WEN Fang,YANG Bo,PENG Xiao-po,ZHANG Shuang-hong,HUANG Guo-jia.Advance on Graphene Conductive Coatings[J],50(3):141-148, 157
Advance on Graphene Conductive Coatings
Received:March 12, 2020  Revised:June 03, 2020
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DOI:10.16490/j.cnki.issn.1001-3660.2021.03.012
KeyWord:graphene  conductive coatings  filler  mechanism  electrical conductivity
              
AuthorInstitution
WEN Fang Guangzhou Special Pressure Equipment Inspection and Research Institute, National Quality Supervision and Inspection Center of Graphene Product, Guangzhou , China
YANG Bo Guangzhou Special Pressure Equipment Inspection and Research Institute, National Quality Supervision and Inspection Center of Graphene Product, Guangzhou , China
PENG Xiao-po Guangzhou Customs District Technology Center, Guangzhou , China
ZHANG Shuang-hong Guangzhou Special Pressure Equipment Inspection and Research Institute, National Quality Supervision and Inspection Center of Graphene Product, Guangzhou , China
HUANG Guo-jia Guangzhou Special Pressure Equipment Inspection and Research Institute, National Quality Supervision and Inspection Center of Graphene Product, Guangzhou , China
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Abstract:
      Graphene has many physicochemical properties such as ultra-high conductivity, mechanical property and thermal conductivity, which makes it the most widely studied two-dimensional nanomaterials. As a special and functional filler, graphene has been widely studied in the field of conductive anticorrosive coatings. In this paper, the structure characteristics of graphene were briefly summarized. The special crystal structure made it excellent physical and chemical properties. As a filler, graphene could improve the conductivity and corrosion resistance of coatings by taking advantage of its excellent conductivity and lamellar structure. Next, specific problems in the application of graphene in conductive coatings were described in detail. The dispersion of graphene was solved by adding additives and functionalizing modification of graphene oxide; an appropriate amount of additive was the key factor of conductive coating performance; graphene composites could reduce the additive amount of graphene and produce synergistic effects; and the preparation process of graphene conductive coating mainly included:solution mixing, melt blending and in-situ polymerization. Then, the conductive mechanism of graphene conductive coatings was described and analyzed by combining with the conductive model. The competition mechanism suggested that the conductivity of doped conductive coatings was the result of competition among conductive pathways, tunnel effect and field emission. Finally, the application prospect of graphene conductive coatings was prospected, and the research suggestions of graphene in the field of conductive coatings were put forward from the aspects of graphene dispersion method, mechanism research, preparation process, etc.
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