ZHAO Ya-xuan,WANG Shao-gang,YE Qing-feng,CHEN Yuan,ZHAO Li.Preparation and Oxidation Resistance of Ni-based Alloy Coating with High Cr Content by Electric Arc Spraying[J],47(1):21-26
Preparation and Oxidation Resistance of Ni-based Alloy Coating with High Cr Content by Electric Arc Spraying
Received:August 17, 2017  Revised:January 20, 2018
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DOI:10.16490/j.cnki.issn.1001-3660.2018.01.004
KeyWord:Ni-based alloy with high Cr content  electric arc spraying  steel Q345  oxidation resistance  microstructure
              
AuthorInstitution
ZHAO Ya-xuan School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing , China
WANG Shao-gang School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing , China
YE Qing-feng School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing , China
CHEN Yuan School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing , China
ZHAO Li School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing , China
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Abstract:
      The work aims to improve high temperature oxidation resistance of power plant equipment and components in high temperature environment. Ni-based alloy coatings with high Cr content were prepared on steel Q345 by adopting arc spraying. Anti-oxidation behavior and oxidation mechanism of the coatings at 750 ℃ were investigated, and comparative analysis was carried out to oxidation behavior of steel Q345 substrate without coating. Cyclic oxidation weight increase test at 750 ℃ showed that, oxidation kinetic curve of the coated sample presented a parabola style, the curve conformed to the parabolic equation ΔW=2.51t0.22 through nonlinear fitting, while the oxidation kinetic curve of uncoated substrate tended grow linearly. The coated samples before and after oxidation were analyzed with SEM and XRD. Continuous constituent phases including oxides Cr2O3 and NiO as well as NiCr2O4 with spinel structure formed on the surface of coatings at high temperature. These phases were uniformly and densely distributed in the coatings, which could effectively prevent oxygen atoms from invading the substrate and inhibit the continuous oxidation process. The Ni-based alloy coatings with high Cr content prepared on steel Q345 by arc spraying exhibits good oxidation resistance at high temperature, which can greatly improve service temperature and service life of steel Q345 components.
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