YANG Bin,LIU Jing-xuan,QI Liang,XIAO Xiang-peng,XIE Yi-gao.Effect of Sodium Dodecyl Sulfate on Electrochemical Behavior of Nickel Plating Electrodeposition[J],45(4):132-136,155
Effect of Sodium Dodecyl Sulfate on Electrochemical Behavior of Nickel Plating Electrodeposition
Received:January 05, 2016  Revised:April 20, 2016
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DOI:10.16490/j.cnki.issn.1001-3660.2016.04.022
KeyWord:nickel coating  carbon fiber  sodium dodecyl sulfate  electrodeposition  linear sweep voltammetry  deposition potential
              
AuthorInstitution
YANG Bin Institute of Engineering, Jiangxi University of Science and Technology, Ganzhou , China
LIU Jing-xuan School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou , China
QI Liang School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou , China
XIAO Xiang-peng Institute of Engineering, Jiangxi University of Science and Technology, Ganzhou , China
XIE Yi-gao School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou , China
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Abstract:
      Objective To investigate the effect of sodium dodecyl sulfate (SDS) on the electrodeposition behavior and quality of nickel coating on carbon fiber surface. Methods The electroplating nickel deposition potential for different concentrations of SDS solution was measured using linear sweep voltammetry. The morphology of nickel plating surface in the beginning of the electrodeposition of nickel was analyzed using scanning electron microscopy. Results The deposition potential of nickel in the solution without additives was about -0. 829 V. When adding 0. 1 ~0. 5 g/ L of SDS, the deposition potential of nickel in the solution increased to -0. 792 ~ 0. 745 V, and the maximum deposition potential( -0. 745 V) of nickel was 0. 3 g / L SDS in the additive. Conclusion The results showed that adding a small amount of SDS solution was beneficial to improve the deposition potential of nickel, which could promote the deposition of nickel plating. The surface of nickel coating consising of a pyramid shaped fine structure was uniform and compact, but excessive amount of SDS would affect the equilibrium of adsorption and desorption on the surface of carbon fiber. There was a SDS micro area of non-desorption on the carbon fiber surface and the nucleation of precipitates in this area was affected. The surface of nickel coating consisting of unevenly distributed pyramidal structure and lamellar structure vertical to the base had poor quality. The optimal concentration of the SDS additive in the solution system should be 0. 3 g / L.
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