耐腐蚀性高熵合金涂层研究进展及展望

王海涛; 杨攀; 赵凡; 曾毅; 邵枫; 向超; 赖建平; 余家欣

doi:10.16490/j.cnki.issn.1001-3660.2026.10.002

PDF(8903 KB)

表面技术 ›› 2026, Vol. 55 ›› Issue (10) : 12-34. DOI: 10.16490/j.cnki.issn.1001-3660.2026.10.002

腐蚀与防护

耐腐蚀性高熵合金涂层研究进展及展望

王海涛, 杨攀, 赵凡^*, 曾毅, 邵枫, 向超, 赖建平, 余家欣^*

作者信息 +

Research Progress and Prospects of Corrosion-resistant High-entropy Alloy Coatings

WANG Haitao, YANG Pan, ZHAO Fan^*, ZENG Yi, SHAO Feng, XIANG Chao, LAI Jianping, YU Jiaxin^*

Author information +

文章历史 +

摘要

海洋环境对海上基础设施和作业装备的腐蚀作用表现出显著的复杂性。海水盐分、微生物活动以及空蚀的共同作用,使得金属材料极易发生腐蚀失效,导致海洋装备服役周期缩短、运维成本增加。表面涂层技术因其高效性和成本效益,已成为海洋装备表面腐蚀防护的重要方法。其中,高熵合金涂层的简单固溶体结构,可以有效降低电偶腐蚀风险,并且在腐蚀介质作用下能够在表面形成致密钝化膜以延缓腐蚀过程,从而表现出优异的耐腐蚀性能。因此,高熵合金涂层在海洋设备领域的腐蚀防护中,展现出巨大的应用潜力。本文以从单一因素到多因素耦合效应的视角,系统概述了近年来耐腐蚀性高熵合金涂层在涂层分类、制备工艺与海洋环境腐蚀行为等方面的研究进展,包括：1）耐腐蚀性高熵合金涂层的分类及成分结构特点;2）耐腐蚀性高熵合金涂层的制备方法及性能特点;3）复杂海洋环境下耐腐蚀性高熵合金涂层的腐蚀行为和机理。总结指出耐腐蚀性高熵合金涂层在实际工程应用中面临涂层成分设计与制备工艺优化、服役性能优化等核心问题。针对海洋环境特性,明确提出通过多尺度仿真建模、工艺-结构优化和原位测试表征开发共同促进涂层防护的优化路径。最后对耐腐蚀性高熵合金涂层的发展前景进行了展望,旨在为下一代高性能耐腐蚀涂层的设计与工程化应用提供理论依据和技术指导。

Abstract

The safe and reliable operation of marine equipment holds significant importance for economic development, technological innovation, and national security. However, the unique corrosive conditions in the marine environment impose stringent requirements on the corrosion-resistant coatings used for marine equipment. Unlike corrosion protection in the atmosphere, corrosion protection in marine environments is affected by multiple mechanisms, including electrochemical corrosion dominated by Cl^-, microbiologically influenced corrosion in deep-sea environments, and cavitation erosion induced by hydrodynamic effects. Cl^- in seawater readily penetrates coating defects, leading to localized pitting corrosion, which reduces coating adhesion and ultimately causes delamination. Microbiologically influenced corrosion, facilitated by biofilms, continuously generates corrosive metabolites (e.g., H₂S) that accelerate coating degradation. Cavitation erosion arises from micro-jet impacts due to bubble collapse, resulting in mechanical fatigue and spalling of the coating. These corrosive conditions make metallic materials highly susceptible to corrosion-induced failure, thereby shortening the service life of marine equipment and increasing maintenance costs. Surface coating technology has emerged as a highly efficient and cost-effective approach for corrosion protection of marine equipment, enabling the isolation of corrosive media through the application of a protective layer, thereby extending the service life. Among various coating systems, high-entropy alloy (HEA) coatings are designed at varying atomic ratios of multiple main elements, which facilitates the formation of simple solid solution structures (e.g., BCC, FCC) or a uniform amorphous phase. These microstructures are dense in nature, effectively reducing the risk of galvanic corrosion. Moreover, under the influence of corrosive media, they can form a dense passive film on the surface, thereby retarding the corrosion process and demonstrating excellent corrosion resistance.
The corrosion resistance of the HEA coating is governed by the type and concentration of corrosion-resistant elements. In particular, elements such as Cr, Al, and Mo contribute to the formation of a solid solution structure and a dense passivation film, thereby effectively enhancing the coating's resistance to corrosive media. However, excessive addition of these elements can lead to elemental segregation, which induces micro-pitting corrosion and degrades the corrosion resistance of the coatings. Furthermore, the preparation methods and processing parameters of the HEA coating strongly influence its corrosion resistance. For instance, during laser deposition, the laser power and the traversing speed of the spray gun significantly influence the porosity of the coating and the precipitation of detrimental phases, thereby affecting its mechanical properties and corrosion resistance. In addition, marine equipment exhibits diverse corrosion behaviors and mechanisms in complex service environments, including electrochemical corrosion, microbial corrosion, and cavitation erosion. The primary objective of current research on corrosion-resistant HEA coatings is to optimize coating composition and process parameters to achieve superior corrosion resistance in complex service environments.
This work reviews recent progress in corrosion-resistant HEA coatings, including classification and compositional characteristics, preparation methods and performance features, and corrosion behaviors and mechanisms in complex marine environments. Key challenges in the practical engineering application of HEA coatings are identified, including coating composition design, process optimization, and in-service performance enhancement. Based on the characteristics of marine environments, a clear optimization pathway that integrates multi-scale simulation, process-structure optimization, and in situ testing and characterization is proposed to enhance coating protection. Finally, the future development prospects of corrosion-resistant HEA coatings are discussed to provide a theoretical foundation and technical guidance for designing and engineering next-generation high-performance corrosion-resistant coatings.

