DU Chong-lin,LIAO Deng-hui,YU Qiang.The Effect of Preparation Temperature and Current Density on the Electrochemical Properties of PbO2 Electrode[J],(5):18-21,37
The Effect of Preparation Temperature and Current Density on the Electrochemical Properties of PbO2 Electrode
Received:April 20, 2012  Revised:October 20, 2012
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KeyWord:PbO2 electrode  overpotential of oxygen evolution  electro-catalytic activity  cell voltage
        
AuthorInstitution
DU Chong-lin Kunming Metallurgy College, Kunming , China
LIAO Deng-hui Kunming Metallurgy College, Kunming , China
YU Qiang Kunming Metallurgy College, Kunming , China
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Abstract:
      Through the analysis of oxygen evolution curve and oxygen evolution kinetic parameters of PbO2 electrode on stainless steel substrate prepared by different temperature and different current density, the effect of temperature and current density on the energy saving property and catalytic activity of PbO2 electrode was studied. The results show that when the temperature is 80℃, current density is 30 mA/cm2, the electrode have a stable composition and good reproducibility, the cell voltage is decreased and have a good electro-catalytic activity; The mainly products are β-PbO2 at low current density and there are partial products are α-PbO2 at high current density; The energy saving property and catalytic activity are highly improved compared with the traditional Pb-Ag alloy anode.
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