环保型植酸缓蚀剂用于烧结NdFeB材料工序间防锈的研究

刘慧丛, 南海洋, 李卫平, 朱立群, 张健, 杜凡

表面技术 ›› 2017, Vol. 46 ›› Issue (4) : 7-11.

PDF(5502 KB)
PDF(5502 KB)
表面技术 ›› 2017, Vol. 46 ›› Issue (4) : 7-11. DOI: 10.16490/j.cnki.issn.1001-3660.2017.04.002

环保型植酸缓蚀剂用于烧结NdFeB材料工序间防锈的研究

  • 刘慧丛1, 南海洋1, 李卫平1, 朱立群1, 张健2, 杜凡2
作者信息 +

Environmental Friendly Phytic Acid Inhibiter Used in Sintered NdFeB to Prevent Corrosion

  • LIU Hui-cong1, NAN Hai-yang1, LI Wei-ping1, ZHU Li-qun1, ZHANG Jian2, DU Fan2
Author information +
文章历史 +

摘要

目的 研究烧结NdFeB材料在工序间的腐蚀行为以及植酸的防锈作用和机制。方法 通过SEM、EDS、XRD和XPS测试了试样的表面形貌、元素成分、相成分和元素结合能状态。结果 NdFeB的晶间富钕相在工序间发生严重腐蚀,造成主相晶粒脱落,不利于镀层结合力。结论 植酸有效地抑制了工序间的腐蚀,其作用机制主要是植酸分子在NdFeB表面的吸附。钕、磷、氧等元素的结合能变化也表明这种吸附包括化学吸附的作用。

Abstract

The work aims to study corrosion behaviors of sintered NdFeB in interprocess as well as rust inhibition and mechanism of phytic acid. Surface morphology, elements composition, phase composition and element bonding energy state were tested with SEM, EDS, XRD and XPS, respectively. NdFeB was subject to serious corrosion in intergranular Nd-rich phase and thereby principal phase grain fell off, which was harmful to the coating adhesion. Phytic acid can efficiently inhibit the interprocess corrosion by adsorption by adsorption of phytic acid on the surface of NdFeB. The change of bonding energy in Nd, P and O elements also shows the effects of adsorption including chemical adsorption.

关键词

植酸;缓蚀剂;NdFeB;腐蚀防护;吸附;富钕相

Key words

phytic acid; inhibitor; NdFeB; corrosion protection; adsorption; Nd rich phase

引用本文

导出引用
刘慧丛, 南海洋, 李卫平, 朱立群, 张健, 杜凡. 环保型植酸缓蚀剂用于烧结NdFeB材料工序间防锈的研究[J]. 表面技术. 2017, 46(4): 7-11
LIU Hui-cong, NAN Hai-yang, LI Wei-ping, ZHU Li-qun, ZHANG Jian, DU Fan. Environmental Friendly Phytic Acid Inhibiter Used in Sintered NdFeB to Prevent Corrosion[J]. Surface Technology. 2017, 46(4): 7-11

基金

国家自然科学基金资助项目(U1637204)

PDF(5502 KB)

Accesses

Citation

Detail

段落导航
相关文章

/