导出引用

王海涛, 杨攀, 赵凡, 曾毅, 邵枫, 向超, 赖建平, 余家欣. 耐腐蚀性高熵合金涂层研究进展及展望[J]. 表面技术. 2026, 55(10): 12-34

WANG Haitao, YANG Pan, ZHAO Fan, ZENG Yi, SHAO Feng, XIANG Chao, LAI Jianping, YU Jiaxin. Research Progress and Prospects of Corrosion-resistant High-entropy Alloy Coatings[J]. Surface Technology. 2026, 55(10): 12-34

中图分类号： TG174

参考文献

[1] TRAN T T T, KANNOORPATTI K, PADOVAN A, et al. A Study of Bacteria Adhesion and Microbial Corrosion on Different Stainless Steels in Environment Containing Desulfovibrio Vulgaris[J]. Royal Society Open Science, 2021, 8(1): 201577.
[2] 孟伟. 石油工业史上的911——墨西哥湾漏油事件[J]. 石油知识, 2020(3): 30-33.
MENG W.911 in the History of Petroleum Industry—Oil Spill in the Gulf of Mexico[J]. Petroleum Knowledge, 2020(3): 30-33.
[3] 国务院安委会关于山东省青岛市“11·22”中石化东黄输油管道泄漏爆炸特别重大事故的通报[J]. 国家安全生产监督管理总局国家煤矿安全监察局公告, 2014(2): 8-11.
The State Council Safety Committee's Report on the "11.22" Sinopec Donghuang Oil Pipeline Leakage and Explosion Accident in Qingdao, Shandong Province[J]. Gazette of the State Administration of Work Safety and the State Administration of Coal Mine Safety, 2014(2): 8-11.
[4] 孙磊, 郭雨嘉, 张盼盼, 等. 激光合金化改性8YSZ热障涂层的抗热腐蚀性能研究[J]. 中国激光, 2023, 50(4): 0402002.
SUN L, GUO Y J, ZHANG P P, et al.Hot Corrosion Resistance of 8YSZ Thermal Barrier Coating Modified by Laser Alloying[J]. Chinese Journal of Lasers, 2023, 50(4): 0402002.
[5] YEH J W, CHEN S K, LIN S J, et al.Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes[J]. Advanced Engineering Materials, 2004, 6(5): 299-303.
[6] TANG Z, HUANG L, HE W, et al.Alloying and Processing Effects on the Aqueous Corrosion Behavior of High-Entropy Alloys[J].entropy, 2014, 16: 895-911.
[7] LIU J, LIU H, CHEN P J, et al.Microstructural Characterization and Corrosion Behaviour of AlCoCrFeNiTix High-Entropy Alloy Coatings Fabricated by Laser Cladding[J]. Surface and Coatings Technology, 2019, 361: 63-74.
[8] ZHU J, CHENG X, ZHANG L M, et al.Microstructures, Wear Resistance and Corrosion Resistance of CoCrFeNi High Entropy Alloys Coating on AZ91 Mg Alloy Prepared by Cold Spray[J]. Journal of Alloys and Compounds, 2022, 925: 166698.
[9] LEE C C, TASI I H, CHEN S H.Impact of Phase Separation on Corrosion Resistance of AlCrFeNi Thermal Spraying HEA Coatings[J]. Materials Chemistry and Physics, 2025, 339: 130757.
[10] DONG M L, LIU P W, WANG C H, et al.Microstructure and Properties of FeCoNiCr and FeCoNiCrW High Entropy Alloy Coatings by Electro-Deposition[J]. Intermetallics, 2024, 175: 108492.
[11] XU J, PENG S, LI Z Y, et al.Remarkable Cavitation Erosion-Corrosion Resistance of CoCrFeNiTiMo High- Entropy Alloy Coatings[J]. Corrosion Science, 2021, 190: 109663.
[12] ZHAO T, ZHANG S, WANG Z Y, et al.Cavitation Erosion/Corrosion Synergy and Wear Behaviors of Nickel-Based Alloy Coatings on 304 Stainless Steel Prepared by Cold Metal Transfer[J]. Wear, 2022, 510: 204510.
[13] MIRACLE D B, SENKOV O N.A Critical Review of High Entropy Alloys and Related Concepts[J]. Acta Materialia, 2017, 122: 448-511.
[14] SALISHCHEV G A, TIKHONOVSKY M A, SHAYSULTANOV D G, et al.Effect of Mn and V on Structure and Mechanical Properties of High-Entropy Alloys Based on CoCrFeNi System[J]. Journal of Alloys and Compounds, 2014, 591: 11-21.
[15] LIU W H, HE J Y, HUANG H L, et al.Effects of Nb Additions on the Microstructure and Mechanical Property of CoCrFeNi High-Entropy Alloys[J]. Intermetallics, 2015, 60: 1-8.
[16] 段敬民, 董勇, 缪东美, 等. 热处理工艺对Al_0.5CoCrFeNi高熵合金在不同介质下腐蚀行为及力学性能的影响[J]. 中国腐蚀与防护学报, 2025, 45(4): 983-994.
DUAN J M, DONG Y, MIAO D M, et al.Corrosion Behavior in Different Media and Mechanical Properties of Al_0.5CoCrFeNi High-Entropy Alloy after Heat Treatment[J]. Journal of Chinese Society for Corrosion and Protection, 2025, 45(4): 983-994.
[17] Meghwal A, Anupam A, Luzin V, et al.Multiscale Mechanical Performance and Corrosion Behaviour of Plasma Sprayed AlCoCrFeNi High-entropy Alloy Coatings[J]. Journal of Alloys and Compounds, 2021, 854: 157140.
[18] LI Q H, YUE T M, GUO Z N, et al.Microstructure and Corrosion Properties of AlCoCrFeNi High Entropy Alloy Coatings Deposited on AISI 1045 Steel by the Electrospark Process[J]. Metallurgical and Materials Transactions A, 2013, 44(4): 1767-1778.
[19] XU Y K, LI Z Y, LIU J R, et al.Microstructure Evolution and Properties of Laser Cladding CoCrFeNiTiAlx High- Entropy Alloy Coatings[J]. Coatings, 2020, 10(4): 373.
[20] MEGHWAL A, ANUPAM A, LUZIN V, et al.Multiscale Mechanical Performance and Corrosion Behaviour of Plasma Sprayed AlCoCrFeNi High-Entropy Alloy Coatings[J]. Journal of Alloys and Compounds, 2021, 854: 157140.
[21] SILVELLO A, TORRES DIAZ E, RÚA RAMIREZ E, et al. Microstructural, Mechanical and Wear Properties of Atmospheric Plasma-Sprayed and High-Velocity Oxy- Fuel AlCoCrFeNi Equiatomic High-Entropy Alloys (HEAs) Coatings[J]. Journal of Thermal Spray Technology, 2023, 32(2): 425-442.
