CaCO3对复合粉粒和实心焊丝明弧堆焊高铬合金组织及耐磨性的影响

龚建勋, 刘超, 黄洪江, 艾孝文, 刘书同

表面技术 ›› 2023, Vol. 52 ›› Issue (2) : 215-224.

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表面技术 ›› 2023, Vol. 52 ›› Issue (2) : 215-224. DOI: 10.16490/j.cnki.issn.1001-3660.2023.02.019
摩擦磨损与润滑

CaCO3对复合粉粒和实心焊丝明弧堆焊高铬合金组织及耐磨性的影响

  • 龚建勋, 刘超, 黄洪江, 艾孝文, 刘书同
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Effects of CaCO3 on the Microstructure and Abrasion Resistance of High Chromium Alloys Deposited by Open Arc Welding with Composite Powder Particles and Solid Wire

  • GONG Jian-xun, LIU Chao, HUANG Hong-jiang, AI Xiao-wen, LIU Shu-tong
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摘要

目的 将活性剂引入复合粉粒,旨在改变电弧对其的作用属性,以提高堆焊金属的合金化元素量,从而改善其耐磨性。方法 以复合粉粒和实心焊丝作为填充材料,采用自保护明弧焊法制备系列高铬合金。借助X射线衍射仪、扫描电镜及附属电子能谱仪等手段,研究复合粉粒添加CaCO3含量对其堆焊高铬合金的组织及耐磨性的影响。结果 随着CaCO3添加量增大,焊缝的碗形熔深随之消除,堆焊合金的粉粒填充量由43.7%提高到47.5%,熔合比由0.281降低至0.140。这使堆焊合金组织由亚共晶变为过共晶结构,初生M7C3相的体积分数随之明显增加,堆焊合金硬度从55.4HRC提高至62.3HRC,磨损质量损失从54.9 mg降低至16.7 mg,耐磨性净增加2.3倍,合金磨损方式包括微观切削和显微剥落。高速摄影仪所拍电弧影像和电流电压数据显示,复合粉粒添加CaCO3粉,使其堆焊电弧形态从圆锥形转变变为扁平钟罩形,电弧覆盖面积扩展约2倍。结论 复合粉粒引入CaCO3粉,促使电弧扩展,这不仅提高了复合粉粒的熔化量,而且显著降低了母材的稀释作用,以微小成本而显著改善了合金组织及耐磨性。

Abstract

The work aims to introduce activating flux into the composite powder particles (CPPs) to change the arc behavior on CPPs and increase the content of alloying elements in hardfacing metals, so as to improve their abrasion resistance. Five groups of high chromium alloys were deposited by self-shielded open arc welding with filler materials such as CPPs and H08A solid wire. Then, the effects of different CaCO3 contents on the arc shape, arc stability, microstructure, and abrasion resistance of high-chromium hardfacing alloys were investigated in detail.

关键词

复合粉粒;明弧;堆焊;高铬合金;活性剂;碳酸钙;耐磨性

Key words

composite powder particles; open arc; hardfacing; high chromium alloy; activating flux; CaCO3; abrasion resistance

引用本文

导出引用
龚建勋, 刘超, 黄洪江, 艾孝文, 刘书同. CaCO3对复合粉粒和实心焊丝明弧堆焊高铬合金组织及耐磨性的影响[J]. 表面技术. 2023, 52(2): 215-224
GONG Jian-xun, LIU Chao, HUANG Hong-jiang, AI Xiao-wen, LIU Shu-tong. Effects of CaCO3 on the Microstructure and Abrasion Resistance of High Chromium Alloys Deposited by Open Arc Welding with Composite Powder Particles and Solid Wire[J]. Surface Technology. 2023, 52(2): 215-224

基金

湖南省自然科学基金(2021JJ30669)

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