环保无铜自抛光防污涂料的制备与性能研究

刘轶龙, 王胜龙, 李春光, 方大庆, 吴建华

表面技术 ›› 2017, Vol. 46 ›› Issue (12) : 1-5.

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PDF(4221 KB)
表面技术 ›› 2017, Vol. 46 ›› Issue (12) : 1-5. DOI: 10.16490/j.cnki.issn.1001-3660.2017.12.001
专题—海洋涂层技术

环保无铜自抛光防污涂料的制备与性能研究

  • 刘轶龙, 王胜龙, 李春光, 方大庆, 吴建华
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Preparation and Performance of Environment-friendly Copper-free Self-polishing Antifouling Paints

  • LIU Yi-long, WANG Sheng-long, LI Chun-guang, FANG Da-qing, WU Jian-hua
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摘要

目的 得到一种可以媲美传统含铜防污涂料防污效果的涂料配方,且具有对海洋环境友好的特点。方法 首先筛选符合无铜涂料技术需求的环保型防污剂,并进行涂料配方研究,得到最优环保无铜防污涂料配方。结果 设计开发的2组不同防污剂复配无铜自抛光防污涂料,其实际防污效果可以达到中期效防污涂料的评价标准,在实际防污效果上可以媲美3年期效以Cu2O为主防污剂的传统含铜自抛光防污涂料。2组防污剂复配配方为Econea/Dcoit及Econea/ZnPT,采用上述2种防污剂进行质量比1:1的防污剂复配,具有1+1>2的实际防污效果,并且在具有较好实际防污效果的同时,具备可以在海水中实现快速降解的优异环境友好性。在无铜涂料配方体系下,中期效防污涂料(3年)中丙烯酸锌树脂的最佳配方含量为40%~50%(湿重)。结论 环保无铜防污涂料的各项性能良好,具有广谱、高效的防污效果。

Abstract

This work aims to obtain a marine environment-friendly copper-free antifouling paint formula which rivals traditional copper antifouling paint. Environment-friendly antifoulant conforming to the technical demand of copper-free paint was selected firstly, coating formula was studied to obtain the optimal formula of environment-friendly copper-free antifouling paint. The two different antifoulants compounding copper-free self-polishing antifouling paint meet the evaluation standard of mid-potency antifouling paint, and can rival the 3 years potency traditional copper antifouling paint. Formula of the two groups is Econea/Dcoit and Econea/ZnPT, respectively. For the antifoulant being compounded by the 2 antifoulants with mass ratio of 1:1, the practical antifouling effect is 1+1>2. These two antifoulants have good practical anti-fouling effect and exhibit excellent environmental friendliness as they can degrade rapidly in seawater. The optimum formula content of acrylic zinc resin is 40%~50% (wet weight) in mid-potency antifouling paint in the copper-free antifouling paint formulation system. Various properties of the environment-friendly copper-free antifouling paint were good. The paint had broad spectrum, high efficiency and excellent antifouling effect.

关键词

无铜;自抛光;防污剂;浅海挂板;环境友好;性能优异

Key words

copper free; self-polishing; antifoulant; raft test; environment friendly; excellent performance

引用本文

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刘轶龙, 王胜龙, 李春光, 方大庆, 吴建华. 环保无铜自抛光防污涂料的制备与性能研究[J]. 表面技术. 2017, 46(12): 1-5
LIU Yi-long, WANG Sheng-long, LI Chun-guang, FANG Da-qing, WU Jian-hua. Preparation and Performance of Environment-friendly Copper-free Self-polishing Antifouling Paints[J]. Surface Technology. 2017, 46(12): 1-5

基金

“十三五”国家海洋经济创新发展示范项目(16CZB023SF12)

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