ZHANG Yi-wen,LI Yao,QIANG Liang-sheng,HAO Jian,LIU Xu-song,AN Xiao-kun,ZHAO Jiu-peng.Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition[J],43(6):11-15 |
Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition |
Received:June 14, 2014 Revised:December 10, 2014 |
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KeyWord:lithium-ion battery negative electrode acetylene black/ Ge electrochemical properties |
Author | Institution |
ZHANG Yi-wen |
School of Science, Harbin Institute of Technology, Harbin , China |
LI Yao |
Center for Composite Material, Harbin Institute of Technology, Harbin , China |
QIANG Liang-sheng |
School of Science, Harbin Institute of Technology, Harbin , China |
HAO Jian |
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin , China |
LIU Xu-song |
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin , China |
AN Xiao-kun |
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin , China |
ZHAO Jiu-peng |
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin , China |
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Abstract: |
Objective To improve the electrochemical performance of the germanium materials of lithium-ion batteries. Methods Germanium nanoparticles (Ge-NPs) and acetylene black anodes were fabricated through electrodeposition of Ge in the new-genera-tion ionic liquids on the surface of acetylene black which was electrophoretically deposited on a copper current collector. The structure and electrochemical properties were characterized by electron microscopy, Raman spectroscopy and constant current chargedischarge methods. Results The acetylene black-Ge nanocomposite exhibited the electrochemical cycling properties of over 600 mAh/ g at 0. 2C after 100 cycles. Conclusion The electrochemical performance of composite was obviously better than Ge or acetylene black by itself as anode electrode material. |
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