[22] LIAN G F, YANG J H, CHEN C R, et al.Influences of Ti and Mo Alloying on the Microstructure and Properties of Laser Cladding for CoCrFeNi High-Entropy Alloys[J]. Journal of Materials Research and Technology, 2023, 27: 5945-5964.
[23] 郭一帆, 郭学平, 卢冰文, 等. 激光熔覆FeCoCrNiAl_0.5Ti_0.5高熵合金涂层腐蚀摩擦复合行为[J]. 中国表面工程, 2025, 38(3): 185-198.
GUO Y F, GUO X P, LU B W, et al.Corrosion-Friction Behavior of Laser Cladding FeCoCrNiAl_0.5Ti_0.5 High Entropy Alloy Coating[J]. China Surface Engineering, 2025, 38(3): 185-198.
[24] YUE K, WANG L, XU Z, et al.Effect of Ti Addition on the Microstructure and Corrosion Behavior of Laser Cladding AlCoCrFeNi High-Entropy Alloy Coatings[J]. Vacuum, 2024, 230: 113633.
[25] XING B W, ZUO X J, LI Q N, et al.Influence of Microstructure Evolution on the Electrochemical Corrosion Behavior of (CoCrFeNi)₉₄Ti_1.5Al_4.5 High Entropy Alloy Coatings[J]. Journal of Thermal Spray Technology, 2022, 31(4): 1375-1385.
[26] ZHOU Y K, KANG J J, MA G Z, et al.Influence of Annealing Treatment on the Microstructure and Corrosion Resistance of AlxTiyCoCrFeNi High-Entropy Coatings[J]. Corrosion Science, 2025, 249: 112838.
[27] MA G L, ZHAO Y, CUI H Z, et al.Addition Al and/or Ti Induced Modifications of Microstructures, Mechanical Properties, and Corrosion Properties in CoCrFeNi High-Entropy Alloy Coatings[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(8): 1087-1102.
[28] QI W, WANG W R, YANG X, et al.Effects of Al and Ti Co-Doping on the Strength-Ductility- Corrosion Resistance of CoCrFeNi-AlTi High-Entropy Alloys[J]. Journal of Alloys and Compounds, 2022, 925: 166751.
[29] LIU J X, WEN Z Q, TANG D F, et al.Effects of Nb and Zr Alloying on the Microstructure, Mechanical Properties, and Corrosion Resistance of CoCrFeNi High-Entropy Alloys[J]. Journal of Materials Engineering and Performance, 2025, 34(7): 5674-5685.
[30] WANG W R, QI W, ZHANG X L, et al.Superior Corrosion Resistance-Dependent Laser Energy Density in (CoCrFeNi)₉₅Nb5 High Entropy Alloy Coating Fabricated by Laser Cladding[J]. International Journal of Minerals, Metallurgy and Materials, 2021, 28(5): 888-897.
[31] WU H, ZHANG S, WU C L, et al.Electrochemical Corrosion Behavior in Sulfuric Acid Solution and Dry Sliding Friction and Wear Properties of Laser-Cladded CoCrFeNiNb x High Entropy Alloy Coatings[J]. Surface and Coatings Technology, 2023, 460: 129425.
[32] WANG W R, QI W, XIE L, et al.Microstructure and Corrosion Behavior of (CoCrFeNi)₉₅Nb5 High-Entropy Alloy Coating Fabricated by Plasma Spraying[J]. Materials, 2019, 12(5): 694.
[33] GAO P H, FU R T, LIU J L, et al.Influence of Plasma Arc Current on the Friction and Wear Properties of CoCrFeNiMn High Entropy Alloy Coatings Prepared on CGI through Plasma Transfer Arc Cladding[J]. Coatings, 2022, 12(5): 633.
[34] MA M X, WANG Z X, ZHU C J, et al.Effect of Mn Doping on Microstructure and Corrosion Behavior of CoCuNiTi High-Entropy Alloy Coatings[J]. Crystals, 2025, 15(1): 29.
[35] WANG C M, YU Y, ZHANG H, et al.Microstructure and Corrosion Properties of Laser Remelted CrFeCoNi and CrMnFeCoNi High Entropy Alloys Coatings[J]. Journal of Materials Research and Technology, 2021, 15: 5187-5196.
[36] ZHANG D D, LI Q, SUN R Z, et al.Effect of Mn Addition on Microstructure and Corrosion Behavior of AlCoCrFeNi High-Entropy Alloy[J]. Intermetallics, 2024, 167: 108236.
[37] BOGDANOV R I, VORKEL V A, IGNATENKO V E, et al.Corrosion and Electrochemical Behavior of CoСrFeNiMo High-Entropy Alloy in Acidic Oxidizing and Neutral Chloride Solutions[J]. Materials Chemistry and Physics, 2023, 295: 127123.
[38] DAI J, FENG H, LI H B, et al.Insights into the Mechanism of Mo Protecting CoCrFeNi HEA from Pitting Corrosion—A Quantitative Modelling Study on Passivation and Repassivation Processes[J]. Journal of Materials Science & Technology, 2024, 182: 152-164.
[39] SHANG X L, WANG Z J, WU Q F, et al.Effect of Mo Addition on Corrosion Behavior of High-Entropy Alloys CoCrFeNiMox in Aqueous Environments[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(1): 41-51.
[40] FU Y, HUANG C, DU C W, et al.Evolution in Microstructure, Wear, Corrosion, and Tribocorrosion Behavior of Mo-Containing High-Entropy Alloy Coatings Fabricated by Laser Cladding[J]. Corrosion Science, 2021, 191: 109727.
[41] CUI C, WU M P, HE R, et al.Microstructure, Wear and Corrosion Behavior of High-Entropy Alloy Coatings: The Concentration of Mo Element and the Dual Effect of Σ-CrMo Phase[J]. Surface and Coatings Technology, 2023, 467: 129726.
[42] DUAN J M, JIANG Z N, HUANG F, et al.Mechanistic Exploration of the Exceptional Corrosion Resistance of the Newly Designed FeCoCrNiMo x Nb x High-Entropy Alloys[J]. Journal of Materials Science & Technology, 2025, 221: 204-219.
[43] DIKICI B, LINDNER T, ŞAKAR E, et al.Enhancing Corrosion Resistance and Radiation Shielding of AISI 304 SS with Nb and Mo-Added Al_0.3CrFeCoNi-Based High-Entropy Alloy Coatings in 3.5wt% NaCl: The Effect of Environmental Temperature[J]. Journal of Alloys and Compounds, 2025, 1020: 179432.
