LI Yan,SUN Ming,LI Hong-bo,LIU Yu-ling,WANG Ao-chen,HE Yan-gang,YAN Chen-qi,ZHANG Jin.Study on CMP Alkaline Polishing Liquid with High Removal Rate for Copper Film and the Determination of Its Performance[J],43(3):74-79
Study on CMP Alkaline Polishing Liquid with High Removal Rate for Copper Film and the Determination of Its Performance
Received:December 29, 2013  Revised:January 17, 2014
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KeyWord:alkaline slurry  copper CMP  TSV technology  FA / O chelating agent  surface roughness
                       
AuthorInstitution
LI Yan Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
SUN Ming Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
LI Hong-bo Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China;College of Information Engineering, Hebei United University, Tangshan , China
LIU Yu-ling Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
WANG Ao-chen Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
HE Yan-gang Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
YAN Chen-qi Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
ZHANG Jin Institute of Microelectronic Technique and Materials, Hebei University of Technology, Tianjin , China
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Abstract:
      Objective The optimal CMP technique used for TSV Technology was explored in this paper. Methods In alkaline condition, chemical mechanical polishing was carried out on the copper film and the high polishing rate and low surface roughness were acquired through adjustment of polishing technical parameters and polishing liquid formulation, taking advantage of the extremely strong chelating ability of FA / O chelating agent. Results The Cu film removal rate reached 2067. 245 nm / min and the roughness was obviously improved after CMP when the pressure was 27. 56 kPa, the flow rate was 175 mL / min, the rotating speed was 105 / 105 r / min, the pH value was 11. 0, the temperature was 40 ℃ , and the slurry contained 1% oxidant, 50% abrasive and 10% chelating agent. Conclusion The process could achieve high polishing rate.
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