GUAN Xiao-yan,WANG Yong-xin,LI Ze-chao,LI Jin-long,LU Xia,WANG Li-ping,XUE Qun-ji.Effects of Cr Layers on Properties of Cr/Cr2N Nano-multilayer Coatings[J],46(11):15-21
Effects of Cr Layers on Properties of Cr/Cr2N Nano-multilayer Coatings
Received:June 01, 2017  Revised:November 20, 2017
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DOI:10.16490/j.cnki.issn.1001-3660.2017.11.003
KeyWord:multi-arc ion plating  Cr/Cr2N nano-multilayer coatings  corrosion resistance  interfaces  wear resistance  seawater environment
                    
AuthorInstitution
GUAN Xiao-yan Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
WANG Yong-xin Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
LI Ze-chao Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
LI Jin-long Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
LU Xia Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
WANG Li-ping Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
XUE Qun-ji Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo , China
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Abstract:
      The work aims to study influences of Cr layers on structures and properties of Cr/Cr2N nano-multilayer coatings, so as to provide theoretical basis for applications of hard coatings in corrosive mediums including seawater. A series of Cr/Cr2N nano-multilayer coatings with different depths of Cr layers were prepared relying on multi-arc ion plating technology. Structures, morphologies and mechanical properties of multilayer coatings were tested with XRD, SEM, nano-indentation and scratch tester, respectively. Electrochemical behaviors of the Cr/Cr2N nano-multilayer coatings in seawater were evaluated with electrochemical workstation. Furthermore, tribological properties of the as-deposited coatings were tested with a tribo-meter. Cr layer had certain effect on structures of the Cr/Cr2N nano-multilayer coatings. Wear rates of the different depths of coatings in seawater were similar, which were approximately 1.2×10−6 mm3/(N•m). The low wear rate indicated excellent wear resistance of the as-deposited coatings. The Cr/Cr2N nano-multilayer coatings with nearly 21 nm thick Cr layer exhibited excellent corrosion resistance with the high impedance in seawater. Metal layer of proper thickness including Cr layer and the interface is crucial to high corrosion resistance of the Cr/Cr2N nano-multilayer coatings. The excellent corrosion and wear resistance of Cr/Cr2N nano-multilayer coatings made them good protective materials in corrosive mediums including seawater.
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