DAI Yuan-jing,LI Xiao-lei,LING Yan-li,ZOU Yang,ZHANG Ji-ping,ZHANG Chen-hui.Tribological Properties of Non-thiophosphorous Organic Molybdenum[J],49(9):35-44
Tribological Properties of Non-thiophosphorous Organic Molybdenum
Received:June 29, 2020  Revised:September 20, 2020
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DOI:10.16490/j.cnki.issn.1001-3660.2020.09.003
KeyWord:SPFMo  anti-friction and anti-wear  self-repairing  low viscosity lubricant additive  SPFMo content  operating temperature
                 
AuthorInstitution
DAI Yuan-jing 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China; 2.Research Institute of Lubrication, Tianjin Research Institute for Advanced Equipment, Tsinghua University, Tianjin , China
LI Xiao-lei 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China; 2.Research Institute of Lubrication, Tianjin Research Institute for Advanced Equipment, Tsinghua University, Tianjin , China
LING Yan-li 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China
ZOU Yang 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China
ZHANG Ji-ping 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China
ZHANG Chen-hui 1.State Key Laboratory of Tribology, Tsinghua University, Beijing , China; 2.Research Institute of Lubrication, Tianjin Research Institute for Advanced Equipment, Tsinghua University, Tianjin , China
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Abstract:
      The aims to research tribological properties of non-thiophosphorous organic molybdenum, in order to meet the demand of the development of low viscosity lubricating oil of engine, a new kind of sulfur- and phosphorus-free organic molybdenum (SPFMo) was synthesized and added into the lubricating oil 0W20. Moreover, the influence of SPFMo content, temperature, load and rotation speed on the tribological performance of 0W20 was studied in detail. The results show that the SPFMo shows good anti-friction and anti-wear performances, both the COF and wear diameter of 0W20 can be decreased. During the friction process, the Mo is enriched and has the function of lubrication, anti-wear and self-repairing. MoS2 and MoO3 are generated by tribochemical reaction, which is the main part of the lubricating film. The SPFMo content and temperature in which the SPFMo can show great tribological performance is 0.25wt%~0.5wt% and 100~130 ℃, respectively. When the temperature is 120 ℃, the COF and wear diameter can be decreased by 27.5% and 7.8% by the addition of 0.5% SPFMo. The COF of 0W20+0.5%SPFMo decreases firstly and then increases with the increase of temperature, decreases with the increase of rotation speed and friction load. The wear diameter of 0W20+0.5%SPFMo decreases firstly and then increases with the increase of temperature, increases with the increase of rotation speed and friction load. Finally, the results can be helpful for designing and selecting new additives of engine oil with high low viscosity.
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