目的 揭示深冷处理后磨削加工对变质层特性、服役性能的影响规律。方法 以GCr15轴承钢为研究对象,分别进行淬火+回火(QT)、淬火+回火+深冷(QTC)、淬火+深冷+回火(QCT)等3种处理,采用不同磨削深度和工件进给速度对3种试样进行磨削加工,并对磨削加工表面进行表征和服役性能测试。结果 在较低磨削深度下,深冷处理试样的表面粗糙度显著低于QT处理试样,3种不同处理试样的白层厚度均随着磨削深度的增加而递增,其中QCT处理试样的白层厚度最大。QTC和QCT处理试样在磨削加工过程中发生残余奥氏体向马氏体的相变,变质层内碳元素呈局部富集。深冷处理试样的黏着磨损程度显著降低,QTC、QCT处理试样的磨损率相较于QT处理试样降低了30%~50%。经深冷处理的磨削加工试样的自腐蚀电流密度显著降低,其耐腐蚀性能显著提高。结论 深冷处理通过调控磨削过程中的热-力耦合效应,降低了表面粗糙度。在深冷处理后进行磨削加工,变质层白层组织通过抑制磨粒嵌入和裂纹扩展,可显著提高试样的表面硬度,有效提升了磨削加工表面的耐磨损和耐腐蚀性能。
Abstract
The work aims to reveal the influence law of grinding processing after cryogenic treatment on the characteristics and service performance of the metamorphic layer. Taking GCr15 bearing steel as the research object, three different process treatments were carried out respectively, namely quenching + tempering (QT), quenching + tempering + cryogenic (QTC), and quenching + cryogenic + tempering (QCT). Different grinding depths and workpiece feed rates were adopted to grind the three specimens. The surface roughness and hardness of the grinding process were measured, and the surface cracks and burn defects were observed. The thickness of the white layer of the grinding metamorphic layer were measured to detect the phase transformation from residual austenite to martensite, and observe the distribution of carbon elements within the metamorphic layer. The wear resistance and corrosion resistance of the grinding surface were evaluated through friction and wear tests and electrochemical corrosion tests. The surface roughness of the cryogenic treated specimens was significantly lower than that of the QT treated specimens at a lower grinding depth. A larger grinding depth was prone to cause surface cracks and burn defects. The thickness of the white layer of the three different treated specimens all increased with the increase of grinding depth, among which the thickness of the white layer of the QCT treated specimens was the largest. During the grinding process of the QTC and QCT treated specimens, a phase transformation from residual austenite to martensite occurred, and the carbon element in the deteriorated layer was locally enriched. Grinding parameters (grinding depth, feed rate) affected the microhardness distribution of the subsurface layer through the thermomechanical coupling effect. The hardness gradient change of the cryogenic treated specimens was more uniform than that of the QT treated specimens, and the surface hardness of the QTC and QCT treated specimens was significantly higher than that of the QT treated specimens. The results of the friction and wear test show that the average friction coefficient of the cryogenic treated specimens is lower than that of the QT treated specimens, the degree of adhesive wear is significantly reduced, and the wear volume and wear depth of the QTC and QCT treated specimens are 30% to 50% lower than those of the QT treated specimens. Electrochemical tests show that the self-corrosion current density of the grinding processing specimens treated by deep cryogenic therapy is significantly reduced, and the corrosion resistance is significantly improved. Deep cryogenic treatment reduces surface roughness and inhibits crack and burn defects by regulating the thermo-force coupling effect during the grinding process. The QCT treated specimens have the maximum thickness of the white layer due to the microstructure adjustment after tempering after deep cryogenic treatment. The residual austenite transformation and carbon element enrichment in the QTC and QCT treated specimens can significantly improve the microhardness of the processed surface. After deep cryogenic treatment and grinding processing, the white layer structure within the deteriorated layer effectively enhances the wear resistance and corrosion resistance of the ground surface by inhibiting the embedding of abrasive grains and crack propagation.
关键词
深冷处理 /
磨削加工 /
变质层 /
服役性能 /
白层
Key words
cryogenic treatment /
grinding processing /
metamorphic layer /
service performance /
white layer
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] 王鹏. GCr15轴承钢高周疲劳损伤机制与疲劳性能优化研究[D]. 合肥: 中国科学技术大学, 2023: 1-27.
WANG P.Study on High Cycle Fatigue Damage Mechanism and Fatigue Performance Optimization of GCr15 Bearing Steel[D]. Hefei: University of Science and Technology of China, 2023: 1-27.
[2] CHENG Y J, WANG Y S, LIN J H, et al.Research Status of the Influence of Machining Processes and Surface Modification Technology on the Surface Integrity of Bearing Steel Materials[J]. The International Journal of Advanced Manufacturing Technology, 2023, 125(7): 2897-2923.