[44] ZHANG R Z, REECE M J.Review of High Entropy Ceramics: Design, Synthesis, Structure and Properties[J]. Journal of Materials Chemistry A, 2019, 7(39): 22148-22162.
[45] CHEN T K, WONG M S, SHUN T T, et al.Nanostructured Nitride Films of Multi-Element High-Entropy Alloys by Reactive DC Sputtering[J]. Surface and Coatings Technology, 2005, 200(5/6): 1361-1365.
[46] BRAIC M, BRAIC V, BALACEANU M, et al.Characteristics of (TiAlCrNbY)C Films Deposited by Reactive Magnetron Sputtering[J]. Surface and Coatings Technology, 2010, 204(12/13): 2010-2014.
[47] GILD J, ZHANG Y Y, HARRINGTON T, et al.High- Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics[J]. Scientific Reports, 2016, 6: 37946.
[48] FENG X G, ZHANG K F, ZHENG Y G, et al.Chemical State, Structure and Mechanical Properties of Multi- Element (CrTaNbMoV)Nx Films by Reactive Magnetron Sputtering[J]. Materials Chemistry and Physics, 2020, 239: 121991.
[49] OU T Y, CHANG L C, ANNALAKSHMI M, et al.Effects of Nitrogen Flow Ratio on the Mechanical and Anticorrosive Properties of Cosputtered (TiZrHfTa)Nx Films[J]. Surface and Coatings Technology, 2024, 477: 130410.
[50] HSUEH H T, SHEN W J, TSAI M H, et al.Effect of Nitrogen Content and Substrate Bias on Mechanical and Corrosion Properties of High-Entropy Films (AlCrSiTiZr)₁₀₀-_xNx[J]. Surface and Coatings Technology, 2012, 206(19/20): 4106-4112.
[51] SUN S, WANG H, HUANG L, et al.Microstructure Evolution and Mechanical Properties of Refractory High-Entropy Alloy Nitride Film[J]. Surface and Coatings Technology, 2024, 483: 130775.
[52] YAN W Q, ZHAO Y M, ZHANG Y F, et al.Corrosion- Resistant and Interfacial Conductive AlTiVCrMo High- Entropy Alloy and (AlTiVCrMo)Nx High-Entropy Ceramics Coatings for Surface Modification of Bipolar Plates in Proton Exchange Membrane Fuel Cells[J]. Journal of Power Sources, 2022, 527: 231217.
[53] DONG Y F, ZHAO Y M, LI J C, et al.Super-Hard and Well-Tough (TiZrVCrCoNi)Nx High Entropy Nitride Coatings with Biphasic Nanocomposite Structure[J]. Vacuum, 2024, 224: 113110.
[54] LI J C, CHEN Y J, ZHAO Y M, et al.Super-Hard (MoSiTiVZr)Nx High-Entropy Nitride Coatings[J]. Journal of Alloys and Compounds, 2022, 926: 166807.
[55] LIN S Y, CHANG S Y, HUANG Y C, et al.Mechanical Performance and Nanoindenting Deformation of (AlCrTaTiZr)NCy Multi-Component Coatings Co-Sputtered with Bias[J]. Surface and Coatings Technology, 2012, 206(24): 5096-5102.
[56] LI Y T, CHEN X M, ZENG X K, et al.Hard yet Tough and Self-Lubricating (CuNiTiNbCr)C x High-Entropy Nanocomposite Films: Effects of Carbon Content on Structure and Properties[J]. Journal of Materials Science & Technology, 2024, 173: 20-30.
[57] LU X L, YANG L Q, LU Y, et al.Nanostructure, Mechanical Properties and Tribological Behavior of High-Entropy Carbonitrides Coatings[J]. Ceramics International, 2025, 51(10): 13420-13429.
[58] WANG G Y, XU J, CHEN Y H, et al.Assessment of the Tribocorrosion Performance of a (TiZrNbTaMo)C Refractory High Entropy Alloy Carbide Coating in a Marine Environment[J]. Journal of Alloys and Compounds, 2023, 965: 171342.
[59] WANG J J, ZHANG H L, YU X, et al.Insight into the Structure and Tribological and Corrosion Performance of High Entropy (CrNbSiTiZr)C Films: First-Principles and Experimental Study[J]. Surface and Coatings Technology, 2021, 421: 127468.
[60] KAO W H, SU Y L, HORNG J H, et al.Effects of Carbon Doping on Mechanical, Tribological, Structural, Anti- Corrosion and Anti-Glass-Sticking Properties of CrNbSiTaZr High Entropy Alloy Coatings[J]. Thin Solid Films, 2021, 717: 138448.
[61] ZHANG H, LI W, XU H, et al.Microstructure and Corrosion Behavior of Laser Cladding FeCoNiCrBSi Based High-entropy Alloy Coatings[J]. Coatings, 2022, 12(5): 628.
[62] SHU F Y, ZHANG X B, WANG H P, et al.Research on Mechanical Properties and Corrosion Behavior of (Co₃₄Fe₈Cr₂₉Ni₈Si₇)₁₀₀-_xBx High Entropy Alloy Coating[J]. Journal of Thermal Spray Technology, 2024, 33(5): 1630-1642.
[63] CUI C Y, LIU X F, FENG L, et al.Effects of B Content on the Microstructure and Corrosion Resistance of Laser Cladding CoCrNiNb_0.6Bx High-Entropy Alloy Coatings[J]. Journal of Alloys and Compounds, 2025, 1032: 181085.
[64] WU Z, TAHERI M, SHIRVANI K, et al.Development of NiCrFeCoBX Eutectic High Entropy Alloy Coating by Laser Cladding: Investigation of Microstructural, Solidification, Corrosion, and Wear Properties[J]. Materials Chemistry and Physics, 2024, 320: 129428.
[65] JIANG D, CUI H Z, CHEN H, et al.Wear and Corrosion Properties of B₄C-Added CoCrNiMo High-Entropy Alloy Coatings with In-Situ Coherent Ceramic[J]. Materials & Design, 2021, 210: 110068.
[66] WU H, WANG L, ZHANG S, et al.Tribological Properties and Sulfuric Acid Corrosion Resistance of Laser Clad CoCrFeNi High Entropy Alloy Coatings with Different Types of TiC Reinforcement[J]. Tribology International, 2023, 188: 108870.
