300M 钢表面冷喷涂锌镍复合涂层性能研究

石仲川, 张晓云, 汤智慧, 陆峰

表面技术 ›› 2016, Vol. 45 ›› Issue (6) : 100-106.

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表面技术 ›› 2016, Vol. 45 ›› Issue (6) : 100-106. DOI: 10.16490/j.cnki.issn.1001-3660.2016.06.015
膜层材料与技术

300M 钢表面冷喷涂锌镍复合涂层性能研究

  • 石仲川1, 张晓云2, 汤智慧2, 陆峰2
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Properties of Cold Spray Zn/Ni Coatings on 300M Steel

  • SHI Zhong-chuan1, ZHANG Xiao-yun2, TANG Zhi-hui2, LU Feng2
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摘要

目的 研究 300M 高强钢表面的冷喷涂锌镍复合涂层的涂层性能。 方法 采用机械混合的方式将锌粉和镍粉进行混合,利用低温气动喷涂技术在 300M 高强钢表面制备锌镍复合涂层,采用扫描电子显微镜、能量色散谱和显微硬度测试仪研究涂层的微观组织结构。采用普通中性盐雾加速实验、涂层破损盐雾加速试验及户外暴晒试验,对冷喷涂锌镍涂层的抗腐蚀性能进行综合评价。考核冷喷涂对300M 钢基材疲劳性能的影响。结果 根据 SEM 的表面及截面图片分析,冷喷涂锌镍复合涂层十分致密,且无孔隙及裂纹,涂层的孔隙率平均为 0.4%,结合强度 40 MPa 左右。根据 EDS 结果分析,锌镍复合涂层中锌的质量分数为 85%左右,镍的质量分数为 15%左右。锌镍复合涂层的显微硬度为 70.8HV0.49。锌镍复合涂层中镍粒子的强化作用,提高了涂层的硬度。冷喷涂锌镍复合涂层具有非常好的抗腐蚀性能,盐雾实验超过 770 h,即使涂层破损也可以达到 600 h。户外暴晒实验 12 个月表面无明显腐蚀,并且冷喷涂对 300M 钢基材的疲劳性能没有影响。 结论 冷喷涂锌镍复合涂层作为抗腐蚀涂层,可以对300M 高强钢提供保护。

Abstract

Objective To study the performance of Zn/Ni composite coatings on 300M high-strength steel surface, which were deposited by cold gas dynamic spray. Methods The coating was sprayed by Zn and Ni physical mixture powder on 300M high-strength steel surface. The morphology and microstructure of the coatings were analyzed by the SEM images, EDS and microhardness tester. The corrosion resistance of Zn/Ni coatings was comprehensively investigated by neutral salt-spray test, coating furcated test and atmospheric exposure test. The effect of cold spray on the fatigue property of 300M steel substrate was tested. Results The surface and cross-section SEM images indicated that the cold sprayed Zn/Ni composite coatings were very compact, without pores and cracks, the porosity of Zn/Ni coatings was 0.4% and the bonding strength was 40 MPa. The EDS analysis result showed that the mass fractions of Zn and Ni in the Zn/Ni composite coatings were about 85% and 15%, respectively. The microhardness of Zn/Ni coatings was 70.8HV0.49, this is because the hardness of the coatings was improved by the strengthening effect of Ni in the Zn/Ni coatings. Cold sprayed Zn/Ni composite coatings had very good corrosion resistance. The salt spray result of Zn/Ni coatings could reach 770 h, and it could reach 600 h even at coatings failure. No obvious corrosion was observed on the surface after 12-month atmospheric exposure test, and cold spray had no influence on the fatigue property of 300M steel substrate. Conclusion Cold sprayed Zn/Ni composite coatings could be used as efficient corrosion-resistant coatings on 300M high strength steel surfaces.

关键词

冷喷涂;锌镍复合涂层;微观结构;硬度;盐雾试验;抗腐蚀性能

Key words

cold spray; Zn/Ni coatings; microstructure; hardness; salt spray; anticorrosion performance

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导出引用
石仲川, 张晓云, 汤智慧, 陆峰. 300M 钢表面冷喷涂锌镍复合涂层性能研究[J]. 表面技术. 2016, 45(6): 100-106
SHI Zhong-chuan, ZHANG Xiao-yun, TANG Zhi-hui, LU Feng. Properties of Cold Spray Zn/Ni Coatings on 300M Steel[J]. Surface Technology. 2016, 45(6): 100-106

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