ZHANG Xue-fei,LI Meng-ya,KONG Long-fei,WANG Meng,YAN Lu,XIAO Feng-juan.Research Progress in Metal Photoelectrochemical Cathodic Protection Materials and Its Anticorrosion Function Realization[J],50(3):128-140
Research Progress in Metal Photoelectrochemical Cathodic Protection Materials and Its Anticorrosion Function Realization
Received:September 29, 2020  Revised:February 08, 2021
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DOI:10.16490/j.cnki.issn.1001-3660.2021.03.011
KeyWord:photoelectrochemical cathodic protection  nano-film materials  semiconductor heterojunctions  photogenerated electrons  photoanode electrodes  anticorrosive coating
                 
AuthorInstitution
ZHANG Xue-fei 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
LI Meng-ya 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
KONG Long-fei 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
WANG Meng 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
YAN Lu 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
XIAO Feng-juan 1.School of Material Science and Engineering,Shijiazhuang , China; 2.Key Laboratory of Advanced Materials for Transportation Engineering and Environment Coordinated Development of Hebei Province, Shijiazhuang Tiedao University, Shijiazhuang , China
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Abstract:
      Photoelectrochemical cathodic protection is an energy-saving, environmentally friendly and economical corrosion protection technology in comparison with traditional corrosion protection methods. In this technology, the photoelectrochemical cathodic protection materials are purposed to generate photogenerated electrons under visible light illumination. The photogenerated electrons are transferred to the metal with the driving force of the potential difference, which is enriched on the metal surface to enable a negative shift of the metal's potential, thereby realizing the forced protection of the metal. This paper summarizes the preparation methods and performance characteristics of photoelectrochemical cathodic protection materials at home and abroad in recent years. It also describes the strategies and technologies of improving photoelectrochemical cathodic protection performance, including morphology control, element doping, semiconductor recombination, heterostructure formation, and material coupling, which can resolve the current problems of TiO2 film materials. Then, the performance and application of non-TiO2 photoelectrochemical cathodic protection nanomaterials are summarized, such as ZnO, SrTiO3, In2O3, g-C3N4, and Bi-based metal oxides. The approaches that realizing the anticorrosion function realization of photoelectrochemical cathodic protection materials are clarified in recent years, including photoanode method and direct coating method. Meanwhile, the advantages and disadvantages of them are compared. Based on the previous reports, the development trendency, the problems about metal photoelectrochemical cathodic protection materials and anticorrosion function realization are proposed.
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