CHEN Huan-tao,ZHANG Xiao-feng,ZHOU Ke-song,LIU Min,DENG Chun-ming,DENG Chang-guang.Structure Evolution of Nano-7YSZ Ceramic Coating During Gradient Thermal Cycle[J],46(6):256-262
Structure Evolution of Nano-7YSZ Ceramic Coating During Gradient Thermal Cycle
Received:January 15, 2017  Revised:June 20, 2017
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DOI:10.16490/j.cnki.issn.1001-3660.2017.06.041
KeyWord:thermal barrier coating  thermal cycle  temperature gradient  sintering mechanism
                 
AuthorInstitution
CHEN Huan-tao 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China
ZHANG Xiao-feng 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China; 3.School of Materials Science and Engineering, South China University of Technology, Guangzhou , China
ZHOU Ke-song 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China; 3.School of Materials Science and Engineering, South China University of Technology, Guangzhou , China
LIU Min 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China
DENG Chun-ming 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China
DENG Chang-guang 1.Guangdong Institute of New Materials, Guangzhou , China; 2.National Engineering Laboratory for Modern Materials Surface Engineering Technology, Guangzhou , China
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Abstract:
      The work aims to get the structure evolution mechanism of nano ceramic coating during gradient thermal cycle by preparing NiCoCrAlYTa bonding layer on nickel-based superalloy (k417) by low temperature-high velocity oxygen flame (HVOF) and nano-7YSZ ceramic coating on the bonding layer by air plasma spraying. Gradient thermal cycle test was carried out on nano-7YSZ TBC with a flame tester to simulate service condition of thermal barrier coating (TBC) in turbine engine. Interface temperatures in TBC were calculated based on one-dimensional model of steady heat conduction. Provided with 40 thermal cycles, the coating subsurface was subject to sintering densification, while base coating of the ceramic layer reserved the original structure. As the thermal cycle number increased to 460 times, entire section of the ceramic layer was subject to sintering densification. The coating sintering densification is mainly affected by temperature. When isometrical grains in the coating contact and form crooked neck, the grains grow slowly since the neck bears static stress in horizontal direction only and diffusion rate of atoms in the grains is slow. However, when non-isometrical grains in the coating contact and form crooked neck, the grains grow quickly since shear force in direction of large grain is present on the neck and the diffusion rate of grains is accelerated.
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