[67] HE R, WU M P, CUI C, et al.Laser Cladding Manufacturing of TiC + TiBx Reinforced FeNiCrTi_0.3Al_0.3 High Entropy Alloy Composite Coating: Effects on Corrosion and Tribology[J]. Journal of Alloys and Compounds, 2024, 970: 172631.
[68] LIU Z C, KONG D J.Microstructure, Corrosive-Wear and Electrochemical Properties of Laser Cladded CoCrFeNiMo-B₄C Coatings in 3.5%NaCl Solution[J]. Optics & Laser Technology, 2023, 159: 108999.
[69] ZOU Y M, QIU Z G, HUANG C J, et al.Microstructure and Tribological Properties of Al₂O₃ Reinforced FeCoNiCrMn High Entropy Alloy Composite Coatings by Cold Spray[J]. Surface and Coatings Technology, 2022, 434: 128205.
[70] GUO Y X, SHANG X J, LIU Q B.Microstructure and Properties of In-Situ TiN Reinforced Laser Cladding CoCr₂FeNiTi x High-Entropy Alloy Composite Coatings[J]. Surface and Coatings Technology, 2018, 344: 353-358.
[71] ALIYU A, REKHA M Y, SRIVASTAVA C.Microstructure-Electrochemical Property Correlation in Electrodeposited CuFeNiCoCr High-Entropy Alloy-Graphene Oxide Composite Coatings[J]. Philosophical Magazine, 2019, 99(6): 718-735.
[72] MOHAN M, SINGH S, PANDEL U, et al.Optimization of Surface Oxide Chemistry for Enhanced Corrosion Resistance of AlMnFeCoNi - Carbon Nanotube Composite Coatings[J]. Journal of Alloys and Compounds, 2024, 1003: 175766.
[73] HUANG L, PAN Y F, ZHANG J X, et al.Densification, Microstructure and Mechanical Performance of TiC/Fe Composites by Spark Plasma Sintering[J]. Journal of Materials Research and Technology, 2020, 9(3): 6116-6124.
[74] WU H, WANG L, ZHANG S, et al.Corrosion and Cavitation Erosion Behaviors of Laser Clad FeNiCoCr High-Entropy Alloy Coatings with Different Types of TiC Reinforcement[J]. Surface and Coatings Technology, 2023, 471: 129910.
[75] LIU Z C, KONG D J.Effects of TiC Mass Fraction on Microstructure, Corrosive-Wear and Electrochemical Properties of Laser Cladded CoCrFeNiMo High-Entropy Alloy Coatings[J]. Tribology International, 2023, 186: 108640.
[76] YIM D, SATHIYAMOORTHI P, HONG S J, et al.Fabrication and Mechanical Properties of TiC Reinforced CoCrFeMnNi High-Entropy Alloy Composite by Water Atomization and Spark Plasma Sintering[J]. Journal of Alloys and Compounds, 2019, 781: 389-396.
[77] GAO Z T, WANG R Q, KE L C, et al.Morphology Distribution and Corrosion Resistance of In-Situ TiC/CoCrFeNi High-Entropy Alloy Coating[J]. Materials Characterization, 2025, 224: 115078.
[78] ZHANG X R, CUI X F, QI M, et al.Corrosion and Passivation Behavior of In-Situ TiC Reinforced Al_0.1CrNbSi_0.1TaTiV Refractory High Entropy Alloy Coatings via Doping C[J]. Corrosion Science, 2024, 227: 111736.
[79] LI S, LI H Q, ZHAI Z H, et al.Corrosion Resistance and Tribological Behavior of FeCoCrNi@GO/Ni High Entropy Alloy-Based Composite Coatings Prepared by Electrodeposition[J]. Surface and Coatings Technology, 2024, 477: 130379.
[80] ZHANG D, YU H, XUE S, et al.Effect of Graphene Oxide on CoCrFeNi High-Entropy Alloy Coatings Prepared by the Electrodeposition Method[J]. Surface and Coatings Technology, 2024, 485: 130919.
[81] ALIYU A, SRIVASTAVA C. Phase Constitution, Surface Chemistry and Corrosion Behavior of Electrodeposited MnFeCoNiCu High Entropy Alloy-Graphene Oxide Composite Coatings[J]. Surface and Coatings Technology, 2022, 429: 127943.
[82] ALIYU A, SRIVASTAVA C.Microstructure and Corrosion Properties of MnCrFeCoNi High Entropy Alloy-Graphene Oxide Composite Coatings[J]. Materialia, 2019, 5: 100249.
[83] ALIYU A, SRIVASTAVA C.Microstructure and Corrosion Performance of AlFeCoNiCu High Entropy Alloy Coatings by Addition of Graphene Oxide[J]. Materialia, 2019, 8: 100459.
[84] MOHAN M, SINGH S, PANDEL U, et al.Evolution of Surface Oxide Chemistry and Its Effect on the Electrochemical Degradation Behaviour of AlCoFeCuNi High Entropy Alloy Coating Incorporated with Multiwalled Carbon Nanotubes[J]. Electrochimica Acta, 2024, 485: 144095.
[85] RAO P, SINGH S, KUMAR K, et al.Understanding the Evolution of Microstructure, Phase Homogeneity, Electrochemical Characteristics and Surface Chemistry of Electrodeposited MnCrCoFeNiCu High Entropy Alloy Coating with Reinforcement of Carbon Nanotubes[J]. Surface and Coatings Technology, 2023, 471: 129912.
[86] MOHAN M, PANDEL U, KUMAR K. Phase Composition, Surface Chemistry and Electrochemical Studies of Electrodeposited AlMnFeCuNi High Entropy Alloy Composite Coatings Incorporated with Carbon Nanotubes[J]. Materials Research Express, 2024, 11(4): 046403.
[87] SINGH S, SRIVASTAVA C.Effect of Carbon Nanotube Incorporation on the Evolution of Morphology, Phase and Compositional Homogeneity, Surface Oxide Chemistry and Corrosion Behaviour of Electrodeposited FeCuMnNiCo- Carbon Nanotube Composite Coatings[J]. Electrochimica Acta, 2023, 439: 141639.
[88] MA Q, ZHAO W, SHI C W, et al.Effect of Synergistic Variation in Ti and Zr Elements on the Microstructure and Properties of Laser Cladding AlCoCrFeNi High-Entropy Alloy Coatings[J]. Materials Characterization, 2023, 205: 113300.