[3] 迟玉伦, 俞鑫, 刘斌, 等. 基于轴承毛坯表面分析的磨削材料去除率模型与应用实验[J]. 表面技术, 2023, 52(4): 338-353.
CHI Y L, YU X, LIU B, et al.Grinding Material Removal Rate Model and Application Experiment Based on Bearing Blank Surface Analysis[J]. Surface Technology, 2023, 52(4): 338-353.
[4] 卢守相, 郭塞, 张建秋, 等. 高性能难加工材料可磨削性研究进展[J]. 表面技术, 2022, 51(3): 12-42.
LU S X, GUO S, ZHANG J Q, et al.Grindability of High Performance Difficult-to-Machine Materials[J]. Surface Technology, 2022, 51(3): 12-42.
[5] MADOPOTHULA U, LAKSHMANAN V, NIMMAGADDA R B.Time Dependent Behavior of Alumina Grains Manufactured by Two Different Routes while Grinding of AISI 52100 Steels[J]. Archives of Civil and Mechanical Engineering, 2017, 17(2): 400-409.
[6] 洪远. 磨削强化变质层微观复合组织转变与宏观性能表征研究[D]. 沈阳: 东北大学, 2021: 69-80.
HONG Y.Study on Microstructure Transformation and Macroscopic Properties Characterization of Grinding-Strengthened Metamorphic Layer[D]. Shenyang: Northeastern University, 2021: 69-80.
[7] 张方圆. 硬切削GCr15轴承钢表面变质层微观组织及抗磨损性能研究[D]. 大连: 大连理工大学, 2019: 93-113.
ZHANG F Y.Study on Microstructure and Wear Resistance of the Metamorphic Layer of GCr15 Bearing Steel in Hard Cutting[D]. Dalian: Dalian University of Technology, 2019: 93-113.
[8] 郭吉恩. 平面磨削淬硬GCr15轴承钢变质层形成规律实验研究[J]. 制造技术与机床, 2023(11): 137-140.
GUO J E.Research on the Formation Rule of Surface Grinding Affected Layer of Hardened GCr15 Steel[J]. Manufacturing Technology & Machine Tool, 2023(11): 137-140.
[9] 陈涛, 刘献礼, 李素燕, 等. 高速硬切削加工表面白层形成机理研究[J]. 机械工程学报, 2015, 51(23): 182-188.
CHEN T, LIU X L, LI S Y, et al.Mechanism of White Layer Formation on Machined Surface of High-Speed Hard Machining[J]. Journal of Mechanical Engineering, 2015, 51(23): 182-188.
[10] ZHANG F Y, DUAN C Z, SUN W, et al.Influence of White Layer and Residual Stress Induced by Hard Cutting on Wear Resistance during Sliding Friction[J]. Journal of Materials Engineering and Performance, 2019, 28(12): 7649-7662.
[11] 邹翩, 于爱兵, 吴其亮, 等. 硬切削白层对GCr15轴承钢表面摩擦磨损性能的影响[J]. 材料保护, 2022, 55(7): 91-95.
ZOU P, YU A B, WU Q L, et al.Effect of White Layer Obtained by Hard Cutting on the Friction and Wear Performances of GCr15 Bearing Steel Surface[J]. Materials Protection, 2022, 55(7): 91-95.
[12] 陈叶青, 吴益文, 秦子威, 等. 深冷处理对GCr15轴承钢组织及力学性能的影响[J]. 机械工程材料, 2018, 42(5): 55-58.
CHEN Y Q, WU Y W, QIN Z W, et al.Effect of Deep Cryogenic Treatment on Microstructure and Mechanical Properties of GCr15 Bearing Steel[J]. Materials for Mechanical Engineering, 2018, 42(5): 55-58.
[13] 李东辉, 李志敏, 肖茂果, 等. 深冷处理对低碳高合金马氏体轴承钢力学性能及组织的影响[J]. 材料研究学报, 2019, 33(8): 561-571.
LI D H, LI Z M, XIAO M G, et al.Effect of Deep Cryogenic Treatment on Mechanical Property and Microstructure of a Low Carbon High Alloy Martensitic Bearing Steel during Tempering[J]. Chinese Journal of Materials Research, 2019, 33(8): 561-571.
[14] 李辉, 尹甜甜, 刘勇. 深冷处理对GCr15轴承钢性能的影响[J]. 轴承, 2015(8): 41-44.
LI H, YIN T T, LIU Y.Effect of Deep Cryogenic Treatment on Performances of Bearing Steel GCr15[J]. Bearing, 2015(8): 41-44.
[15] 宫志鹏, 贺甜甜, 李林芳, 等. 残留奥氏体含量对GCr15轴承钢摩擦磨损性能的影响[J]. 材料热处理学报, 2023, 44(5): 123-134.
