DUAN Ti-gang,HUANG Guo-sheng,MA Li,ZHANG Wei,PENG Wen-shan,XU Li-kun,LIN Zhi-feng,HE Hua,BI Tie-man.Research on Preparation and Anticorrosion Performance of Carbon Steel-substrate Self-healing Coating[J],50(4):344-350, 375
Research on Preparation and Anticorrosion Performance of Carbon Steel-substrate Self-healing Coating
Received:April 07, 2020  Revised:July 21, 2020
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DOI:10.16490/j.cnki.issn.1001-3660.2021.04.036
KeyWord:self-healing coating  nicrocapsule  two-component  neutral salt spray test
                          
AuthorInstitution
DUAN Ti-gang State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
HUANG Guo-sheng State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
MA Li State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
ZHANG Wei State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
PENG Wen-shan State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
XU Li-kun State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
LIN Zhi-feng State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao , China
HE Hua Dalian Shipbuilding Industry Co., Ltd, Dalian , China
BI Tie-man Dalian Shipbuilding Industry Co., Ltd, Dalian , China
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Abstract:
      The emulsion polymerization method with tung oil and inhibitor serving as the capsule core is used to synthetize the self-healing microcapsules. And a certain amount of self-healing microcapsules are added into the anticorrosive coating in order to improve the self-healing ability of coating and to enhance the anticorrosion performance of carbon steels. Analysis results of SEM and thermogravimetry show that self-healing microcapsules possess a diameter of ~3 μm and that the core coverage percent reaches 48%. Experimental results of neutral salt spray tests and immersion tests show that the organic coating presents an optimal anticorrosive ability accompanying with the best self-healing action when the content of microcapsules in the coating reaches 10% and the ratio of tung oil and inhibitor in the core is 5∶1. The organic anticorrosive coating with two- component microcapsules has the satisfactory self-healing activity, and has long-term protective effects on the metal materials.
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