纳米WC增强Ni基合金喷熔层组织结构与抗磨粒磨损特性

唐康康, 丁彰雄, 李超

表面技术 ›› 2017, Vol. 46 ›› Issue (8) : 27-32.

PDF(7191 KB)
PDF(7191 KB)
表面技术 ›› 2017, Vol. 46 ›› Issue (8) : 27-32. DOI: 10.16490/j.cnki.issn.1001-3660.2017.08.005
专题——复合涂层及其制备技术

纳米WC增强Ni基合金喷熔层组织结构与抗磨粒磨损特性

  • 唐康康, 丁彰雄, 李超
作者信息 +

Microstructure and Abrasive Wear Resistance of Nano-WC Reinforced Ni-based Alloy Spray-melted Coatings

  • TANG Kang-kang, DING Zhang-xiong, LI Chao
Author information +
文章历史 +

摘要

目的 研究纳米WC对Ni基合金喷熔层抗磨粒磨损性能的影响。方法 采用扫描电镜、X射线衍射分析了氧乙炔火焰喷熔Ni基合金层和两种不同结构WC增强Ni基合金喷熔层的微观组织和相结构,并通过磨粒磨损试验平台对三种涂层进行磨损性能测试。结果 纳米WC粉末的加入,能有效提高喷熔层的宏观硬度。通过组织分析得出纳米WC增强Ni基喷熔层中除含有γ-(Ni,Cr)固溶体、Cr的碳化物、硼化物以及微米级WC颗粒之外,还含有一定量的纳米WC团聚体和少量高硬度的W2C相。磨粒磨损实验结果显示,纳米WC增强Ni基喷熔层的磨损失重分别为Ni60和NiWC35涂层失重的56%和73%。对比磨损后涂层的表面微观形貌可知,纳米WC颗粒在涂层中能有效降低磨粒压入喷熔层的深度,从而控制磨粒对喷熔层的犁削量。结论 纳米WC增强Ni基合金喷熔层中含有的γ-(Cr,Ni)固溶体、Cr23C6、Cr7C3、Cr3Ni2及未熔化的WC颗粒和WC脱碳形成的W2C等硬质相,使镍基自熔合金涂层的硬度有较大提高,同时也大大提高了涂层的抗磨粒磨损性能。

Abstract

The work aims to study effects of Nano-WC on abrasive wear resistance of Ni-based alloy spray-melted coating. Microstructure and phase structure of Ni-based alloy spray-melted in oxyacetylene flame as well as WC-reinforced Ni-based alloy spray-melted coatings of two different structures were analyzed using scanning electron microscopy (SEM) and X-ray diffractometer (XRD). Meanwhile, wear resistance of the three coatings was tested using abrasive wear testbed. Addition of nano-WC powder could effectively improve macro hardness of spray-melted coating. Nano-WC reinforced Ni-based alloy spray-melted coatings contained not only γ-(Ni, Cr) solid solutions, Cr carbide, boride and micro-scale WC particles, but also a certain amount of nano-WC particles and a small amount of high-hardness W2C phase. The results of abrasive test showed that wear weight loss of nano WC-reinforced layer was 56% of that of NiWC35 coating and 73% of that of Ni60. Compared with surface microstructure of the worn coating, nano-WC particles in the coating could effectively reduce depth of abrasive particles impressed into the spray-melted layer, so as to control ploughing amount of the abrasive particles on the spraying layer. Generally, the by γ-(Ni,Cr) solid solutions, Cr23C6, Cr7C3, Cr3Ni2, unmelted WC particles and hardness phases such as W2C formed by WC decarburization in the nano WC-reinforced Ni-based alloy spray-melted coating can greatly improve hardness and abrasive wear resistance of the coating.

关键词

磨粒磨损;纳米WC;Ni基合金;喷熔层;氧乙炔火焰喷熔

Key words

abrasive wear; nano WC; Ni-based alloy; spray-meltedand fused coatings; oxyacetylene-acetylene flame spray melting

引用本文

导出引用
唐康康, 丁彰雄, 李超. 纳米WC增强Ni基合金喷熔层组织结构与抗磨粒磨损特性[J]. 表面技术. 2017, 46(8): 27-32
TANG Kang-kang, DING Zhang-xiong, LI Chao. Microstructure and Abrasive Wear Resistance of Nano-WC Reinforced Ni-based Alloy Spray-melted Coatings[J]. Surface Technology. 2017, 46(8): 27-32

基金

国家自然科学基金(51422507)

PDF(7191 KB)

Accesses

Citation

Detail

段落导航
相关文章

/