聚环氧琥珀酸衍生物及复合配方在天然海水中阻垢缓蚀性能的研究

贾静娴, 柳鑫华, 王丽红, 付占达, 魏金芳, 王鹏飞, 王磊, 赵腾达

表面技术 ›› 2021, Vol. 50 ›› Issue (12) : 390-399.

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表面技术 ›› 2021, Vol. 50 ›› Issue (12) : 390-399. DOI: 10.16490/j.cnki.issn.1001-3660.2021.12.039
腐蚀与防护

聚环氧琥珀酸衍生物及复合配方在天然海水中阻垢缓蚀性能的研究

  • 贾静娴1, 王丽红1, 付占达1, 魏金芳1, 王鹏飞1, 王磊1, 赵腾达1, 柳鑫华2
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Study on Scale and Corrosion Inhibition Properties of Polyepoxy-succinic Acid Derivatives and Composite Formulas in Natural Seawater

  • JIA Jing-xian1, WANG Li-hong1, FU Zhan-da1, WEI Jin-fang1, WANG Peng-fei1, WANG Lei1, ZHAO Teng-da1, LIU Xin-hua2
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摘要

目的 为提高聚环氧琥珀酸(PESA)的阻垢缓蚀综合性能,拓展其应用范围,将2-氨基乙磺酸(SEA)引入PESA分子中,合成聚环氧琥珀酸衍生物(SEA-PESA)并应用于海水环境。方法 将PESA和SEA缩合制备了SEA-PESA,用傅里叶红外光谱和核磁氢谱表征其结构。研究了 SEA-PESA及其四元复合配方在天然海水中的缓蚀和阻垢等综合性能。结果 在海水环境中,SEA-PESA质量浓度为160 mg/L,对Q235钢片的缓蚀率为61.82%,而PESA仅为52.17%。PESA和SEA-PESA的四元复合配方的缓蚀率分别高达88.87%、96.99 %,腐蚀速率分别为0.065 52、0.017 72 mm/a,SEA-PESA四元复合配方缓蚀效果明显优于PESA,更好地契合了国标的要求。SEA-PESA四元复合配方以抑制阳极为主,是一种阳极型缓蚀剂;在海水中也表现出良好的阻垢性能,在10 mg/L用量下阻垢率达100%。结论 本研究证实了SEA-PESA用于冷却系统和热脱盐工艺过程中,特别是海水环境中抑制腐蚀和结垢方面的潜能,应用前景广阔。

Abstract

In order to improve the comprehensive scale and corrosion inhibition performance of polyepoxysuccinic acid (PESA) and expand its application range, 2-aminoethylsulfonic acid (SEA) was introduced into PESA molecule to synthesize a polyepoxysuccinic acid derivative (SEA-PESA) and applied in seawater environment. SEA-PESA was synthesized by condensation of PESA and SEA, and the structure of SEA-PESA was characterized by Fourier-infrared spectroscopy and 1HNMR. Comprehensive property of scale and corrosion inhibition were studied on SEA-PESA and its quaternary formulation in natural seawater. In seawater environment, when SEA-PESA concentration is 160 mg/L, and the corrosion inhibition efficiencies of Q235 carbon steel is 61.82%, while that of PESA is only 52.17%. The corrosion inhibition rates of the quaternary formulations of PESA and SEA-PESA were 88.87% and 96.99%, respectively, and the corrosion rates were 0.06 552 mm/a and 0.017 72 mm/a. The corrosion inhibition effect of the quaternary formulations of SEA-PESA was better than PESA’s, which better met the requirements of national standards. SEA-PESA quaternary formulation is an anodic corrosion inhibitor, which mainly inhibits the anode. It also showed good scale inhibition performance in seawater, and the scale inhibition rate reached 100% at the dosage of 10 mg/L. This study confirmed the potential of SEA-PESA for corrosion inhibition and scaling inhibition in cooling systems and thermal desalination processes, especially in seawater environment, and has a broad application prospect.

关键词

海水;2-氨基乙磺酸;聚环氧琥珀酸衍生物;缓蚀剂;阻垢缓蚀机理

Key words

seawater; 2-taurine; polyepoxysuccinic acid derivative; scale and corrosion inhibition mechanism

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贾静娴, 柳鑫华, 王丽红, 付占达, 魏金芳, 王鹏飞, 王磊, 赵腾达. 聚环氧琥珀酸衍生物及复合配方在天然海水中阻垢缓蚀性能的研究[J]. 表面技术. 2021, 50(12): 390-399
JIA Jing-xian, LIU Xin-hua, WANG Li-hong, FU Zhan-da, WEI Jin-fang, WANG Peng-fei, WANG Lei, ZHAO Teng-da. Study on Scale and Corrosion Inhibition Properties of Polyepoxy-succinic Acid Derivatives and Composite Formulas in Natural Seawater[J]. Surface Technology. 2021, 50(12): 390-399

基金

河北省钢铁联合自然基金(B2017209228);唐山师范学院博士基金(2018A04)

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