[89] DADA M, POPOOLA P, MATHE N, et al.Effect of Laser Parameters on the Properties of High Entropy Alloys: A Preliminary Study[J]. Materials Today: Proceedings, 2021, 38: 756-761.
[90] LIU Y S, XIANG D D, WANG K M, et al.Corrosion of Laser Cladding High-Entropy Alloy Coatings: A Review[J]. Coatings, 2022, 12(11): 1669.
[91] LI S, DING J Y, LIU Z Y, et al.Evolution of Microstructure and Properties of AlCoCrFeNi High- Entropy Alloy Coatings Fabricated at Different Laser Power Levels[J]. Materials Today Communications, 2025, 46: 112644.
[92] SHU F Y, ZHANG B L, LIU T, et al.Effects of Laser Power on Microstructure and Properties of Laser Cladded CoCrBFeNiSi High-Entropy Alloy Amorphous Coatings[J]. Surface and Coatings Technology, 2019, 358: 667-675.
[93] CHONG Z Z, SUN Y N, CHENG W J, et al.Enhanced Wear and Corrosion Resistances of AlCoCrFeNi High- Entropy Alloy Coatings via High-Speed Laser Cladding[J]. Materials Today Communications, 2022, 33: 104417.
[94] HE R, WU M P, CUI C, et al.Effects of Laser Energy Density on Microstructure and Corrosion Resistance of FeCrNiMnAl High Entropy Alloy Coating[J]. Optics & Laser Technology, 2022, 152: 108188.
[95] GAO Q, LIU H, CHEN P J, et al.Multi-Objective Optimization for Laser Cladding Refractory MoNbTiZr High-Entropy Alloy Coating on Ti₆Al₄V[J]. Optics & Laser Technology, 2023, 161: 109220.
[96] HUANG Y B, HU Y L, ZHANG M J, et al.Multi- Objective Optimization of Process Parameters in Laser Cladding CoCrCuFeNi High-Entropy Alloy Coating[J]. Journal of Thermal Spray Technology, 2022, 31(6): 1985-2000.
[97] MARTIN P M.Handbook of Deposition Technologies for Films and Coatings: Science, Applications and Technology[M]. Boston: Elsevier, 2009.
[98] KUCZYK M, KRÜLLE T, ZAWISCHA M, et al. Microstructure and Mechanical Properties of High Entropy Alloy Nitride Coatings Deposited via Direct Current Cathodic Vacuum Arc Deposition[J]. Surface and Coatings Technology, 2022, 448: 128916.
[99] BAPTISTA A, SILVA F J G, PORTEIRO J, et al. On the Physical Vapour Deposition (PVD): Evolution of Magnetron Sputtering Processes for Industrial Applications[J]. Procedia Manufacturing, 2018, 17: 746-757.
[100] ZENG X K, LI Y T, ZHANG X D, et al.Effect of Bias Voltage on the Structure and Properties of CuNiTiNbCr Dual-Phase High Entropy Alloy Films[J]. Journal of Alloys and Compounds, 2023, 931: 167371.
[101] DAI C D, FU Y, GUO J X, et al.Effects of Substrate Temperature and Deposition Time on the Morphology and Corrosion Resistance of FeCoCrNiMo_0.3 High-Entropy Alloy Coating Fabricated by Magnetron Sputtering[J]. International Journal of Minerals, Metallurgy and Materials, 2020, 27(10): 1388-1397.
[102] OBEYDAVI A, SHAFYEI A, LEE J W.Effect of Sputtering Power and Substrate Bias on Microstructure, Mechanical Properties and Corrosion Behavior of CoCrFeMnNi High Entropy Alloy Thin Films Deposited by Magnetron Sputtering Method[J]. Intermetallics, 2024, 172: 108369.
[103] CHEN R, CAI Z B, PU J B, et al.Effects of Nitriding on the Microstructure and Properties of VAlTiCrMo High-Entropy Alloy Coatings by Sputtering Technique[J]. Journal of Alloys and Compounds, 2020, 827: 153836.
[104] MESYATS G A.Ecton Mechanism of the Cathode Spot Phenomena in a Vacuum Arc[J]. IEEE Transactions on Plasma Science, 2013, 41(4): 676-694.
[105] CHEN S N, ZHANG Y F, ZHAO Y M, et al.Preparation and Regulation of AlCrNiTiSi High Entropy Alloy Coating by a Multi-Arc Magnetic Filter Cathode Vacuum Arc System[J]. Surfaces and Interfaces, 2021, 26: 101400.
[106] YAN D Y, XU W J, LI J F, et al.Effect of Nitrogen/Argon Ratios on Structures and Properties of High-Entropy (ZrTiNbV)N Nitride Films by Multi-Arc Ion Plating[J]. Vacuum, 2024, 225: 113173.
[107] ZHAO Y M, YAN W Q, CHEN Y J, et al.Influence of N Concentration on Structure and Properties of (AlCrMoTiV)Nx Films by Co-Filter Cathodic Vacuum Arc Deposition[J]. Surface and Coatings Technology, 2023, 459: 129366.
[108] TAGHAVI POURIAN AZAR G, ER D L, ÜRGEN M. The Role of Superimposing Pulse Bias Voltage on DC Bias on the Macroparticle Attachment and Structure of TiAlN Coatings Produced with CA-PVD[J]. Surface and Coatings Technology, 2018, 350: 1050-1057.
[109] LEE P E, TU Y K, TSAI M H, et al.Macroparticle Reduction and Its Transport Mechanism through a Magnetic Filter during Cathodic Vacuum Arc Deposition with an HEA Target[J]. Coatings, 2022, 12(10): 1437.
[110] AMIN S, PANCHAL H.A review on Thermal Spray Coating Processes[J]. Transfer, 2016, 2(4): 556-563.
[111] 曹甫洋, 王浩权, 季谦, 等. 大气等离子喷涂FeCoCrNiMn高熵合金涂层的耐海水腐蚀与磨损性能[J]. 中国腐蚀与防护学报, 2024, 44(6): 1529-1537.
CAO F Y, WANG H Q, JI Q, et al.Tribo-Corrosion Performance of Atmospheric Plasma Sprayed FeCoCrNiMn High Entropy Alloy Coatings[J]. Journal of Chinese Society for Corrosion and Protection, 2024, 44(6): 1529-1537.
[112] LI L, YANG N P, LIU Y Q, et al.Study on Mechanical Properties and Electrochemical Corrosion Resistance of Arc Sprayed FeAlMoNbCrC and FeAlMoNiCrC Coatings[J]. Journal of Thermal Spray Technology, 2025, 34(5): 1763-1781.
