硅烷涂层对316L不锈钢耐腐蚀性能的影响

林元华, 马毓聪, Mohd Talha, 李冰, 石云升, 孙志鹏, 唐亮

表面技术 ›› 2019, Vol. 48 ›› Issue (2) : 220-225.

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表面技术 ›› 2019, Vol. 48 ›› Issue (2) : 220-225. DOI: 10.16490/j.cnki.issn.1001-3660.2019.02.031
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硅烷涂层对316L不锈钢耐腐蚀性能的影响

  • 林元华1, 马毓聪2, Mohd Talha2, 李冰2, 石云升2, 孙志鹏2, 唐亮3
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Effect of Silane Coating on Corrosion Resistance of 316L Stainless Steel

  • LIN Yuan-hua1, MA Yu-cong2, Mohd Talha2, LI Bing2, SHI Yun-Sheng2, SUN Zhi-peng2, TANG Liang3
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摘要

目的 提高316L不锈钢的耐腐蚀性能。方法 在316L不锈钢样品表面涂覆主要成分为1,2-二(三乙氧基硅基)乙烷(BTSE)的硅烷涂层。通过电化学分析测试,评价涂覆硅烷涂层的316L不锈钢的耐蚀性,并通过扫描电子显微镜和扫描电化学显微镜对其表面形貌进行分析。结果 在相同的腐蚀环境下,与未涂覆硅烷涂层的316L不锈钢样品相比,涂覆硅烷涂层样品的表面更加光滑,点蚀现象明显好转。电化学测试结果显示,涂覆硅烷涂层的316L不锈钢样品的腐蚀电位为?565.02 mV,未涂覆硅烷涂层样品的腐蚀电位为?796.01 mV,前者明显高于后者,其腐蚀倾向明显减小。另外,涂覆硅烷涂层的316L不锈钢样品的腐蚀电流为2.5177 μA,未涂覆硅烷涂层样品的腐蚀电流为5.4291 μA,涂覆硅烷涂层样品的腐蚀电流明显更小,表现出了更好的耐腐蚀性能。通过观察扫描电化学显微镜图像可以得出,未涂覆硅烷涂层的316L不锈钢样品的电流范围为?3.144×10?9 ~ ?1.957×10?9 A,涂覆硅烷涂层的316L不锈钢样品的电流范围为?3.004×10?9~ ?1.975×10?9 A,涂覆硅烷涂层样品的电流范围更窄,腐蚀程度明显减轻。结论 在316L不锈钢表面涂覆硅烷涂层可以在一定程度上减缓样品的腐蚀程度,硅烷涂层起到了物理屏障的作用,显着提高了316L不锈钢的耐腐蚀性。

Abstract

The work aims to improve the corrosion resistance of 316L stainless steel. The silane coating with 1,2-bis (tri-ethoxysilyl) ethane (BTSE) as main component was coated on the surface of the 316L stainless steel sample. The corrosion re-sistance of coating on 316 stainless steel was evaluated by electrochemical analysis. The surface morphology was analyzed by scanning electron microscopy and scanning electrochemical microscopy. The silane-coated sample surface was smoother and pitting corrosion was significantly improved when compared to the silane-coated 316L stainless steel sample in the same corrosive environment. From the electrochemical test results, the corrosion potential of the silane-coated 316L stainless steel sample was ?565.02 mV and the corrosion potential of the uncoated-silane sample was ?796.01 mV. The corrosion potential of silane-coated 316L stainless steel sample was significantly higher than that of uncoated-silane sample, and the corrosion tendency was significantly reduced. In addition, the silane-coated 316L stainless steel sample had a corrosion current of 2.5177 μA and the uncoated sample had a corrosion current of 5.4291 μA. The silane-coated sample exhibited lower corrosion current and showed better corrosion resistance. From the scanning electrochemical microscopy image, the uncoated 316L stainless steel sample had a current range of ?3.144×10?9 ~ ?1.957×10?9 A, and the silane-coated 316L stainless steel sample had a current range of ?3.004×10?9 ~ ?1.975×10?9 A. The silane-coated sample had a narrower current range and less corrosion. Therefore, silane coating on the surface of 316L stainless steel can slow the corrosion of the sample to a certain extent. The silane coating acts as a physical barrier and significantly improves the corrosion resistance of 316L stainless steel.

关键词

腐蚀;硅烷涂层;电化学;不锈钢;点蚀

Key words

corrosion; silane coating; electrochemistry; stainless steel; pitting

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林元华, 马毓聪, Mohd Talha, 李冰, 石云升, 孙志鹏, 唐亮. 硅烷涂层对316L不锈钢耐腐蚀性能的影响[J]. 表面技术. 2019, 48(2): 220-225
LIN Yuan-hua, MA Yu-cong, Mohd Talha, LI Bing, SHI Yun-Sheng, SUN Zhi-peng, TANG Liang. Effect of Silane Coating on Corrosion Resistance of 316L Stainless Steel[J]. Surface Technology. 2019, 48(2): 220-225

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