AlCrBN/AlCrSiN纳米晶多层复合涂层的制备及其性能

张磊, 刘琰, 曾晓梅, 瓦西里.佩列诺维奇, 陈燕鸣, 李正刚, 张俊, 杨兵

表面技术 ›› 2022, Vol. 51 ›› Issue (2) : 48-56, 107.

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表面技术 ›› 2022, Vol. 51 ›› Issue (2) : 48-56, 107. DOI: 10.16490/j.cnki.issn.1001-3660.2022.02.005
专题——高速加工刀具涂层技术

AlCrBN/AlCrSiN纳米晶多层复合涂层的制备及其性能

  • 张磊1, 刘琰1, 曾晓梅1, 陈燕鸣1, 李正刚1, 张俊1, 杨兵1, 瓦西里.佩列诺维奇2
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Preparation and Performance of AlCrBN/AlCrSiN Nanocrystalline Multilayer Composite Coatings

  • ZHANG Lei1, LIU Yan1, ZENG Xiao-mei1, CHEN Yan-ming1, LI Zheng-gang1, ZHANG Jun1, YANG Bing1, Vasiliy,Pelenovich2
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摘要

目的 制备高硬度、高耐磨性、自润滑及高热稳定性的AlCrBN/AlCrSiN纳米晶多层复合涂层,探索涂层的微观结构、力学性能、耐磨性能及高温热稳定性能。方法 采用多弧离子镀技术在WC-Co硬质合金以及不锈钢基底上,制备AlCrBN/AlCrSiN多层纳米晶复合涂层。采用扫描电子显微镜、X射线衍射、透射电子显微镜、纳米压痕仪等设备,对涂层在不同温度(600~1000 ℃)下退火前后的表面形貌、微观结构、力学性能、耐磨性能进行系统研究。结果 AlCrSiN/AlCrBN涂层为典型的纳米晶复合多层结构,涂层主要由fcc-AlCrN纳米晶镶嵌在非晶的SiNx和BNx中并形成多层结构。涂层具有优异的热稳定性能,其结构能够保持到800 ℃不发生变化,当温度增加到900 ℃时,涂层发生调幅分解,形成c-AlN、hcp-AlN和Cr2N等复合结构,在1000 ℃退火后,涂层结构基本稳定,仍能检测到CrN相。涂层纳米硬度及平均摩擦因数分别为29.15 GPa和0.67。结论 AlCrSiN/AlCrBN涂层具有优异的力学性能、耐磨性能及高温热稳定性能,在800 ℃以下保持稳定,在1000 ℃退火后仍能保持较高的硬度及良好的耐磨性能,在高速切削刀具中具有良好的应用前景。

Abstract

To extend the service life of cutting tool, AlCrBN/AlCrSiN nanocrystalline multilayer composite coating with high hardness, high wear resistance, self-lubrication and high thermal stability was prepared on the cemented WC-Co carbide and stainless steel substrate by multi-arc ion plating technology. The morphology, structure, mechanical properties and wear resistance of the coating before and after annealing in the range of 600~1000 ℃ were systematically studied by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, nano-indentation and friction and wear tester. The AlCrSiN/AlCrBN coating exhibits a typical nanocrystalline composite multilayer structure with fcc-AlCrN nanocrystals embedded in the amorphous SiNx and BNx. The coating has excellent thermal stability performance, and its structure can be maintained to 800 ℃ without change. When the temperature increases to 900 ℃, the coating undergoes amplitude modulation decomposition, forming structures such as c-AlN, hcp-AlN and Cr2N. The structure of coating is stable after annealing at 1000 ℃, since CrN phase also can be detected in the coating. The coating nanohardness and average friction coefficient are 29.15 GPa and 0.67, respectively. AlCrSiN/AlCrBN coating has excellent mechanical properties, wear resistance and high temperature thermal stability, remains stable below 800 ℃, and can still maintain high hardness and good wear resistance after annealing at 1000 ℃, and has good application prospects in the field of high-speed cutting tool coating.

关键词

多弧离子镀;切削刀具涂层;纳米复合结构;力学性能;耐磨性能;热稳定性

Key words

arc ion plating; cutting tool coatings; nanocomposite structure; mechanical properties; wear resistance; thermal stability

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张磊, 刘琰, 曾晓梅, 瓦西里.佩列诺维奇, 陈燕鸣, 李正刚, 张俊, 杨兵. AlCrBN/AlCrSiN纳米晶多层复合涂层的制备及其性能[J]. 表面技术. 2022, 51(2): 48-56, 107
ZHANG Lei, LIU Yan, ZENG Xiao-mei, Vasiliy,Pelenovich, CHEN Yan-ming, LI Zheng-gang, ZHANG Jun, YANG Bing. Preparation and Performance of AlCrBN/AlCrSiN Nanocrystalline Multilayer Composite Coatings[J]. Surface Technology. 2022, 51(2): 48-56, 107

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国家自然科学基金(U1832127)

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