莫高窟壁画疱疹病害的微观形貌和成分研究

陈港泉, 胡红岩, 李燕飞, 李振, 靳治良, 钱玲, 水碧纹, 吕功煊

表面技术 ›› 2016, Vol. 45 ›› Issue (10) : 162-167.

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表面技术 ›› 2016, Vol. 45 ›› Issue (10) : 162-167. DOI: 10.16490/j.cnki.issn.1001-3660.2016.10.025
表面失效及防护

莫高窟壁画疱疹病害的微观形貌和成分研究

  • 陈港泉1, 胡红岩2, 李振2, 靳治良2, 钱玲2, 吕功煊2, 李燕飞3, 水碧纹3
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Micro-morphology and Composition of Mural Herpes in Mogao Grottoes

  • CHEN Gang-quan1, HU Hong-yan2, LI Zhen2, JIN Zhi-liang2, QIAN Ling2, LYU Gong-xuan2, LI Yan-fei3, SHUI Bi-wen3
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摘要

目的 研究壁画疱疹盐分或元素的分布规律,为病害治理提供依据。方法 使用扫描电子显微镜(SEM)、场发射扫描电子显微镜(FESEM)、X 射线能谱(EDS)、X 射线衍射(XRD)对疱疹表面的微观形貌、结构及成分进行分析。结果 SEM 研究结果表明,疱疹表面被粘土质包裹,其核心部分为无机结晶盐,从部分疱疹剖面可观测到立方体或者近立方体形态的无机盐晶体。FESEM 及EDS 分析结果显示,大部分疱疹盐结晶的主要成分以Na、Cl 元素为主,少部分疱疹中含有Mg、Ca、S 等元素。另外,疱疹中Na 和Cl 以及S 和Ca 元素具有良好的比例对应关系。结论 莫高窟壁画疱疹中的无机盐主要由易溶盐NaCl 构成,少量疱疹还含有CaCl2、MgSO4、CaSO4 等可溶盐或中溶盐。

Abstract

The work aims to study the distribution law of salt or elements in mural herpes so as to provide basis for mural salts damage treatment. The morphology, structure, internal elements and composition of the herpes were investigated by virtue of scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), X-ray energy spectrometer (EDS) and X-ray diffraction (XRD). The SEM and FESEM clearly showed that the herpes surfaces were covered by clay with a major composition of inorganic crystals of salt in the core herpes. Furthermore, cubic or cube-like salt crystals could be observed on cross-sections of the herpes. According to the results of FESEM and EDS analysis, the Na and Cl elements were main components of salt crystals in the majority of herpes, and Ca, S, Mg and other elements could also be detected in some herpes. More specifically, some elements, such as Na and Cl, Ca and S, exhibited good proportionality. On the basis of above results, it can be concluded that the inorganic salts in mural herpes are mainly composed of soluble salt NaCl, and a small number of herpes contains soluble salt or sparingly soluble salt such as CaCl2, CaSO4, MgSO4.

关键词

疱疹病害;盐;莫高窟;壁画;扫描电子显微镜

Key words

herpes damage; salts; Mogao grottoes; mural; SEM

引用本文

导出引用
陈港泉, 胡红岩, 李燕飞, 李振, 靳治良, 钱玲, 水碧纹, 吕功煊. 莫高窟壁画疱疹病害的微观形貌和成分研究[J]. 表面技术. 2016, 45(10): 162-167
CHEN Gang-quan, HU Hong-yan, LI Yan-fei, LI Zhen, JIN Zhi-liang, QIAN Ling, SHUI Bi-wen, LYU Gong-xuan. Micro-morphology and Composition of Mural Herpes in Mogao Grottoes[J]. Surface Technology. 2016, 45(10): 162-167

基金

国家自然科学基金面上项目(21177021);国家文物局课题(20110207); 973 计划课题(2012CB720901、2012CB720905);国家科技支撑计划课题(2014BAK16B01)

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