GE Meng-qi,ZHANG Jie,XU Jing,LEI Jing-lei,LI Ling-jie.In-situ Fabrication of Self-collected Ni(OH) 2 Supercapacitor Electrode Materials by Hydrothermal Treatment of Ni Foam in H2O2 Solution[J],44(1):47-50,63
In-situ Fabrication of Self-collected Ni(OH) 2 Supercapacitor Electrode Materials by Hydrothermal Treatment of Ni Foam in H2O2 Solution
Received:December 22, 2014  Revised:January 20, 2015
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KeyWord:Ni(OH) 2  hydrothermal method  in-situ fabrication  supercapacitor
              
AuthorInstitution
GE Meng-qi School of Chemistry and Chemical Engineering, Chongqing University, Chongqing , China
ZHANG Jie School of Chemistry and Chemical Engineering, Chongqing University, Chongqing , China
XU Jing School of Chemistry and Chemical Engineering, Chongqing University, Chongqing , China
LEI Jing-lei School of Chemistry and Chemical Engineering, Chongqing University, Chongqing , China
LI Ling-jie School of Chemistry and Chemical Engineering, Chongqing University, Chongqing , China
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Abstract:
      Objective To in-situ fabricate self-collected Ni(OH)2 supercapacitor electrode materials with excellent capacitance and good cycle stability by a facile, cost-effective and green method. Methods The hydrothermal treatment of Ni foam was performed in a 15wt. % H2O2 solution at 180 ℃ for 24 h to in-situ fabricate Ni(OH)2. The morphologies, phase composition and electrochemical performance of the as-prepared Ni(OH)2 electrode material were characterized. Results The β-Ni(OH)2 hexagonal platelets with the side lengths of 400 ~600 nm and the thickness of ~200 nm were obliquely laid on the Ni foam at high densities. The electrode demonstrated excellent capacitance (2534 F/ g at a scan rate of 1 mV/ s) and good cycling stability (91% capacitance retention after 1000 cycles at a scan rate of 50 mV / s) in 2 mol / L KOH aqueous solution. Conclusion The fabrication method developed here was facile, cost-effective and green. The as-prepared binder-free, self-collected electrode material exhibited remarkable electrochemical performance with high specific capacity and good cycling stability.
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