质子交换膜燃料电池金属双极板改性碳基涂层技术研究进展

辛洋, 郭鹏, 李昊, 陈仁德, 孙丽丽, 马冠水, 汪爱英

表面技术 ›› 2020, Vol. 49 ›› Issue (6) : 22-33.

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表面技术 ›› 2020, Vol. 49 ›› Issue (6) : 22-33. DOI: 10.16490/j.cnki.issn.1001-3660.2020.06.003
专题——碳基功能薄膜材料与应用

质子交换膜燃料电池金属双极板改性碳基涂层技术研究进展

  • 辛洋1, 郭鹏2, 李昊2, 陈仁德2, 孙丽丽2, 马冠水2, 汪爱英3
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Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells

  • XIN Yang1, GUO Peng2, LI Hao2, CHEN Ren-de2, SUN Li-li2, MA Guan-shui2, WANG Ai-ying3
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摘要

对比了碳基涂层改性金属极板、未涂覆的金属极板和传统石墨极板性能的优劣,阐述了碳基涂层在优化金属极板导电耐蚀性能方面取得的最新成果,以及在质子交换膜燃料电池(Proton exchange membrane fuel cells, PEMFCs)环境长期运行后,碳基涂层出现性能失效及寿命受限等问题。通过分析影响碳基涂层性能的因素,指出由于非晶碳材料设计、微观结构等对其性能影响规律的系统化研究不足,导致非晶碳涂层/金属极板损伤及退化机理不明确。重点阐述了国内外关于PEMFCs金属极板改性碳基涂层材料技术的研究进展,包括调控本征碳基涂层(a-C)微观形貌优化涂层性能;采用理论计算与实验相结合的方法制备金属掺杂碳基涂层(a-C: Me),解决涂层与特定金属基体间粘附性差、压应力高等问题;设计多层结构碳基涂层以减少贯穿性缺陷。探讨了几类涂层失效机制,并对金属极板改性用碳基涂层技术进行了展望。

Abstract

In this work, the performances of bare metallic plate, traditional graphite plate and metallic bipolar plate modified with carbon-based coating used in the proton exchange membrane fuel cells (PEMFCs) were compared; the latest achievements of carbon-based coatings in improving the conductivity and corrosion resistance of metallic bipolar plates were reviewed; and issues such as performance degradation and limited life of carbon-based coatings were discussed, especially after long-term operation in PEMFCs environment. By analyzing the factors that affect the performance of carbon-based coatings, it was found that systematic researches on the relationship between microstructure of carbon-based coating and its performance were insufficient, leading to an unclear damage and degradation mechanism of a-C carbon coating/ metallic bipolar plate. The research progress of modified carbon-based coating materials for PEMFCs metal plates at home and abroad was mainly discussed, including improving the coating performance by adjusting the microstructure of carbon-based coatings (a-C); preparing metal-doped carbon coating (a-C:Me) by combing theoretical calculation with practice; solving the poor adhesion, high pressure stress and other issues between coating and special metallic matrix, design multi-layer structures to reduce penetrability defects. The failure mechanism of several kinds of coatings was discussed and the development trend of carbon-based coating technology for metallic plate modification was prospected.

关键词

质子交换膜燃料电池;双极板;碳基涂层;导电性能;耐腐蚀性能

Key words

proton exchange membrane fuel cell; bipolar plate; carbon-based film; conductivity; corrosion resistance

引用本文

导出引用
辛洋, 郭鹏, 李昊, 陈仁德, 孙丽丽, 马冠水, 汪爱英. 质子交换膜燃料电池金属双极板改性碳基涂层技术研究进展[J]. 表面技术. 2020, 49(6): 22-33
XIN Yang, GUO Peng, LI Hao, CHEN Ren-de, SUN Li-li, MA Guan-shui, WANG Ai-ying. Research Progress of Carbon-based Coating for Metal Bipolar Plates of Proton Exchange Membrane Fuel Cells[J]. Surface Technology. 2020, 49(6): 22-33

基金

王宽诚率先人才计划卢嘉锡国际团队(GJTD-2019-13);国家自然科学基金(51801226);宁波市“科技创新2025”重大专项(2018B10014)

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