C/SiC复合材料与抗氧化陶瓷涂层的优化匹配

杨彦龙, 张凯峰, 曹生珠, 汤富领, 薛红涛

表面技术 ›› 2020, Vol. 49 ›› Issue (9) : 291-297.

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表面技术 ›› 2020, Vol. 49 ›› Issue (9) : 291-297. DOI: 10.16490/j.cnki.issn.1001-3660.2020.09.033
表面失效及防护

C/SiC复合材料与抗氧化陶瓷涂层的优化匹配

  • 杨彦龙1, 汤富领1, 薛红涛1, 张凯峰2, 曹生珠2
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Optimal Matching of Anti-oxidation Ceramic Coatings with C/SiC Composites

  • YANG Yan-long1, TANG Fu-ling1, XUE Hong-tao1, ZHANG Kai-feng2, CAO Sheng-zhu2
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摘要

目的 快速筛选与C/SiC复合材料界面热应力最低匹配的抗氧化涂层材料。方法 在原用于单层陶瓷材料热冲击计算模型的基础上改造建立了一个简易但能合理解释热冲击下抗氧化涂层失效的解析模型。采用有限元模型对解析模型得到的界面热应力加以验证,二者结果基本一致。结果 当裂纹长度小于30 μm时,裂纹对涂层-基体界面热应力的影响几乎可以忽略,然而,当涂层表面预制长度大于30 μm的微裂纹或增加涂层中的微裂纹密度均能够有效降低涂层-基体界面的热应力,提高涂层在服役条件下的断裂临界温差,改善涂层材料的抗热震性,提高涂层的使用寿命。利用该解析模型计算出各温度下涂层-基体体系具体的断裂临界温差,并预测涂层-基体体系最危险的工作温度区间。结论 解析模型可以用来方便地计算涂层材料的热应力和断裂临界温差,从而筛选出热应力最小匹配的涂层材料。C/SiC复合材料的抗氧化涂层中预制长度大于30 mm的微裂纹,可有效提高涂层抗热震性能。

Abstract

The work aims to quickly select the anti-oxidation coating materials on the C/SiC composites with the minimum interfacial thermal stress. An easy-used analytical model based on the thermal shock calculation model previously used for single-layer ceramic materials was established, which could reasonably explain the failure of oxidation resistant coating under thermal shock. The thermal stress obtained by the analytical model was verified by the finite element model and the results were consistent. When the crack length was less than 30 μm, the effect of the crack on the interfacial thermal stress of the coating- substrate was almost negligible. However, the micro-cracks with the pre-fabrication length over 30 μm or the increase of crack density on the coating surface could effectively reduce the coating-substrate interfacial thermal stress and improve the critical fracture temperature difference of the coating under service conditions, strengthening the thermal shock resistance of coating materials and increasing the service life of coatings. The particular critical fracture temperature difference of the coating- substrate system was calculated at different initial temperature by this analytical model and the most dangerous working temperature range of the coating-substrate system was predicted. The analytic model can easily calculate thermal stress and critical fracture temperature difference of coating materials, thus screening out optimal matching of anti-oxidation coating material with C/SiC composites. The crack with pre-fabrication length over 30 mm in the anti-oxidation coating material of C/SiC composite can effectively improve the thermal shock performance of coating.

关键词

有限元;C/SiC复合材料;热冲击;涂层;界面热应力

Key words

finite element; C/SiC composite; thermal shock; coating; interfacial thermal stress

引用本文

导出引用
杨彦龙, 张凯峰, 曹生珠, 汤富领, 薛红涛. C/SiC复合材料与抗氧化陶瓷涂层的优化匹配[J]. 表面技术. 2020, 49(9): 291-297
YANG Yan-long, ZHANG Kai-feng, CAO Sheng-zhu, TANG Fu-ling, XUE Hong-tao. Optimal Matching of Anti-oxidation Ceramic Coatings with C/SiC Composites[J]. Surface Technology. 2020, 49(9): 291-297

基金

真空技术与物理国家级重点实验室开放基金(ZWK1706);国家自然科学基金(11764027)

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