LIU Qiu-yue,ZHANG Xiu-qing,PU Hai-zhou,XU Jin-peng.Study on the Preparation and Properties of Ni-P / Ni-Sn-P Duplex Coatings on AZ91D Magnesium Alloy[J],44(2):34-37,133
Study on the Preparation and Properties of Ni-P / Ni-Sn-P Duplex Coatings on AZ91D Magnesium Alloy
Received:October 20, 2014  Revised:February 20, 2015
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DOI:10.16490/j.cnki.issn.1001-3660.2015.02.007
KeyWord:AZ91D magnesium alloy  Ni-P coating  Ni-P / Ni-Sn-P duplex coatings  corrosion resistance
           
AuthorInstitution
LIU Qiu-yue School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai , China
ZHANG Xiu-qing School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai , China
PU Hai-zhou School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai , China
XU Jin-peng School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai , China
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Abstract:
      Objective To improve the corrosion resistance of AZ91D magnesium alloy and expand the range of application. Methods Ni-P coating was first prepared on AZ91D magnesium alloy by electroless plating, then Ni-Sn-P coating was prepared on this basis, forming Ni-P/ Ni-Sn-P duplex coatings. The microstructure and corrosion resistance of Ni-P/ Ni-Sn-P duplex coatings were investigated and compared with those of Ni-P coating. Results The results showed that the surface of Ni-P/ Ni-Sn-P duplex coatings was more uniform, compact, with fewer defects, lower porosity and amorphous structure. The corrosion potential of the secondary Ni-Sn-P coating was about -0. 77 V, which was lower than that of the first Ni-P coating ( -0. 68 V). The potential difference between the two coatings formed micro etching point, with Ni-P coating as the cathode, and Ni-Sn-P coating as the anode, and the anode was corroded first. Conclusion The outer layer of Ni-Sn-P coating in the Ni-P/ Ni-Sn-P duplex coatings could protect the first Ni-P coating from corroding and diffuse the corrosion current in the horizontal direction, thus greatly enhancing the corrosion resistance of AZ91D magnesium alloy.
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