大型原油储罐内壁底板腐蚀机理及防护措施

刘栓, 王娟, 程红红, 南峰, 郭小平, 程庆利, 蒲吉斌, 王立平

表面技术 ›› 2017, Vol. 46 ›› Issue (11) : 47-54.

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PDF(1001 KB)
表面技术 ›› 2017, Vol. 46 ›› Issue (11) : 47-54. DOI: 10.16490/j.cnki.issn.1001-3660.2017.11.007
专题—海洋环境表面工程

大型原油储罐内壁底板腐蚀机理及防护措施

  • 刘栓1, 王娟1, 程红红1, 南峰1, 蒲吉斌1, 王立平1, 郭小平2, 程庆利3
作者信息 +

Corrosion Mechanism and Protective Measures of Inner Wall Baseplate of Large Crude Oil Storage Tank

  • LIU Shuan1, WANG Juan1, CHENG Hong-hong1, NAN Feng1, PU Ji-bin1, WANG Li-ping1, GUO Xiao-ping2, CHENG Qing-li3
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文章历史 +

摘要

大型原油储罐底板腐蚀是影响和决定油罐服役寿命的关键问题。原油本身并不具备强腐蚀性,油品在开采过程中常夹杂一定水和腐蚀性介质,在长期存储过程中“水沉油浮”,腐蚀性沉积水在油罐底部聚集,使罐底长期处于沉积水浸没状态。沉积水成分复杂,含有大量氯离子、硫酸盐和厌氧微生物,这些介质使油罐罐底处于强腐蚀环境,对油罐底板产生持续腐蚀。同时,浮顶油罐立柱的冲击和振动、液体紊流和原油压力会加速油罐底板腐蚀失效。详细探讨了油罐罐底的腐蚀机理和失效衍化机制,分析罐底在沉积水环境中的腐蚀形式,包括电化学腐蚀、冲刷腐蚀、堆积腐蚀、微生物腐蚀以及焊缝腐蚀等,介绍了环氧类、聚氨酯类、富锌底漆类、氟碳类等重防腐涂层的发展现状,分析了油罐防护所采用的重防腐涂料技术,提出了油罐底板防护的未来研究方向。

Abstract

Caseplate corrosion is a key issue affecting and determining service life of large-scale crude oil storage tank. Crude oil itself is noncorrosive, however, water and certain corrosive medium are usually mixed up with oils during exploitation process. “Water sinks and oil floats” during long-term storage, corrosive sedimentary water deposits on the bottom of oil tank, hence the tank bottom has been immersing in sedimentary water for a long term. Chemical composition of the sedimentary water is complex, which contains plenty of chloride, sulfate and anaerobic microorganisms. The mediums expose the oil tank bottom to strong corrosive environment and cause continuous corrosion to oil tank baseplate. Meanwhile, shock and vibration of the floating roof tank column, liquid turbulence and crude oil pressure will accelerate corrosion failure of oil tank baseplate. Corrosion mechanism and failure derivation mechanism of the oil tank bottom were discussed in detail; corrosion forms of tank bottom in sedimentary water environment were analyzed, including electrochemical corrosion, erosion corrosion, stack corrosion, microbial corrosion and weld corrosion; development status of heavy-duty anti-corrosive coating was introduced, including epoxy, polyurethane, zinc rich primer, fluorocarbon coatings; heavy-duty anti-corrosive coating technologies adopted by oil tank protection were analyzed; finally future research directions of oil tank baseplate protection was presented.

关键词

原油储罐;底板腐蚀;沉积水;腐蚀机理;阴极保护;重防腐涂料

Key words

crude oil tank; baseplate corrosion; sedimentary water; corrosion mechanism; cathodic protection; heavy-duty anti-corrosive coating

引用本文

导出引用
刘栓, 王娟, 程红红, 南峰, 郭小平, 程庆利, 蒲吉斌, 王立平. 大型原油储罐内壁底板腐蚀机理及防护措施[J]. 表面技术. 2017, 46(11): 47-54
LIU Shuan, WANG Juan, CHENG Hong-hong, NAN Feng, GUO Xiao-ping, CHENG Qing-li, PU Ji-bin, WANG Li-ping. Corrosion Mechanism and Protective Measures of Inner Wall Baseplate of Large Crude Oil Storage Tank[J]. Surface Technology. 2017, 46(11): 47-54

基金

国家自然科学基金(41506098);中国博士后基金和第九批特等资助(2015M580528,2016T90553);浙江省博士后科研项目择优资助(BSH1502160);宁波市自然科学基金(2016A610261)

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