TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能

马永, 朱红梅, 孙楚光, 廖帮亮, 申龙章, 何彬, 朱卫华, 王新林

表面技术 ›› 2017, Vol. 46 ›› Issue (6) : 238-243.

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表面技术 ›› 2017, Vol. 46 ›› Issue (6) : 238-243. DOI: 10.16490/j.cnki.issn.1001-3660.2017.06.038
专题——激光表面处理技术

TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能

  • 马永1, 朱红梅1, 孙楚光1, 廖帮亮1, 申龙章1, 何彬1, 朱卫华2, 王新林3
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Microstructure and Properties of Y2O3-doped Laser Cladded Composite Coating on TC4 Titanium Alloy

  • MA Yong1, ZHU Hong-mei1, SUN Chu-guang1, LIAO Bang-liang1, SHEN Long-zhang1, HE Bin1, ZHU Wei-hua2, WANG Xin-lin3
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摘要

目的 提高钛合金表面的耐磨性能。方法 在TiB2:TiC=1:3的粉末配比下,添加不同质量分数Y2O3稀土氧化物,制备成膏状混合粉末。采用5 kW横流CO2激光器,在TC4钛合金表面激光熔覆掺Y2O3的TiB2和TiC粉末,制备耐磨性复合涂层。通过扫描电子显微镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)对激光熔覆层的微观形貌和组织成分进行了分析;用显微维氏硬度计对熔覆层的显微硬度进行了测量;用万能摩擦磨损试验机对熔覆层的耐磨性能进行了测试。结果 添加4%Y2O3后,熔覆层中部组织明显细化,结合区由致密组织结构转变为晶须网状结构;熔覆层的最高显微硬度为1404.6HV0.2,是基体的3.7倍;熔覆层的磨损量减少了66.67%,且其摩擦系数有明显的降低。结论 添加4%Y2O3对TC4钛合金表面激光熔覆TiB/TiC复合熔覆层耐磨性能有显著的提高。

Abstract

The work aims to improve wear resistance of TC4 titanium alloy. Pasty mixed powder was prepared at a proper ratio of TiB2:TiC (1:3) and adding Y2O3 rare earth oxide in different mass fractions. Wear resistant composite coating was prepared by laser cladding Y2O3-doped TiB2 and TiC powder on the surface of TC4 titanium alloy using 5 kW continuous wave CO2 laser. Microstructure and composition of the laser cladding layers were analyzed with scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and X-ray diffractometer (XRD); microhardness of the laser cladding layer was measured with Vickers hardness tester; and wear resistance was tested with universal friction and wear tester. After 4% Y2O3 was added, grain size of the middle structure was greatly refined; microstructure of the bonding zone was transformed from compact structure to reticular whisker structure; maximum microhardness of the cladding layer was 1404.6HV0.2, 3.7 times as high as that of TC4 substrate; wear loss of the cladding layer decreased by 66.67%, and the friction coefficient decreased remarkably. Wear resistance of the laser cladded TiC/TiB composite cladding coating on the surface of TC4 titanium alloy can be improved significantly by adding 4% Y2O3.

关键词

TC4钛合金;激光熔覆;复合涂层;显微组织;显微硬度;耐磨性能

Key words

TC4 titanium alloy; laser cladding; composite coating; microstructure; microhardness; wear resistance

引用本文

导出引用
马永, 朱红梅, 孙楚光, 廖帮亮, 申龙章, 何彬, 朱卫华, 王新林. TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能[J]. 表面技术. 2017, 46(6): 238-243
MA Yong, ZHU Hong-mei, SUN Chu-guang, LIAO Bang-liang, SHEN Long-zhang, HE Bin, ZHU Wei-hua, WANG Xin-lin. Microstructure and Properties of Y2O3-doped Laser Cladded Composite Coating on TC4 Titanium Alloy[J]. Surface Technology. 2017, 46(6): 238-243

基金

湖南省自然科学基金(2015JJ6098)

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