[113] WANG J W, DIAO W, CHENG B, et al.Excellent Tribocorrosion Resistance in Artificial Seawater of High Entropy Alloy FeCrNiCoAl Coating Prepared by HVOF[J]. Journal of Alloys and Compounds, 2024, 1009: 176931.
[114] OPPONG BOAKYE G, STRAUME E O, GUNNARSSON B G, et al.Corrosion Behaviour of HVOF Developed Mo-Based High Entropy Alloy Coating and Selected Hard Coatings for High Temperature Geothermal Applications[J]. Materials & Design, 2023, 235: 112431.
[115] LIU Z, YAN D R, DONG Y C, et al.The Effect of Modified Epoxy Sealing on the Electrochemical Corrosion Behaviour of Reactive Plasma-Sprayed TiN Coatings[J]. Corrosion Science, 2013, 75: 220-227.
[116] MA T D, WANG D B, TONG W P, et al.Significantly Enhanced Corrosion Resistance for Fe-Based Amorphous Coatings via Sealing Treatment: Based on Hybridisation and Superhydrophobicity Strategy[J]. Applied Surface Science, 2025, 680: 161435.
[117] MEHMOOD K, UMER M A, MUNAWAR A U, et al.Microstructure and Corrosion Behavior of Atmospheric Plasma Sprayed NiCoCrAlFe High Entropy Alloy Coating[J]. Materials, 2022, 15(4): 1486.
[118] MU Y K, ZHANG L B, XU L, et al.Frictional Wear and Corrosion Behavior of AlCoCrFeNi High-Entropy Alloy Coatings Synthesized by Atmospheric Plasma Spraying[J]. Entropy, 2020, 22(7): 740.
[119] SONG P S, CHENG J B, WANG X Y, et al.Corrosion and Corrosion-Wear Behavior of the (FeCoCrNi)₇₅B15Si10 High-Entropy Amorphous Alloy Coatings Prepared by Plasma Spraying[J]. Corrosion Science, 2025, 253: 113013.
[120] ZHANG M, ZHANG Y, DAI P Y, et al.Study on the Process Parameters and Corrosion Resistance of FeCoNiCrAl High Entropy Alloy Coating Prepared by Atmospheric Plasma Spraying[J]. Materials, 2025, 18(7): 1396.
[121] NEWBERY A P, GRANT P S.Large Arc Voltage Fluctuations and Droplet Formation in Electric Arc Wire Spraying[J]. Powder Metallurgy, 2003, 46(3): 229-235.
[122] GEDZEVICIUS I, VALIULIS A V.Analysis of Wire Arc Spraying Process Variables on Coatings Properties[J]. Journal of Materials Processing Technology, 2006, 175(1/2/3): 206-211.
[123] BAHRAMI E, KHODAEI M.Optimization of Cored Wire Arc Spraying of Amorphous FeCrNiSiWNbB Coating; Hot-Corrosion and High-Temperature Erosion Evaluations[J]. Journal of Thermal Spray Technology, 2025, 34(4): 1368-1383.
[124] ZHOU Y K, KANG J J, JIN G, et al.Effect of Vacuum Heat Treatment on Microstructure and Corrosion Behavior of HVOF Sprayed AlCoCrFeNiCu High Entropy Alloy Coatings[J]. Journal of Iron and Steel Research International, 2023, 30(8): 1550-1561.
[125] ZHANG D D, LI Q, CHANG C T, et al.Effects of Mn Addition on Wear and Corrosion Resistances of AlCoCrFeNi High-Entropy Alloy Coating Sprayed by HVOF[J]. Journal of Materials Research and Technology, 2025, 34: 627-638.
[126] CHENG J, WU Y P, HONG S, et al.Spray Parameters Optimization, Microstructure and Corrosion Behavior of High-Velocity Oxygen-Fuel Sprayed Non-Equiatomic CuAlNiTiSi Medium-Entropy Alloy Coatings[J]. Intermetallics, 2022, 142: 107442.
[127] LÖBEL M, LINDNER T, MEHNER T, et al. Microstructure and Corrosion Properties of AlCrFeCoNi High- Entropy Alloy Coatings Prepared by HVAF and HVOF[J]. Journal of Thermal Spray Technology, 2022, 31(1): 247-255.
[128] DEHESTANI M, SHARAFI S, KHAYATI G R.The Effect of Pulse Current Density on the Microstructure, Magnetic, Mechanical, and Corrosion Properties of High-Entropy Alloy Coating Fe-Co-Ni-Mo-W, Achieved through Electro Co-Deposition[J]. Intermetallics, 2022, 147: 107610.
[129] POPESCU A J, BRANZOI F, CONSTANTIN I, et al.Electrodeposition, Characterization, and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy Thin Films[J]. Coatings, 2021, 11(11): 1367.
[130] YOOSEFAN F, ASHRAFI A, MONIR VAGHEFI S M. Microstructure and Corrosion Properties of Electrodeposited CoCrFeMnNi High Entropy Alloy Coatings[J]. Frontiers in Materials, 2022, 9: 891011.
[131] AKBARPOUR M R, GHARIBI ASL F.Fabrication of High-Performance Graphene/Nickel-Cobalt Composite Coatings Using Ultrasonic-Assisted Pulse Electrodeposition[J]. Ceramics International, 2023, 49(9): 13829-13835.
[132] LI D W, SHI H Y, LIANG D Y, et al.Microstructural Evolution and Mechanical Properties of CrCoFeMnNi High-Entropy Alloys under Femtosecond Laser Ablation: A Molecular Dynamics Approach[J]. Journal of Materials Research and Technology, 2025, 35: 6333-6340.
[133] ISLAM M R, ISLAM J, HASAN R, et al.Effect of Alloying Element Content, Temperature, and Strain Rate on the Mechanical Behavior of NbTiZrMoV High Entropy Alloy: A Molecular Dynamics Study[J]. Materials Today Communications, 2024, 40: 110071.
[134] LIU Y H, XIE J W, TANG L.Design and Evaluation Method of Erosion-Resistant and Wear-Resistant CoCrFeMnNi High-Entropy Alloy Coating Based on Molecular Dynamics Simulation and Machine Learning[J]. Corrosion Science, 2025, 254: 113048.
