂Si₂O₇ are firstly compared. RE₂SiO₅ generally exhibits relatively high chemical and environmental stability, but its thermal expansion coefficient is often higher than that of SiC_f/SiC substrates, increasing the risk of thermally induced interfacial stresses during cyclic exposure. By contrast, β-RE₂Si₂O₇, especially silicates containing small-radius rare-earth cations, provides better thermal-expansion compatibility with substrates, whereas phase transformation, Si-containing species volatilization, and grain-boundary penetration may compromise its long-term stability in aggressive environments.
The review then focuses on the multi-component design of rare-earth monosilicates and disilicates. Multi-cation occupation of the rare-earth sublattice expands the available compositional space and enables simultaneous regulation of phase constitution, lattice parameters, local bonding environments, and defect structures. Appropriate control of the average rare-earth ionic radius can promote the formation and retention of structurally favorable X2-type RE₂SiO₅ or β-RE₂Si₂O₇ phases. Differences in atomic mass and ionic size, together with lattice distortion and local chemical complexity, enhance phonon scattering and can substantially suppress thermal conductivity. The resulting thermophysical response is not governed solely by configurational entropy. Rather, the effects of specific elemental combinations, defect evolution, phonon anharmonicity, and high-temperature structural reconstruction must also be considered, particularly because some highly disordered systems may lose their low-thermal-conductivity advantage at elevated temperatures.
Recent studies on high-temperature water-vapor corrosion and CMAS attack are further reviewed. Multi-component design can modify Si-O and RE-O bonding, surface wettability, grain-boundary structure, and cation migration behavior, thereby affecting hydrolysis, volatile hydroxide formation, Si depletion, and the integrity of corrosion-product layers. In CMAS environments, the corrosion resistance of rare-earth silicates depends not only on whether interfacial reactions occur, but also on whether apatite- or garnet-type reaction products form continuous and dense barriers capable of suppressing further melt penetration and ionic diffusion. Multi-component chemistry may therefore improve environmental durability by slowing elemental transport, altering grain-boundary penetration pathways, and regulating the composition and compactness of protective reaction layers.
Finally, the remaining challenges for multi-component rare-earth silicate EBCs are discussed, including phase stability above 1 500 ℃, degradation under coupled thermal, water-vapor, and CMAS conditions, the lack of long-duration and coating- level validation, and the difficulty of reproducible large-scale processing. Future research should move from single-property optimization toward coordinated control of thermal matching, heat transport, phase stability, and corrosion resistance. Integrated composition-structure-process design, low-cost manufacturing, first-principles calculations, high-throughput screening, and machine-learning-assisted materials discovery are expected to accelerate the development of next-generation rare-earth silicate EBC systems for extreme aero-engine environments and support the reliable service of SiC_f/SiC hot-section components at increasingly higher operating temperatures.

导出引用

刘原, 邵建伟, 苏杭, 吴萌萌, 雷力明, 李树索, 宫声凯. 多组元稀土硅酸盐环境障涂层材料研究进展[J]. 表面技术. 2026, 55(16): 167-189

LIU Yuan, SHAO Jianwei, SU Hang, WU Mengmeng, LEI Liming, LI Shusuo, GONG Shengkai. Advances in Multi-component Rare-earth Silicate Environmental Barrier Coating Materials[J]. Surface Technology. 2026, 55(16): 167-189

中图分类号： TB32

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