激光熔覆工艺对CoCrMo钴基合金涂层组织与性能的影响

赵永胜, 葛超, 吴影, 陈春伦, 刘艳, 陈辉

表面技术 ›› 2024, Vol. 53 ›› Issue (23) : 216-227.

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PDF(15880 KB)
表面技术 ›› 2024, Vol. 53 ›› Issue (23) : 216-227. DOI: 10.16490/j.cnki.issn.1001-3660.2024.23.019
激光表面改性技术

激光熔覆工艺对CoCrMo钴基合金涂层组织与性能的影响

  • 赵永胜, 葛超, 吴影, 陈春伦, 刘艳, 陈辉
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Effect of Laser Cladding Process on Microstructure and Mechanical Properties of CoCrMo Cobalt-based Alloy Coating

  • ZHAO Yongsheng, GE Chao, WU Ying, CHEN Chunlun, LIU Yan, CHEN Hui
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摘要

目的 以激光熔覆技术在制动盘表面制备CoCrMo钴基涂层,提高其摩擦面的力学性能。方法 以24CrNiMo钢为基体,CoCrMo合金粉末为涂层材料,研究了工艺参数对熔宽、熔高、熔深和稀释率的影响规律。通过组织和性能测试,分析不同工艺参数下涂层的组织、拉伸性能和耐磨损性能等。结果 稀释率随着激光功率和扫描速度的增加而增大,但随送粉速度的增加而减小。熔宽和熔高分别随激光功率和送粉速度的增加而增大,但随扫描速度的增加而减小。涂层物相主要由γ-Co、Ni-Cr-Co-Mo和少量的ε-Co相组成。显微硬度随着激光功率和送粉率的增加而增大,但随着扫描速度增加而减小,最大值约为304HV0.2。抗拉强度和伸长率随着激光功率的增加而增大,但随送粉速率的增加而减小,而随扫描速度的增加先增大而减小。抗拉强度和伸长率最大值分别达到了(1 202±60) MPa和(17.4±1.3)%。激光功率和送粉率较高或扫描速度较低时,具有良好的耐磨性,但耐磨性提高不显著,磨损机理为磨粒磨损和黏着磨损。结论 激光熔覆工艺对熔宽、熔高和稀释率影响显著,但对涂层微观组织影响不明显。优化激光熔覆工艺参数可以有效提高熔覆层的硬度和拉伸性能,但对耐磨性的影响较小。

Abstract

As the speed of high-speed trains continues to increase significantly, the 24CrNiMo cast steel material used in brake discs is increasingly found inadequate in meeting the rigorous braking performance requirements necessary for these advanced high-speed trains. This inadequacy necessitates the exploration of alternative materials that can withstand the higher stress and thermal demands placed on brake systems. Cobalt-based alloys, recognized for their exceptional mechanical properties, including superior strength, excellent wear resistance, and high-temperature stability, are now being widely utilized in demanding applications such as rail transportation, aerospace, and other high-performance fields. The work aims to investigate the impact of laser cladding technology on the microstructure and mechanical properties of CoCrMo cobalt-based alloy cladding coatings. The primary goal is to enhance the strength, wear resistance, and overall durability of the brake disc friction surface to meet the elevated performance demands of modern high-speed train brake systems. In the experimental setup, 24CrNiMo steel brake discs serve as the substrate material, and CoCrMo cobalt-based alloy powder is used for cladding. The study meticulously examines how variations in single-factor laser cladding process parameters, such as laser power, scanning speed, and powder feeding rate, affect critical aspects including melt width, melt height, melt depth, and dilution rate. Comprehensive evaluations are conducted by various techniques, including optical microscopy (OM), scanning electron microscopy (SEM), microhardness testing, friction and wear testing, and tensile testing, to assess the microstructure and mechanical properties of the cladding coatings under different conditions. The experimental results indicate that both melt width and dilution rate increase as the laser power increases, while melt height and melt depth remain relatively stable across different power settings. The dilution rate also increases with increasing scanning speed, but melt height and melt width decrease with increasing scanning speed. Moreover, the melt height increases as the powder feeding rate rises, whereas the dilution rate decreases as the feeding rate increases. Despite variations in process parameters, the microstructure of the cladding coating exhibits minimal changes, predominantly consisting of γ-Co, Ni-Cr-Co-Mo solid solution, and a small amount of ε-Co phase. The microstructure is characterized mainly by columnar and cellular crystals. The microhardness of the cladding coating increases with increasing laser power and powder feeding rates, but decreases with the increasing scanning speed, reaching a peak value of approximately 304HV0.2. The tensile strength and yield strength demonstrate an increasing trend with the increasing laser power but decrease with the increasing scanning speed. After fracture, the elongation increases with laser power, initially rises and then decreases with the increasing scanning speed, and decreases with the increasing powder feeding rates. Under varying process parameters, the maximum tensile strength achieved is (1 202±60) MPa, with a maximum elongation of (17.4±1.3)%. Although laser power does not significantly affect wear resistance, higher laser power and powder feeding rates or lower scanning speed, result in improved wear resistance, with abrasive wear and adhesive wear identified as the primary wear mechanisms. Overall, the laser cladding process has a significant impact on the melt width, melt height, and dilution rate, though its effect on the microstructure of the cladding coating is relatively minor. By optimizing the laser cladding process parameters, it is possible to substantially enhance the hardness and tensile properties of the cladding coating, although the impact on wear resistance remains somewhat limited.

关键词

CoCrMo钴基合金;24CrNiMo钢;制动盘;微观组织;拉伸性能;耐磨性

Key words

CoCrMo cobalt-based alloy; 24CrNiMo steel; brake disc; microstructure; tensile properties; wear resistance

引用本文

导出引用
赵永胜, 葛超, 吴影, 陈春伦, 刘艳, 陈辉. 激光熔覆工艺对CoCrMo钴基合金涂层组织与性能的影响[J]. 表面技术. 2024, 53(23): 216-227
ZHAO Yongsheng, GE Chao, WU Ying, CHEN Chunlun, LIU Yan, CHEN Hui. Effect of Laser Cladding Process on Microstructure and Mechanical Properties of CoCrMo Cobalt-based Alloy Coating[J]. Surface Technology. 2024, 53(23): 216-227

基金

国家自然科学基金(52105372,52375387)

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