GONG Z P, HE T T, LI L F, et al.Effect of Retained Austenite Content on Friction and Wear Properties of GCr15 Bearing Steel[J]. Transactions of Materials and Heat Treatment, 2023, 44(5): 123-134.
[16] WEI X H, ZHANG X, HE W C, et al.Influence of Deep Cryogenic Treatment on Microstructural Evolution and Transformation Kinetics Simulation by Finite Element Method of Low-Carbon High-Alloy Martensitic-Bearing Steel[J]. Steel Research International, 2022, 93(9): 2100785.
[17] LI D H, HE W C, ZHANG X, et al.Effects of Traditional Heat Treatment and a Novel Deep Cryogenic Treatment on Microstructure and Mechanical Properties of Low-Carbon High-Alloy Martensitic Bearing Steel[J]. Journal of Iron and Steel Research International, 2021, 28(3): 370-382.
[18] WU H Y, HAN D X, DU Y, et al.Effect of Initial Spheroidizing Microstructure after Quenching and Tempering on Wear and Contact Fatigue Properties of GCr15 Bearing Steel[J]. Materials Today Communications, 2022, 30: 103152.
[19] 李勇翰. 高碳铬轴承钢特征显微组织调控与性能评价研究[D]. 合肥: 中国科学技术大学, 2024: 85-110.
LI Y H.Study on Characteristic Microstructure Regulation and Performance Evaluation of High Carbon Chromium Bearing Steel[D]. Hefei: University of Science and Technology of China, 2024: 85-110.
[20] 韩斌, 于宗洋, 李涛. GCr15轴承钢大圆材的球化退火工艺[J]. 金属热处理, 2015, 40(1): 90-93.
HAN B, YU Z Y, LI T.Spheroidizing Annealing Process of Big Size Bar of Bearing Steel GCr15[J]. Heat Treatment of Metals, 2015, 40(1): 90-93.
[21] 冯硕, 丁腾威, 李娜, 等. 深冷处理对轴承钢及其磨削加工表面质量的影响[J]. 表面技术, 2025, 54(9): 248-259.
FENG S, DING T W, LI N, et al.Effect of Cryogenic Treatment on Bearing Steel and Grinding Surface Quality[J]. Surface Technology, 2025, 54(9): 248-259.
[22] RASMUSSEN C J, FÆSTER S, DHAR S, et al. Surface Crack Formation on Rails at Grinding Induced Martensite White Etching Layers[J]. Wear, 2017, 384: 8-14.
[23] CHENG D M, JIN G D, GAO Y F, et al.Study on Grinding-Affected Layer of Outer-Ring Inner Raceway of Tapered Roller Bearing[J]. Materials, 2023, 16(22): 7219.
[24] FENG A X, XU G X, CHEN C L, et al.Surface Characteristics and Wear Resistance of GCr15 Bearing Steel by Cryogenic Treatment-Laser Peening[J]. Applied Physics A, 2022, 128(10): 921.
[25] 刘震寰, 李勇翰, 刘洋, 等. GCr15轴承钢时效过程碳化物的演化行为[J]. 材料研究学报, 2024, 38(2): 130-140.
LIU Z H, LI Y H, LIU Y, et al.Carbide Evolution Behavior of GCr15 Bearing Steel during Aging Process[J]. Chinese Journal of Materials Research, 2024, 38(2): 130-140.
[26] 黄伟锋. 强化研磨加工GCr15轴承钢耐腐蚀行为研究[D]. 广州: 广州大学, 2021: 45-75.
HUANG W F.Study on Corrosion Resistance Behavior of GCr15 Bearing Steel Processed by Strengthened Grinding[D]. Guangzhou: Guangzhou University, 2021: 45-75.
[27] SUN C, HONG Y, XIU S C, et al.Grain Refinement Mechanism of Metamorphic Layers by Abrasive Grinding Hardening[J]. Journal of Manufacturing Processes, 2021, 69: 125-141.
[28] 张德嘉. 淬硬GCr15轴承钢平面磨削表面变质层形成机理及特性研究[D]. 长沙: 长沙理工大学, 2022: 22-58.
ZHANG D J.Study on Formation Mechanism and Characteristics of Surface Metamorphic Layer in Plane Grinding of Hardened GCr15 Bearing Steel[D]. Changsha: Changsha University of Science & Technology, 2022: 22-58.
[29] 闫续范. H13钢加工白层组织及其电化学特性[D]. 济南: 山东大学, 2015: 41-50.
YAN X F.Microstructure and Electrochemical Characteristics of White Layer in H13 Steel Processing[D]. Jinan: Shandong University, 2015: 41-50.
基金
国家自然科学基金(52375446); 山东省重点研发计划(2024JMRH0307); 山东省高等学校“青创团队计划”(2023KJ110)