HU Chuan-bo,ZHENG Yan-sheng,YANG Shi-chun,WANG Fa-long,MO Chun-yan,QING Yong-quan,MO Qian.Preparation and Anti-corrosive Performance Study of Aniline Homopolymer ( Copolymer) / Epoxy Composite Coatings[J],43(4):158-163
Preparation and Anti-corrosive Performance Study of Aniline Homopolymer ( Copolymer) / Epoxy Composite Coatings
Received:February 26, 2014  Revised:April 06, 2014
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KeyWord:chemical oxidation polymerization method  aniline homopolymer  aniline copolymer  epoxy coating  anti-corrosion performance  passivation film
                    
AuthorInstitution
HU Chuan-bo School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China
ZHENG Yan-sheng School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China;College of Lushan, Guangxi University of Science and Technology, Liuzhou , China
YANG Shi-chun School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan , China
WANG Fa-long School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China
MO Chun-yan School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China
QING Yong-quan School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China
MO Qian School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou , China
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Abstract:
      Objective To study the anti-corrosion performance of aniline homopolymer / epoxy composite coating and aniline copolymer / epoxy composite coating in 3. 5% NaCl solution. Methods Chemical oxidation polymerization method was adopted to prepare aniline homopolymer and copolymer. The polymers were characterized by SEM, XRD, UV-vis and IR; the anti-corrosion performance of composite coating in 3. 5% NaCl solution was analyzed by electrochemical test. Results Aniline homopolymer / epoxy composite coating and aniline copolymer / epoxy composite coating both had different levels of anti-corrosion effect. In contrast, the aniline copolymer / epoxy composite coating had the highest corrosion potential and the lowest corrosion current density. Conclusion Aniline copolymer produced a layer of passivation film on the surface of carbon steel, granting the aniline copolymer / epoxy composite coating with good anti-corrosion performance.
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