CAO Jing-yi,ZHANG Hai-yong,YANG Wen-jing,CHEN Rong-rong,LIU Jing-yuan,WANG Jun.Preparation and Properties of KCC-1/PVDF Superhydrophobic and Ultra-slip Surfaces[J],49(6):152-158
Preparation and Properties of KCC-1/PVDF Superhydrophobic and Ultra-slip Surfaces
Received:July 03, 2019  Revised:June 20, 2020
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DOI:10.16490/j.cnki.issn.1001-3660.2020.06.018
KeyWord:superhydrophobic  ultra-slip  KCC-1  PVDF  corrosion resistance  anti-icing
                 
AuthorInstitution
CAO Jing-yi 1.Unit 92228, People’s Liberation Army, Beijing , China
ZHANG Hai-yong 1.Unit 92228, People’s Liberation Army, Beijing , China
YANG Wen-jing 2.School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin , China
CHEN Rong-rong 2.School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin , China
LIU Jing-yuan 2.School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin , China
WANG Jun 2.School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin , China
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Abstract:
      The work aims to prepare KCC-1/PVDF superhydrophobic coatings by incorporating silica (KCC-1) microspheres into polyvinylidene fluoride (PVDF) and then prepare ultra-slip coatings by using different coating modifiers on this basis. KCC-1 microspheres were synthesized by calcination with cetylpyridinium bromide as a template and dispersed in polyvinylidene fluoride (PVDF) solution to prepare KCC-1/PVDF coating on the surface of magnesium alloy. Then, the surface of KCC-1/PVDF coating was modified with different modifiers (PFOTES, HDTES and dimethicone). After the modification with HDTES, a superhydrophobic coating with a water contact angle of 155° was obtained. Added with dimethicone, an ultra-slip surface with a sliding angle of 4.5° was obtained. In the friction and wear test, the wear resistance of the ultra-slip surface was better than that of the superhydrophobic surface and the blank magnesium alloy. The results of the anti-icing experiment showed that the superhydrophobic and ultra-slip surfaces could effectively delay the freezing of droplets on the surface. The KCC-1/PVDF superhydrophobic and ultra-slip surfaces can effectively protect the magnesium alloy substrate and the ultra-slip coating is superior to the superhydrophobic coating in corrosion resistance, of which the corrosion inhibition efficiency IE% is 100% and 98.28%, respectively.
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