[135] ZHANG M D, XU H Q, LI G.By Machine Learning Tailor Al/Mo Ratio to Adjust FCC+L12+BCC Structured CoFeMnNi-Based High-Entropy Alloys for Improved Corrosion Resistance[J]. Journal of Alloys and Compounds, 2025, 1041: 183825.
[136] SONG H Q, FENG C S, GUAN Z, et al.Effect of Al/Cr Ratio on Structure, Magnetism, and Corrosion Resistance of FeCoNiCr₁-_xAlx High Entropy Alloys[J]. Journal of Alloys and Compounds, 2025, 1010: 177415.
[137] FU Y, DAI C D, LUO H, et al.The Corrosion Behavior and Film Properties of Al-Containing High-Entropy Alloys in Acidic Solutions[J]. Applied Surface Science, 2021, 560: 149854.
[138] CUI Y W, CHEN L Y, WANG L Q, et al.Response of the Metastable Pitting Corrosion of Laser Powder Bed Fusion Produced Ti-6Al-4V to H+ Concentration Changes[J]. Metals, 2023, 13(3): 514.
[139] QIU X W, WU M J, LIU C G, et al.Corrosion Performance of Al₂CrFeCo_xCuNiTi High-Entropy Alloy Coatings in Acid Liquids[J]. Journal of Alloys and Compounds, 2017, 708: 353-357.
[140] XING B W, DING Q, JIN B Q, et al.Corrosion Resistance and Passivation Behavior of CoCrFeNi-TiAl High-Entropy Alloy Coatings in Acidic Solutions[J]. Journal of Thermal Spray Technology, 2022, 31(5): 1673-1682.
[141] BI D, CHANG Y, LUO H, et al.Corrosion Behavior and Passive Film Characteristics of AlNbTiZrSix High- Entropy Alloys in Simulated Seawater Environment[J]. Corrosion Science, 2023, 224: 111530.
[142] RAMEL F, BRASSEUR G, PIEULLE L, et al.Growth of the Obligate Anaerobe Desulfovibrio Vulgaris Hildenborough under Continuous Low Oxygen Concentration Sparging: Impact of the Membrane-Bound Oxygen Reductases[J]. PLoS One, 2015, 10(4): e0123455.
[143] CHENG J, WU Y P, DUAN J Z, et al.The Influence of SRB on Corrosion Behavior of Cu-Based Medium- Entropy Alloy Coating Sprayed by HVOF[J]. Bioelectrochemistry, 2024, 156: 108633.
[144] ZHOU E Z, QIAO D X, YANG Y, et al. A Novel Cu- Bearing High-Entropy Alloy with Significant Antibacterial Behavior Against Corrosive Marine Biofilms[J]. Journal of Materials Science & Technology, 2020, 46: 201-210.
[145] YANG C T, FENG H, CHEN X B, et al. Enhanced Pitting Corrosion Resistance of CoCrFeMnNi High Entropy Alloy in the Presence of Desulfovibrio VulgarisviaNitrogen Doping[J]. Journal of Materials Science & Technology, 2023, 139: 92-102.
[146] BAIG U, DASTAGEER M A, GONDAL M A, et al. Photocatalytic Deactivation of Sulphate Reducing Bacteria Using Visible Light Active CuO/TiO₂ Nanocomposite Photocatalysts Synthesized by Ultrasonic Processing[J]. Journal of Photochemistry and Photobiology B: Biology, 2023, 242: 112698.
[147] YEH Y, WU P, LI J F, et al. Tetrapodal ZnO Nanomaterial Synthesis for Antibacterial Fluoroethylene Vinyl Ether Polymer Coating[J]. Materials Letters, 2023, 344: 134435.
[148] AMANN T, WAIDELE M, KAILER A. Analysis of Mechanical and Chemical Mechanisms on Cavitation Erosion-Corrosion of Steels in Salt Water Using Electrochemical Methods[J]. Tribology International, 2018, 124: 238-246.
[149] LI L, NIE S J, LI C T, et al. Study on Cavitation Erosion-Corrosion Behavior of CoCrFeNiMoCu_0.1 High Entropy Alloy in 3.5 Wt% NaCl Solution[J]. Ultrasonics Sonochemistry, 2024, 110: 107021.
[150] ZHAO T, WANG L, ZHANG S, et al. Effect of Synergistic Cavitation Erosion-Corrosion on Cavitation Damage of CoCrFeNiMn High Entropy Alloy Layer by Laser Cladding[J]. Surface and Coatings Technology, 2023, 472: 129940.
[151] HOI K C, LEI W H, LIU Y N, et al. Cavitation Erosion of the CoCrFeNi High Entropy Alloy Having Elemental Segregation[J]. Wear, 2023, 530: 204990.
[152] CAO H B, HOU G L, XU T C, et al. Effect of Seawater Temperature on the Corrosion and Cavitation Erosion-Corrosion Resistance of Al₁₀Cr₂₈Co₂₈Ni34 High-Entropy Alloy Coating[J]. Corrosion Science, 2024, 228: 111822.
[153] YU D T, WU C L, CUI X X, et al. Study on Microstructure, Mechanical Properties, Wear and Cavitation Erosion Resistance of Fecrniti_0.3Al_0.3 High Entropy Alloy Coatings by Laser Cladding[J]. Materials Today Communications, 2025, 49: 113840.
[154] CHANG W W, WU Z Y, GAO J G, et al. Improving Corrosion and Microbial Corrosion Resistance of CoCrFeNi High Entropy Alloy in Marine Environment by Trace Amount of Ce Addition[J]. Materials & Design, 2025, 254: 114081.
[155] CHEN H, HAN S X, ZHANG H W, et al. Corrosion Resistance and Antibacterial Performances of a Novel Ag-Bearing FeCrNiAl_0.6Ti_0.6Ag_xHigh Entropy Alloy Coatings[J]. Corrosion Science, 2025, 256: 113224.
[156] WEI Z, WU Y P, HONG S, et al. Ultrasonic Cavitation Erosion Behaviors of High-Velocity Oxygen-Fuel (HVOF) Sprayed AlCoCrFeNi High-Entropy Alloy Coating in Different Solutions[J]. Surface and Coatings Technology, 2021, 409: 126899.
[157] WU C L, ZHANG S, ZHANG C H, et al. Phase Evolution and Cavitation Erosion-Corrosion Behavior of FeCoCrAlNiTi x High Entropy Alloy Coatings on 304 Stainless Steel by Laser Surface Alloying[J]. Journal of Alloys and Compounds, 2017, 698: 761-770.